Chapter 4, Problem 4.26P

Compute the standard heat of reaction for each of the following reactions taking place at 298.15 K in dilute aqueous solution at zero ionic strength.

1. D-Glucose + ATP²- →D-Glucose 6-phosphate- + ADP-
2. D-Glucose 6-phosphate- → D-Fructose 6-phosphate-
3. D-Glucose 6-phospahte- + ATP²- →D-Fructose 1, 6-biphosphate²- + ADP-
4. D-Glucose + 2 ADP- + 2H₂PO-₄+ 2 NAD+ → 2 Pyruvate- + 2 ATP²- + 2 NADH + 4H+ + 2H₂O
5. D-Glucose + 2 ADP- + 2H₂PO-₄ → 2 Lactate + 2 ATP²- + 2H+ + 2H₂O
6. D-Glucose + 2 ADP- + 2H₂PO-₄ → 2CO₂ + 2 Ethanol + 2 ATP²- + 2H₂O
7. 2 NADH + O₂+ 2H+ →2 NAD+ + 2H₂O
8. ADP- + H₂PO-₄→ ATP²- + H₂O
9. 2 NADH + O₂+ 2 ADP- + 2H₂PO-₄+ O₂+ 2H+ → 2 NAD+ + 2ATP²- + 4H₂O
10. $D-Fructose+2AD{P}^{-}+2H_{2}P{O}_4^{-}\to 2C{O}_2+2Ethanol+2AT{P}^{2-}+2H_{2}O$
11. $D-Galactose+2AD{P}^{-}+2H_{2}P{O}_4^{-}\to 2C{O}_2+2$
12. $Ethanol+2AT{P}^{2-}+2H_{2}O$
$N{H}_4^{+}+L-aspartat{e}^{-}+AT{P}^{2-}\to L-asparagine+AD{P}^{-}+H_{2}P{O}_4^{-}$