Package: Organic Chemistry With Connect 2-semester Access Card
4th Edition
ISBN: 9781259671838
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 4, Problem 4.42P
Interpretation Introduction
Interpretation: To identify which among the given compounds is not the isomer of undecane.
Concept introduction: Isomers are those compounds which have same molecular formula but different structure.
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a. Which of the following compounds have the same empirical formula?(1) But-2-ene(2) Propane(3) EtheneA. (1) and (2) onlyB. (1) and (3) onlyC. (2) and (3) onlyD. (1), (2) and (3)
b. Which of the following statements concerning homologous series is INCORRECT?A. Members of a series have identical chemical properties.B. Members of a series have the same general formula.C. Each member differs from the next by a −CH2− group.D. Members of a series show a gradual change of physical properties.
Draw the structural formula for each of the following.
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a.3-isobutylhexane
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b.2,2,4-trimethylpentane, also called isoocta11e. This substance is the reference (100 level) for octane ratings.
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c. 2-tert-butylpentane
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d.The names given in parts a and c are incorrect.Give the correct names for these hydrocarbons
What kinds of reactions are common to alkanes? List an example of each.
Chapter 4 Solutions
Package: Organic Chemistry With Connect 2-semester Access Card
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - (a) Classify the carbon atoms in each compound as...Ch. 4 - Problem 3.3 Classify a carbon atom by the number...Ch. 4 - Problem 4.3 Draw the five constitutional isomers...Ch. 4 - Prob. 4.6PCh. 4 - Prob. 4.7PCh. 4 - Draw the five constitutional isomers that have...Ch. 4 - Give the IUPAC name for each compound. a. c. b. ...Ch. 4 - Give the IUPAC name for each compound. a....
Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.12PCh. 4 - Give the IUPAC name for each compound.Ch. 4 - Give the structure corresponding to each IUPAC...Ch. 4 - Arrange the following compounds in order of...Ch. 4 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4 - Prob. 4.17PCh. 4 - a.Draw the three staggered and three eclipsed...Ch. 4 - Problem 4.19 Consider rotation around the...Ch. 4 - Calculate the destabilization present in each...Ch. 4 - Problem 4.21 Classify the ring carbons as up or...Ch. 4 - Draw a second chair conformation for each...Ch. 4 - Prob. 4.23PCh. 4 - Problem 4.25 Draw the structure for each compound...Ch. 4 - For cis-1, 3-diethylcyclobutane, draw a a...Ch. 4 - Prob. 4.26PCh. 4 - Problem 4.28 Consider .
Draw structures f or the...Ch. 4 - Problem 4.29 Draw a chair conformation of...Ch. 4 - Prob. 4.29PCh. 4 - Draw the products of each combustion reaction.Ch. 4 - Explain why beeswax is insoluble in H2O, slightly...Ch. 4 - Prob. 4.32PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - Consider the substituted cyclohexane shown in the...Ch. 4 - Prob. 4.35PCh. 4 - 3.31 For each alkane: (a) classify each carbon...Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Give the IUPAC name for each compound. a. h.k....Ch. 4 - 4.39 Give the structure and IUPAC name for each of...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - Prob. 4.42PCh. 4 - Prob. 4.43PCh. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - 4.45 Which conformation in each pair is higher in...Ch. 4 - Considering rotation around the bond highlighted...Ch. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - 4.49 Label the sites of torsional and steric...Ch. 4 - Prob. 4.52PCh. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - 4.56 Convert each of the following structures into...Ch. 4 - Prob. 4.59PCh. 4 - Prob. 4.60PCh. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 4.62PCh. 4 - Prob. 4.63PCh. 4 - 4.62 Draw the three constitutional isomers having...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Which of the following compounds are lipids?Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 4.72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 4.74PCh. 4 - Prob. 4.75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- The compound CH2=CHCH2CH2CH3 is an example of: a. a pentane. b. a hexene. c. an alkene. d. organic macromolecule.arrow_forwardPetrol is a complex mix of light hydrocarbons. Petrol with octane number 95 contains 95% 2,2,4-trimethylpentane. This compound can be obtained by breaking up a large hydrocarbon molecule such as dodecane, C12H26 using a catalyst such as zeolite. a) name the process where a large hydrocarbon molecule is broken into smaller molecules b) write an equation for the breaking up of dodecane into 2,2,4-trimethylpentane if another branched hydrocarbon compound is formed at the same time. c) what is the other hydrocarbon obtained ? d) draw the structural formula of 2,2,4-trimethylpentane.arrow_forwardConsider the reaction in the attached picture:  1. The reaction is an example of ______. a. Addition reaction b. substitution reaction c. elimination reaction  2. The reaction shows _________ a. Oxidation of alcohol to produce an alkene b. Dehydration of alcohol to produce an alkyne c. Dehydration of alcohol to produce an alkenearrow_forward
- Illustrate the Combustion of Alkanes ?arrow_forwardDraw the shorthand structures of the following molecules: 1.) Butane 2.) 2-methylhexanearrow_forwardWhich of the following statement is true about alkanes?  a Alkanes are one of the three unsaturated hydrocarbons.  b Alkanes are always linear molecules.  c Alkanes are commonly derived from petroleum and natural gas.  d Alkanes have 4 additional hydrogens compared to an alkene with the same number of carbon.arrow_forward
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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
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