Chemistry for Engineering Students
Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 4, Problem 4.85PAE
Interpretation Introduction

Interpretation:

To calculate the mass of sulfur dioxide from 1.25 kg calcium sulfate

Concept introduction:

  • Use stoichiometry to relate to the moles of each reactant/product
  • Use molar mass to relate total mass of species

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Sodium carbonate is often added to laundry detergents to soften hard water and make the detergent more effective. Suppose that a particular detergent mixture is designed to soften hard water that is 3.8×10−3M in Ca2+ and 1.1×10−3M in Mg2+ and that the average capacity of a washing machine is 24.5 gallons of water. 1gallon=3.785L   If the detergent requires using 0.61 kg detergent per load of laundry, determine what percentage (by mass) of the detergent should be sodium carbonate in order to completely precipitate all of the calcium and magnesium ions in an average load of laundry water. Express your answer in percent to two significant figures.
Sodium carbonate is often added to laundry detergents to soften hard water and make the detergent more effective. Suppose that a particular detergent mixture is designed to soften hard water that is 3.8×10−3M in Ca2+ and 1.1×10−3M in Mg2+ and that the average capacity of a washing machine is 24.5 gallons of water. 1gallon=3.785L If the detergent requires using 0.61 kg detergent per load of laundry, determine what percentage (by mass) of the detergent should be sodium carbonate in order to completely precipitate all of the calcium and magnesium ions in an average load of laundry water.
1.58g of magnesium hydrogencarbonate was added to a 1.68 mol/L solution of acetic acid, CH₃COOH in water (50.0 mL), producing carbon dioxide gas, water and magnesium acetate, Mg(CH3COO)2. a) Write a balanced chemical equation for the reaction.  b) What mass of acetic acid is in the aqueous solution?  c) Which of the reactants is the limiting reagent? Justify your answer.  d) If 1.23 g of magnesium acetate was produced, what is the percentage yield of the reaction? e) What is the theoretical yield (in grams) of carbon dioxide from this reaction?  f) The above reaction is performed in a closed 25 L container at 10 °C. Upon completion of the reaction, what will the final pressure of CO2 be inside the container?

Chapter 4 Solutions

Chemistry for Engineering Students

Ch. 4 - 4.4 Automobile exhaust often contains traces of...Ch. 4 - 4.5 Methane, ethane, and propane are also...Ch. 4 - 4.6 Use the web to research prices of gasoline at...Ch. 4 - For the following reactions, write the ratios that...Ch. 4 - 4.8 In an experiment carried out at very low...Ch. 4 - 4.9 Sulfur, S8, combines with oxygen at elevated...Ch. 4 - 4.10 How many moles of oxygen can be obtained by...Ch. 4 - 4.11 MTBE, C5H12O, is one of the additives that...Ch. 4 - 4.12 In petroleum refining, hydrocarbons are often...Ch. 4 - 4.13 For the following reactions, determine the...Ch. 4 - 4.14 The combustion of liquid chloroethylene,...Ch. 4 - 4.15 What mass of the unknown compound is formed...Ch. 4 - 4.16 Many metals react with halogens to give metal...Ch. 4 - 4.17 Phosgene is a highly toxic gas that has been...Ch. 4 - Prob. 4.18PAECh. 4 - 4.19 How many metric tons of carbon are required...Ch. 4 - 4.20 Assuming a charcoal briquette is composed...Ch. 4 - 4.21 Ammonium nitrate, NH4NO3, will decompose...Ch. 4 - If 3.4 mol Al and 6.2 mol Fe2O3 are mixed, what is...Ch. 4 - If 8.4 moles of disilane, Si2H6, is combined with...Ch. 4 - 4.22 Generally, an excess of O2 is needed for the...Ch. 4 - 4.23 In the reaction of arsenic with bromine,...Ch. 4 - 4.24 Ammonia gas can be prepared by the reaction...Ch. 4 - 4.25 When octane is combusted with inadequate...Ch. 4 - 4.26 The equation for one of the reactions in the...Ch. 4 - 4.27 Copper reacts with sulfuric acid according to...Ch. 4 - 4.28 One of the steps in the manufacture of nitric...Ch. 4 - 4.29 When Al(OH)3 reacts with sulfuric acid, the...Ch. 4 - 4.30 Copper reacts with nitric acid via the...Ch. 4 - 4.31 How much HNO3 can be formed in the following...Ch. 4 - 4.32 Hydrogen and oxygen are reacted and the water...Ch. 4 - 4.33 Silicon carbide, an abrasive, is made by the...Ch. 4 - Prob. 4.36PAECh. 4 - Prob. 4.37PAECh. 4 - 4.36 Sometimes students in chemistry labs...Ch. 4 - 4.37 The theoretical yield and the actual yield...Ch. 4 - 4.38 A reaction that produced 4.8 mg of taxol, an...Ch. 4 - Methanol, CH3OH, is used in racing cars because it...Ch. 4 - 4.40 When iron and steam react at high...Ch. 4 - 4.41 The percentage yield of the following...Ch. 4 - 4.42 Sulfur hexafluoride is a very stable gas...Ch. 4 - 4.43 Magnesium nitride forms in a side reaction...Ch. 4 - 4.44 Industrial production of hydrogen gas uses...Ch. 4 - 4.45 If 21 g of H2S is mixed with 38 g of O2 and...Ch. 4 - 4.46 A mixture of 10.0 g of NO and 14.0 g of NO2...Ch. 4 - 4.47 Silicon carbide is, an abrasive used in the...Ch. 4 - 4.48 Elemental phosphorous is used in the...Ch. 4 - 4.49 Small quantities of hydrogen gas can be...Ch. 4 - Prob. 4.52PAECh. 4 - 4.51 What is the role of an indicator in a...Ch. 4 - 4.52 What volume of 0.812 M HCl, in milliliters,...Ch. 4 - Prob. 4.55PAECh. 4 - Prob. 4.56PAECh. 4 - Hydrazine, N2H4, is a weak base and can react with...Ch. 4 - Prob. 4.58PAECh. 4 - Prob. 4.59PAECh. 4 - Prob. 4.60PAECh. 4 - 4.59 Aluminum dissolves in HCI according to the...Ch. 4 - 4.60 Why are fuel additives used?Ch. 4 - 4.61 What is actually measured by the octane...Ch. 4 - Prob. 4.64PAECh. 4 - Prob. 4.65PAECh. 4 - 4.64 Using the web, find information about the...Ch. 4 - 4.65 Using the web, find out how lead “poisons”...Ch. 4 - Prob. 4.68PAECh. 4 - You have 0.954 g of an unknown acid, H2A, which...Ch. 4 - Prob. 4.70PAECh. 4 - 4.79 Phosphoric add (H3PO4) is important in the...Ch. 4 - 4.80 The reaction shown below is used to destroy...Ch. 4 - Prob. 4.73PAECh. 4 - One way of determining blood alcohol levels is by...Ch. 4 - Prob. 4.75PAECh. 4 - The pictures below show a molecular-scale view of...Ch. 4 - The pictures below show a molecular-scale view of...Ch. 4 - 4.84 Aluminum chloride (AlCl3) is used as a...Ch. 4 - 4.85 In the cold vulcanization of rubber, disulfur...Ch. 4 - Prob. 4.80PAECh. 4 - Prob. 4.81PAECh. 4 - 4.88 A quality control technician needs to...Ch. 4 - Prob. 4.83PAECh. 4 - 4.90 Iron metal can be refined (rom the mineral...Ch. 4 - Prob. 4.85PAECh. 4 - Prob. 4.86PAECh. 4 - 4.93 A mixture of methane (CH4) and propane (C3H8)...Ch. 4 - Prob. 4.88PAECh. 4 - Prob. 4.89PAECh. 4 - Prob. 4.90PAECh. 4 - Prob. 4.91PAECh. 4 - Prob. 4.92PAECh. 4 - Prob. 4.93PAECh. 4 - Prob. 4.94PAECh. 4 - Prob. 4.95PAECh. 4 - Prob. 4.96PAECh. 4 - Prob. 4.97PAECh. 4 - 4.104 When 2.750 g of the oxide Pb3O4 is heated to...Ch. 4 - Prob. 4.99PAECh. 4 - 4.106 An ore sample with a mass of 670 kg contains...Ch. 4 - 4.107 Existing stockpiles of the refrigerant...Ch. 4 - 4.108 Elemental analysis is sometimes carried out...Ch. 4 - Prob. 4.103PAECh. 4 - 4.110 Write the balanced chemical equation lot the...Ch. 4 - 4.111 Aluminum metal reacts with sulfuric acid to...Ch. 4 - 4.112 A metallurgical firm wishes to dispose of...
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  • Ethanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.
    1.58g of magnesium hydrogencarbonate was added to a 1.68 mol/L solution of acetic acid, CH3COOH in water (50.0 mL), producing carbon dioxide gas, water and magnesium acetate, Mg(CH3COO)2. a) Write a balanced chemical equation for the reaction.  b) What mass of acetic acid is in the aqueous solution?  c) Which of the reactants is the limiting reagent? Justify your answer.  d) If 1.23 g of magnesium acetate was produced, what is the percentage yield of the reaction? e) What is the theoretical yield (in grams) of carbon dioxide from this reaction?  f) The above reaction is performed in a closed 25 L container at 10 °C. Upon completion of the reaction, what will the final pressure of CO2 be inside the container?      please answer d, e and f
    If 10.8 mL of 0.25 M HCl(aq) reacts with an excess of Mg(OH)2(aq), what mass of magnesium chloride could be produced? What mass of water could be produced?
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