Concept explainers
(a)
Interpretation: An expression analogous to the Clausius-Clapeyron equation, starting for the Clapeyron equation for the temperature variation of the vapour pressure of a solid has to be derived.
Concept introduction: Clapeyron equation can be used to calculate the enthalpy of various phase transitions. The phase transition between the liquid and solid state of a substance is calculated by the following formula.
(b)
Interpretation: The standard enthalpy of sublimation of chloromethane at
Concept introduction: Clausius-Clapeyron expression correlates the pressure and temperature for the processes that includes the phase transitions. Clausius-Clapeyron equation is shown below.
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