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A wire weighing 0.250 g and containing 92.50% Fe is dissolved in HCI. The iron is completely oxidized to Fe3+ by bromine water. The solution is then treated with tin(II) chloride to bring about the reaction
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Chapter 4 Solutions
Owlv2, 4 Terms (24 Months) Printed Access Card For Masterton/hurley's Chemistry: Principles And Reactions, 8th
- You are given a solid mixture of NaNO2 and NaCl and are asked to analyze it for the amount of NaNO2 present. To do so, you allow the mixture to react with sulfamic acid, HSO3NH2, in water according to the equation NaNO2(aq) + HSO3NH2(aq) NaHSO4(aq) + H2O() + N2(g) What is the weight percentage of NaNO2 in 1.232 g of the solid mixture if reaction with sulfa-mic acid produces 295 mL of dry N2 gas with a pressure of 713 mm Hg at 21.0 C?arrow_forwardPotassium permanganate (KMnO4) solutions are used for the determination of Fe2+ in samples of unknown concentration. As a laboratory assistant, you are supposed to prepare 500 mL of a 0.1000 M KMnO4 solution. What mass of KMnO4, in grams, do you need?arrow_forwardOn Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?arrow_forward
- Triiodide ions are generated in solution by the following (unbalanced) reaction in acidic solution: IO3(aq) + I(aq) I3(aq) Triiodide ion concentration is determined by titration with a sodium thiosulfate (Na2S2O3) solution. The products are iodide ion and tetrathionate ion (S4O6). a. Balance the equation for the reaction of IO3 with I ions. b. A sample of 0.6013 g of potassium iodate was dissolved in water. Hydrochloric acid and solid potassium iodide were then added. What is the minimum mass of solid KI and the minimum volume of 3.00 M HQ required to convert all of the IO3 ions to I ions? c. Write and balance the equation for the reaction of S2O32 with I3 in acidic solution. d. A 25.00-mL sample of a 0.0100 M solution of KIO. is reacted with an excess of KI. It requires 32.04 mL of Na2S2O3 solution to titrate the I3 ions present. What is the molarity of the Na2S2O3 solution? e. How would you prepare 500.0 mL of the KIO3 solution in part d using solid KIO3?arrow_forward4.112 A metallurgical firm wishes to dispose of 1300 gallons of waste sulfuric acid whose molarity is 1.37 M. Before disposal, it will be reacted with calcium hydroxide (slaked lime), which costs $0.23 per pound. (a) Write the balanced chemical equation for this process. (b) Determine the cost that the firm will incur from this use of slaked lime.arrow_forwardA stock solution of potassium dichromate, K2Cr2O7, is made by dissolving 84.5 g of the compound in 1.00 L of solution. How many milliliters of this solution are required to prepare 1.00 L of 0.150 M K2Cr2O7?arrow_forward
- Acetic acid (HC2H3O2) can be prepared by the action of the acetobacter organism on dilute solutions of ethanol (C2H5OH). The equation for the reaction is C2H5OH(aq)+O2(g)HC2H3O2(aq)+H2OHow many milliliters of a 12.5% (by volume) solution of ethanol are required to produce 175 mL of 0.664 M acetic acid? (Densityofpureethanol=0.789g/mL.)arrow_forwardDetermine the volume of sulfuric acid solution needed to prepare 37.4 g of aluminum sulfate, Al2(SO4)3, by the reaction 2Al(s)+3H2SO4(aq)Al2(SO4)3(aq)+3H2(g) The sulfuric acid solution, whose density is 1.104 g/mL, contains 15.0% H2SO4 by mass.arrow_forwardYou wish to determine the weight percent of copper in a copper-containing alloy. After dissolving a 0.251 -g sample of the alloy in acid, an excess of KI is added, and the Cu2+ and I ions undergo the reaction 2 Cu2+(aq) + 5 I(aq) 2 CuI(s) + I3(aq) The liberated I3 is titrated with sodium thiosulfate according to the equation I3 (aq) + 2 S2O32(aq) S4O62(aq) + 3 I (aq) (a) Designate the oxidizing and reducing agents in the two reactions above. (b) If 26.32 mL of 0.101 M Na2S2O3 is required for titration to the equivalence point, what is the weight percent of Cu in the alloy?arrow_forward
- Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?arrow_forwardDetermine the volume of sodium hydroxide solution needed to prepare 26.2 g sodium phosphate, Na3PO4, by the reaction 3NaOH(aq)+H3PO4(aq)Na3PO4(aq)+3H2O(l) The sodium hydroxide solution, whose density is 1.133 g/mL, contains 12.0% NaOH by mass.arrow_forwardAqueous solutions of ammonium sulfide and mercury(II) nitrate react and a precipitate forms. (a) Write the overall balanced chemical equation and indicate the state (aq) or (s) for each compound. (b) Name each product. (c) Write the complete ionic equation. (d) Write the net ionic equation.arrow_forward
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