EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Textbook Question
Chapter 4.2, Problem 8P
Assign relative priorities to each set of substituents:
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What is true about the relationship between the following compounds?
CH3
CH3
CH;
CH;
CH3
CH3
A
В
O All three are stereoisomers of each other.
OA and B are the same compound while C is a stereoisomer.
All three are the same compound.
A and B are the same while C is a conformer, all of the same compound .
O A and C are the same while B is a stereoisomer.
Give the IUPAC name for each polyfunctional compound.
Assign priorities to these set of Substituents
Chapter 4 Solutions
EBK ORGANIC CHEMISTRY
Ch. 4.1 - Prob. 2PCh. 4.1 - Prob. 3PCh. 4.1 - Prob. 4PCh. 4.1 - Prob. 5PCh. 4.1 - Which of the roll owing compounds have a dipole...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Assign relative priorities to each set of...Ch. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Prob. 10PCh. 4.2 - Name each of the following:
Ch. 4.2 - Draw the Z isomer of an alkene that has a CH3 and...Ch. 4.3 - Prob. 13PCh. 4.4 - Prob. 14PCh. 4.5 - Prob. 16PCh. 4.6 - Prob. 17PCh. 4.7 - Prob. 18PCh. 4.8 - Prob. 20PCh. 4.8 - Prob. 22PCh. 4.8 - Prob. 23PCh. 4.8 - Prob. 24PCh. 4.8 - Draw a perspective formula for each or the...Ch. 4.8 - Prob. 27PCh. 4.9 - Prob. 28PCh. 4.9 - What is the configuration of the following...Ch. 4.9 - Prob. 32PCh. 4.10 - Prob. 33PCh. 4.10 - (S)-(+)-Monosodium glutamate (MSG) is a flavor...Ch. 4.11 - Prob. 35PCh. 4.11 - Prob. 36PCh. 4.12 - Prob. 38PCh. 4.12 - Prob. 39PCh. 4.12 - The stereoisomer of cholesterol found in nature is...Ch. 4.12 - Prob. 41PCh. 4.13 - 1-Bromo-2-methylcyclopentane has four pairs of...Ch. 4.13 - Prob. 43PCh. 4.13 - Draw all possible stereoisomers for each of the...Ch. 4.13 - Prob. 45PCh. 4.13 - Of all the possible cyclooctanes that have one...Ch. 4.13 - Prob. 47PCh. 4.13 - Prob. 48PCh. 4.14 - Which of the following compounds has a...Ch. 4.14 - Draw all the stereoisomers for each of the...Ch. 4.15 - Prob. 52PCh. 4.15 - Name the isomers you drew in Problem 52.Ch. 4.15 - Chloramphenicol is a broad-spectrum antibiotic...Ch. 4.15 - Draw a perspective formula for each of the...Ch. 4.15 - Name the following:Ch. 4.15 - Prob. 57PCh. 4.15 - Prob. 59PCh. 4.15 - Convert the perspective formula to a skeletal...Ch. 4.15 - Prob. 62PCh. 4.16 - Prob. 63PCh. 4.17 - Limonene exists as two different stereoisomers....Ch. 4 - a. Draw three constitutional isomers with...Ch. 4 - Prob. 65PCh. 4 - Prob. 66PCh. 4 - Which of the following has an asymmetric center?...Ch. 4 - Prob. 68PCh. 4 - Prob. 69PCh. 4 - Prob. 70PCh. 4 - Prob. 71PCh. 4 - Assign relative priorities to each set of...Ch. 4 - Prob. 73PCh. 4 - Which of the following are optically active?Ch. 4 - Prob. 75PCh. 4 - Name the following:Ch. 4 - Which of the following has an achiral...Ch. 4 - Using skeletal structures, draw the stereoisomers...Ch. 4 - Prob. 79PCh. 4 - Citrate synthase, one of the enzymes in the series...Ch. 4 - Prob. 81PCh. 4 - Prob. 82PCh. 4 - Prob. 83PCh. 4 - Prob. 84PCh. 4 - Prob. 85PCh. 4 - Prob. 86PCh. 4 - Prob. 87PCh. 4 - Prob. 88PCh. 4 - Prob. 89PCh. 4 - a. Draw all the isomers with molecular formula...Ch. 4 - Prob. 91PCh. 4 - Prob. 92PCh. 4 - Draw structures for the following: a....Ch. 4 - For each of the following structures, draw the...Ch. 4 - Prob. 95PCh. 4 - Prob. 96PCh. 4 - Prob. 97PCh. 4 - a. Using the wedge-and-dash notation, draw the...Ch. 4 - Prob. 99PCh. 4 - Prob. 100PCh. 4 - Prob. 101PCh. 4 - a. Draw the two chair conformers for each of the...Ch. 4 - Prob. 103PCh. 4 - Is the following compound optically active?Ch. 4 - Prob. 105P
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- What is the correct IUPAC name (preferred = acceptable) for the following compound? %3D Br (2Z)-5-bromo-3-methylhex-2-ene O (2E)-5-bromo-3-methylhex-2-ene O 2-bromo-4-methylhex-4-ene O (4Z)-2-bromo-4-methylhex-4-enearrow_forwardExamples: Name the following compounds: Parent chain: Substituent(s): Position of each substituent: Name: Parent chain: Substituent(s): Position of each substituent: Name: Parent chain: Substituent(s): Position of each substituent: Name:arrow_forwardIndicate whether the pair of structures shown represent stereoisomers, constitutional isomers, different conformations of the same compound, or the same conformation of a compound viewed from a different perspective. Note that cis, trans isomers are an example of stereoisomers. HỌ. CH3- H H3C- CH 30- CH3 H H QCH3 CH3 OCH 3 H CH3 CH3O F -OH CH3 H -OCH3 _OCH3 given option stereoisomers constitutional isomers different conformations same conformationarrow_forward
- eck the box under each compound that exists as a pair of cis/trans isomers. If none of them do, check the none of the ve box under the table. OH CI CH3 ? НО —с—CH—ОН CH3-C=C –CH3 ОН ОН CH3 CI НО C=C CH3 C=C -CH3 O none of the abovearrow_forwardQ9. Draw all the four possible stereoisomers of compound 1 using dashed/filled wedge bonds to show the relative position of substituents in space. ndicate the enantiomeric or diastereomeric relationship between each pair of isomers. OH .COOH H3C 1arrow_forwardAssign relative priorities to each set of substituents: a. ¬Br ¬I ¬OH ¬CH3b. ¬CH2CH2OH ¬OH ¬CH2Cl ¬CH“CH2arrow_forward
- Q2 / Draw the following compounds so that they are optically active. A ) Br-CH2-CH2 -CH(CI)-CH(CI)-CH2-CH2-Br B) OH-CH2-CH(CH3)-CH2-CH(CH3)-CH2-OH B/ Draw the following compound in a chair position. RAarrow_forwardParent chain: Substituent(s): Position of each substituent: OH Name: Parent chain: OH Substituent(s): Position of each substituent: Name: Parent chain: он Substituent(s): Position of each substituent: Name: Parent chain: Но- Substituent(s): Position of each substituent: Br Name: Parent chain: Substituent(s): Position of each substituent: он Name:arrow_forward10) Circle each achiral molecule among those shown below. BiH. C/ CI Br OH CH3arrow_forward
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