ORGANIC CHEMISTRY,VOL.1 >CUSTOM<
ORGANIC CHEMISTRY,VOL.1 >CUSTOM<
10th Edition
ISBN: 9781260020724
Author: Carey
Publisher: MCG CUSTOM
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Chapter 5, Problem 30P
Interpretation Introduction

Interpretation:

Each oxygen in the compound zoapatanol is to be classified according to the functional group to which it belongs. If the oxygen is part of an alcohol, it is to be classified as primary, secondary, or tertiary.

Concept introduction:

Functional groups in which an oxygen is bonded only to a carbon or carbon and hydrogen are – alcohol ROH, ether ROR, aldehyde RC(O)H, ketone RC(O)R, carboxylic acid RCOOH, ester RCOOR.

Alcohols are classified as primary, secondary, and tertiary based on whether the hydroxyl group is bonded to a primary, secondary, or a tertiary carbon.

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1) The carbonyl group of aldehydes and ketones is polar where the ⸹+ symbol is placed on the oxygen atom and the ⸹- symbol is placed on the carbon atom. a) True b) False 2) Why is the boiling points of ethers similar to thise of alkanes instead of alcohols? a) Both ether molecules and alkanes molecules are polar, whereas alcohol molecules are nonpolar. b) Hydrogen bonding between ethr molecules is strong and this property is similar to that of alkanes. However, hydrogen bonding is weaker in alcohols than it is in both ethers and alkanes. c) Although ether molecules are polar, they cannot form hydrogen bonds with other ether molecules. Similarly, alkane molecules do not form hydrogen bonds, whereas there is hydrogen bonding in alcohols. d) None of these are correct explanations
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