Concept explainers
(a)
Interpretation: The comparison between the boiling points of stereoisomers A and B and, stereoisomers A and C is to be stated.
Concept introduction: Enantiomers are the stereoisomers that have exactly opposite
(b)
Interpretation: The solutions of pure A, pure B, pure C, an equal mixture of A and B, and an equal mixture of A and C are to be characterized as optically active or inactive.
Concept introduction: Enantiomers are the stereoisomers that have exactly opposite
(c)
Interpretation: The number of fraction obtained after distillation of
Concept introduction: Enantiomers are the stereoisomers that have exactly opposite
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ORGANIC CHEMISTRY SOLUTIONS MANUAL
- مگر compound e Reagents a. HX b. c. H₂O, H₂SO4 d. X₂ e. H₂. Pd 1. X₂, H₂O g. Oso, then NaHSO, h. 1. j. HBr, H₂O₂. hv k. 1. compound a bb Hg(OAc)₂, H₂O then NaBH, BH, then H₂O₂. NaOH O, then (CH₂)₂S 2 equivalents of NaNH₂ H₂, Lindlar's catalyst P. adi✔ m. Na/NH₂ n. H₂SO₂, HgSO4 o 9₁ bb r. compound b compound c S L PBr u SOCI₂ V. H₂PO w. H₂CrO₂ X PCC compound f (sia) BH then H₂O₂, NaOH 1 equivalent of NaNH₂ NBS, hy Br₂, hv (CH₂)₂CO¹K* compound d y. Z aa. bb. Na 104 mCPBA NaOH, H₂O compound garrow_forward15. Give the major organic product, paying attention to stereochemistry (syn/anti). Indicate if a racemic mixture is expected. a. a. BH3 b. H2O2, OH a. BH3 b. b. H2O2, OH a. BH3 a. BH3 C. d. b. H2O2, OH b. H₂O2, OH e. a. BH3 b. H₂O2, OHarrow_forwardPick the reactant or solvent in each part that gives the faster SN2 reaction.a. reaction of -OH with CH3CH2Br or CH3CH2Clb. reaction of CH3CH2CH2Cl with NaOH or NaOCOCH3c. reaction of CH3CH2CH2I with -OCH3 in CH3OH or DMSOarrow_forward
- select reagents: cyclopentanone Reagents a. C6H5CHO b. NaOH, ethanol c. Pyrrolidine, cat. Hj. d. H₂C=CHCN e. H3O+ f. LDA g. A) bg EtOC(=O)CO₂Et h. i. B) ka k. I. m. O: BrCH₂CH=CH₂ NatOEt, ethanol Br₂, H+ K+ t-BUO™ CH2(CO2Et)z heat C) jh CO₂Et D) Imarrow_forward1. Write reactions of butane with the following reagents: a. Br2/t °C; b. KMnO4/ H2O/20 °C;arrow_forwardWhich of the following represents regiospecific reaction? a. b. C. d. CH3 H₂C MO= H₂C CH3 + HCI + HI CH₂(CH₂)₂CH=CH₂ + HBr C=CH₂ + HF Ether Ether Ether CH3 CI Major Product CH3 Minor Product CH3 (CH3)CHCH₂F Main Product CH₂(CH₂)3-CH₂Br + CH3(CH,),CHBr-CH3 O Oarrow_forward
- What is the product from the following reaction? A. A B. B D. D Br Br NaNH, (2 equivalents) A Br B C Br Darrow_forwardWhat is a reasonable product of the series of transformations below? A. B. 1. CH3CI, AICI3 2. fuming H₂SO4 SO3H SO3H C. CI D. CI ? SO3H SO3Harrow_forwardItems 49-51: Given the following reaction: CH3 H. CH3 49. What is the product of the reaction? A. В. C. D. 50. Which MO will be involved in this electrocyclic reaction? 888888 888888 888888 A. B. C. 51. The reaction will go through: A. a conrotatory motion B. a disrotatory motion C. none of thesearrow_forward
- 10. Provide unambiguous structural formulas for reaction products A, B, and C. Br 1) I (2 eq.) 2) B(OMe)3 Pd(PPhala Grubbs cat. Barrow_forwardShow how to bring about the following conversion. H. HO H. (гасеmic)arrow_forwardWhich of the following reactions is AS a negative value? a. b. CH3 + CH3 C. (CH3)2C(OH)2 d. CH3COOCH3 + H₂O CH3CH3 (CH3)₂C=O + H₂O CH₂COOH + CH₂OHarrow_forward
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