Explanation The given phase diagram is shown below as, The partially miscible liquids are not miscible to each other at all temperature and pressure. At x B = 0.3 , when the mixture is heated up to temperature T 2 , both the liquids are present in the mixture and are not completely miscible. Thus, the number of phases till temperature T 2 is 2 and the composition of A is more as x B = 0.3 which means x A = 0.7

11th Edition

ISBN: 9780198769866

Author: ATKINS, P. W. (peter William), De Paula, Julio, Keeler, JAMES

Publisher: Oxford University Press

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Question

Chapter 5, Problem 5C.2BE

Interpretation Introduction

Interpretation: The number, composition and relative amount of phases present at each stage when the mixture is heated at xB=0.3 have to be stated.

Concept introduction: The azeotropic mixture is defined as a mixture of two or more liquids which evaporates without altering the composition of the mixture. The azeotropic mixture has a constant boiling point because of the same composition in liquid as well as vapor phase. The components of azeotropic mixture are not separated by distillation processes.

The phase diagram represents the changes in the mixture on changing the conditions like temperature and pressure of the mixture.

Expert Solution & Answer

Chapter 5 Solutions

Atkins' Physical Chemistry

Ch. 5 - Prob. 5A.1ST Ch. 5 - Prob. 5A.2ST Ch. 5 - Prob. 5A.3ST Ch. 5 - Prob. 5A.4ST Ch. 5 - Prob. 5B.2ST Ch. 5 - Prob. 5C.2ST Ch. 5 - Prob. 5F.1ST Ch. 5 - Prob. 5A.1DQ Ch. 5 - Prob. 5A.2DQ Ch. 5 - Prob. 5A.3DQ

Ch. 5 - Prob. 5A.4DQ Ch. 5 - Prob. 5A.5DQ Ch. 5 - Prob. 5A.1AE Ch. 5 - Prob. 5A.1BE Ch. 5 - Prob. 5A.2AE Ch. 5 - Prob. 5A.2BE Ch. 5 - Prob. 5A.3AE Ch. 5 - Prob. 5A.3BE Ch. 5 - Prob. 5A.4AE Ch. 5 - Prob. 5A.4BE Ch. 5 - Prob. 5A.5AE Ch. 5 - Prob. 5A.5BE Ch. 5 - Prob. 5A.6AE Ch. 5 - Prob. 5A.6BE Ch. 5 - Prob. 5A.7AE Ch. 5 - Prob. 5A.7BE Ch. 5 - Prob. 5A.8AE Ch. 5 - Prob. 5A.8BE Ch. 5 - Prob. 5A.9AE Ch. 5 - Prob. 5A.9BE Ch. 5 - Prob. 5A.10AE Ch. 5 - Prob. 5A.10BE Ch. 5 - Prob. 5A.11AE Ch. 5 - Prob. 5A.11BE Ch. 5 - Prob. 5A.1P Ch. 5 - Prob. 5A.3P Ch. 5 - Prob. 5A.4P Ch. 5 - Prob. 5A.5P Ch. 5 - Prob. 5A.6P Ch. 5 - Prob. 5A.7P Ch. 5 - Prob. 5B.1DQ Ch. 5 - Prob. 5B.2DQ Ch. 5 - Prob. 5B.3DQ Ch. 5 - Prob. 5B.4DQ Ch. 5 - Prob. 5B.5DQ Ch. 5 - Prob. 5B.6DQ Ch. 5 - Prob. 5B.7DQ Ch. 5 - Prob. 5B.1AE Ch. 5 - Prob. 5B.1BE Ch. 5 - Prob. 5B.2AE Ch. 5 - Prob. 5B.2BE Ch. 5 - Prob. 5B.3AE Ch. 5 - Prob. 5B.3BE Ch. 5 - Prob. 5B.4AE Ch. 5 - Prob. 5B.4BE Ch. 5 - Prob. 5B.5AE Ch. 5 - Prob. 5B.5BE Ch. 5 - Prob. 5B.6AE Ch. 5 - Prob. 5B.6BE Ch. 5 - Prob. 5B.7AE Ch. 5 - Prob. 5B.7BE Ch. 5 - Prob. 5B.8AE Ch. 5 - Prob. 5B.8BE Ch. 5 - Prob. 5B.9AE Ch. 5 - Prob. 5B.9BE Ch. 5 - Prob. 5B.10AE Ch. 5 - Prob. 5B.10BE Ch. 5 - Prob. 5B.11AE Ch. 5 - Prob. 5B.11BE Ch. 5 - Prob. 5B.12AE Ch. 5 - Prob. 5B.12BE Ch. 5 - Prob. 5B.1P Ch. 5 - Prob. 5B.2P Ch. 5 - Prob. 5B.3P Ch. 5 - Prob. 5B.4P Ch. 5 - Prob. 5B.5P Ch. 5 - Prob. 5B.6P Ch. 5 - Prob. 5B.9P Ch. 5 - Prob. 5B.11P Ch. 5 - Prob. 5B.13P Ch. 5 - Prob. 5C.1DQ Ch. 5 - Prob. 5C.2DQ Ch. 5 - Prob. 5C.3DQ Ch. 5 - Prob. 5C.1AE Ch. 5 - Prob. 5C.1BE Ch. 5 - Prob. 5C.2AE Ch. 5 - Prob. 5C.2BE Ch. 5 - Prob. 5C.3AE Ch. 5 - Prob. 5C.3BE Ch. 5 - Prob. 5C.4AE Ch. 5 - Prob. 5C.4BE Ch. 5 - Prob. 5C.1P Ch. 5 - Prob. 5C.2P Ch. 5 - Prob. 5C.3P Ch. 5 - Prob. 5C.4P Ch. 5 - Prob. 5C.5P Ch. 5 - Prob. 5C.6P Ch. 5 - Prob. 5C.7P Ch. 5 - Prob. 5C.8P Ch. 5 - Prob. 5C.9P Ch. 5 - Prob. 5C.10P Ch. 5 - Prob. 5D.1DQ Ch. 5 - Prob. 5D.2DQ Ch. 5 - Prob. 5D.1AE Ch. 5 - Prob. 5D.1BE Ch. 5 - Prob. 5D.2AE Ch. 5 - Prob. 5D.2BE Ch. 5 - Prob. 5D.3AE Ch. 5 - Prob. 5D.3BE Ch. 5 - Prob. 5D.4AE Ch. 5 - Prob. 5D.4BE Ch. 5 - Prob. 5D.5AE Ch. 5 - Prob. 5D.5BE Ch. 5 - Prob. 5D.6AE Ch. 5 - Prob. 5D.1P Ch. 5 - Prob. 5D.2P Ch. 5 - Prob. 5D.3P Ch. 5 - Prob. 5D.4P Ch. 5 - Prob. 5D.5P Ch. 5 - Prob. 5D.6P Ch. 5 - Prob. 5D.7P Ch. 5 - Prob. 5E.1DQ Ch. 5 - Prob. 5E.2DQ Ch. 5 - Prob. 5E.3DQ Ch. 5 - Prob. 5E.4DQ Ch. 5 - Prob. 5E.1AE Ch. 5 - Prob. 5E.1BE Ch. 5 - Prob. 5E.2AE Ch. 5 - Prob. 5E.2BE Ch. 5 - Prob. 5E.3AE Ch. 5 - Prob. 5E.3BE Ch. 5 - Prob. 5E.4AE Ch. 5 - Prob. 5E.4BE Ch. 5 - Prob. 5E.5AE Ch. 5 - Prob. 5E.5BE Ch. 5 - Prob. 5E.1P Ch. 5 - Prob. 5E.2P Ch. 5 - Prob. 5E.3P Ch. 5 - Prob. 5F.1DQ Ch. 5 - Prob. 5F.2DQ Ch. 5 - Prob. 5F.3DQ Ch. 5 - Prob. 5F.4DQ Ch. 5 - Prob. 5F.5DQ Ch. 5 - Prob. 5F.1AE Ch. 5 - Prob. 5F.1BE Ch. 5 - Prob. 5F.2AE Ch. 5 - Prob. 5F.2BE Ch. 5 - Prob. 5F.3AE Ch. 5 - Prob. 5F.3BE Ch. 5 - Prob. 5F.4AE Ch. 5 - Prob. 5F.4BE Ch. 5 - Prob. 5F.5AE Ch. 5 - Prob. 5F.5BE Ch. 5 - Prob. 5F.6AE Ch. 5 - Prob. 5F.6BE Ch. 5 - Prob. 5F.7AE Ch. 5 - Prob. 5F.7BE Ch. 5 - Prob. 5F.8AE Ch. 5 - Prob. 5F.8BE Ch. 5 - Prob. 5F.1P Ch. 5 - Prob. 5F.2P Ch. 5 - Prob. 5F.3P Ch. 5 - Prob. 5F.4P Ch. 5 - Prob. 5.1IA Ch. 5 - Prob. 5.2IA Ch. 5 - Prob. 5.3IA Ch. 5 - Prob. 5.4IA Ch. 5 - Prob. 5.5IA Ch. 5 - Prob. 5.6IA Ch. 5 - Prob. 5.8IA Ch. 5 - Prob. 5.9IA Ch. 5 - Prob. 5.10IA

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