Explanation The required reaction is given below. N H 4 ( N H 2 C O 2 ) ( s ) ⇌ 2 N H 3 ( g ) + C O 2 ( g ) The expression for equilibrium constant for the above reaction can be written as shown below, K c = [ N H 3 ] 2 [ C O 2 ] The change in concentration of any solid substance present in a reaction is always taken to be one. An equilibrium table can be set up as given below. C o m p o s i t i o n ( M ) N H 4 ( N H 2 C O 2 ) N H 3 C O 2 I n i t i a l c o n c e n t r a t i o n − 0 0 C h a n g e i n c o n c e n t r a t i o n − + 2 x + x E q u i l i b r i u m c o n c e n t r a t i o n − 2 x x Now, these values in the fourth row can be inserted in the equilibrium constant expression as shown below. K c = ( 2 x ) 2 ( x ) Given that, at equilibrium 17.4 m g o f C O 2 was present. Therefore, its concentration can be calculated as follows, [ C O 2 ] = M o l e s V o l u m e = 17.4 × 10 − 3 g 44

Chemical Principles: The Quest for Insight

7th Edition

ISBN: 9781464183959

Author: Peter Atkins, Loretta Jones, Leroy Laverman

Publisher: W. H. Freeman

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Chapter 5, Problem 5I.33E

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Interpretation:

The value of Kc for the decomposition of ammonium carbamate into ammonia and carbon dioxide has to be calculated. The reaction is given below.

NH4(NH2CO2)(s)⇌2NH3(g)+CO2(g)

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Chapter 5, Problem 5I.32E

Chapter 5, Problem 5I.34E

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Chemical Principles: The Quest for Insight

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The value of K c for the decomposition of ammonium carbamate into ammonia and carbon dioxide has to be calculated. The reaction is given below. N H 4 ( N H 2 C O 2 ) ( s ) ⇌ 2 N H 3 ( g ) + C O 2 ( g )

Solution Summary: The author explains how the value of K_c for the decomposition of ammonium carbamate into carbon dioxide has to be calculated.

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Interpretation:

The value of Kc for the decomposition of ammonium carbamate into ammonia and carbon dioxide has to be calculated. The reaction is given below.

NH4(NH2CO2)(s)⇌2NH3(g)+CO2(g)

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Chapter 5 Solutions

The value of K c for the decomposition of ammonium carbamate into ammonia and carbon dioxide has to be calculated. The reaction is given below. N H 4 ( N H 2 C O 2 ) ( s ) ⇌ 2 N H 3 ( g ) + C O 2 ( g )

Solution Summary: The author explains how the value of K_c for the decomposition of ammonium carbamate into carbon dioxide has to be calculated.

Videos

Interpretation: The value of Kc for the decomposition of ammonium carbamate into ammonia and carbon dioxide has to be calculated. The reaction is given below. NH4(NH2CO2)(s)⇌2NH3(g)+CO2(g)

Want to see the full answer?

Chapter 5 Solutions

Interpretation:

The value of Kc for the decomposition of ammonium carbamate into ammonia and carbon dioxide has to be calculated. The reaction is given below.

NH4(NH2CO2)(s)⇌2NH3(g)+CO2(g)