Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 6, Problem 6.2PAE
6.2 Unlike XRF, AAS cannot be used for nondestructive testing. Explain why not.
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For the ion Ag^+
1. Write the complete electronic configuration.
2. Give the abbreviated electronic configuration or noble gas core notation
3. Identify the number of unpaired electron.
4. Indicate whether paramagnetic or diamagnetic
5- The cover of the car’s engine is called a hood. The hood is coated with an insulator to reduce thermal conductivity. (Refer to the link Resource 7 & Resource 10).
A- Which element in the periodic table would you recommend using in coating the hood? Explain by defining and applying electronic configuration.
B- Relate your choice of elements for coating the hood to the effective nuclear charge and the shielding effect.
C- What is the relation between ionization energy and elements that are poor conductors of heat? Explain.
7.24 The electron configuration of B is 1s22s2 , 2p1. (a) Ifeach core electron (i.e., the 1s electrons) were totallyeffective in shielding the valence electrons (i.e., the2s and 2p electrons) from the nucleus and the valenceelectrons did not shield one another, what would be theshielding constant (σ) and the effective nuclear charge(Zeff) for the 2s and 2p electrons? (b) In reality, theshielding constants for the 2s and 2p electrons in B areslightly different. They are 2.42 and 2.58, respectively.Calculate Zeff for these electrons, and explain thedifferences from the values you determined in part (a).
Chapter 6 Solutions
Chemistry for Engineering Students
Ch. 6 - describe trace analysis and explain its role in...Ch. 6 - describe waves in terms of frequency, wavelength,...Ch. 6 - Prob. 3COCh. 6 - relate the frequency, wavelength, and amplitude of...Ch. 6 - describe the photoelectric effect by stating what...Ch. 6 - Prob. 6COCh. 6 - • use Planck’s equation to calculate the energy of...Ch. 6 - Prob. 8COCh. 6 - Prob. 9COCh. 6 - • describe similarities and differences between...
Ch. 6 - Prob. 11COCh. 6 - Prob. 12COCh. 6 - • identify an orbital (as 1s, 3p, etc.) from its...Ch. 6 - • list the number of orbitals of each type (1s,...Ch. 6 - • sketch the shapes of s and p orbitals and...Ch. 6 - • rank various orbitals in terms of size and...Ch. 6 - Prob. 17COCh. 6 - Prob. 18COCh. 6 - Prob. 19COCh. 6 - Prob. 20COCh. 6 - Prob. 6.1PAECh. 6 - 6.2 Unlike XRF, AAS cannot be used for...Ch. 6 - Prob. 6.3PAECh. 6 - Prob. 6.4PAECh. 6 - Prob. 6.5PAECh. 6 - Prob. 6.6PAECh. 6 - 6.7 Arrange the following regions of the...Ch. 6 - 6.8 Calculate the wavelength in meters, of...Ch. 6 - 6.9 If a string of decorative lights includes...Ch. 6 - 6.10 Define the term refraction.Ch. 6 - 6.11 Define the term photon.Ch. 6 - 6.12 Find the energy of a photon with each of the...Ch. 6 - 6.13 Place these types of radiation in order of...Ch. 6 - 6.14 For photon with the following energies,...Ch. 6 - Prob. 6.15PAECh. 6 - 6.16 Various optical disk drives rely on laser...Ch. 6 - 6.17 The laser in most supermarket barcode...Ch. 6 - 6.18 Assume that a microwave oven operates at a...Ch. 6 - 6.19 Fill in the blanks below to complete a...Ch. 6 - 6.20 When light with a wavelength of 58.5 nm...Ch. 6 - 6.21 The electron binding energy fur copper metal...Ch. 6 - Prob. 6.22PAECh. 6 - 6.23 Describe how the Bohr model of the atom...Ch. 6 - 6.24 According to the Bohr model of the atom, what...Ch. 6 - 6.25 Define the term ground state.Ch. 6 - 6.26 The figure below depicts the first four...Ch. 6 - 6.27 Refer w the data and energy-Ievel diagram...Ch. 6 - 6.28 A neon atom cmi light at many wavelengths,...Ch. 6 - 6.29 A mercury atom emits light at many...Ch. 6 - 6.30 How did the observation of electron...Ch. 6 - 6.31 Why do we use a wave function to describe...Ch. 6 - 6.32 What are the mathematical origins of quantum...Ch. 6 - Prob. 6.33PAECh. 6 - 6.34 Which of the following represent valid sets...Ch. 6 - 6.35 A particular orbital has n = 4 and l = 2....Ch. 6 - 6.36 Why are there no 2d orbitals?Ch. 6 - 6.34 What is the maximum number of electrons in an...Ch. 6 - 6.38 How many orbitals correspond to each of the...Ch. 6 - Prob. 6.39PAECh. 6 - 6.40 Referring to Figure 6.15, draw a 4p orbitals,...Ch. 6 - 6.41 Consider a 3d orbital. (a) What are the...Ch. 6 - Prob. 6.42PAECh. 6 - 6.43 Define the term spin paired.Ch. 6 - 6.44 On what does the Pauli exclusion principle...Ch. 6 - Prob. 6.45PAECh. 6 - Prob. 6.46PAECh. 6 - 6.47 Depict two ways to place electrons in the 2p...Ch. 6 - 6.48 Write the ground state electron configuration...Ch. 6 - 6.49 Which of these electron configurations are...Ch. 6 - 6.50 From the list of atoms and ions given,...Ch. 6 - Prob. 6.51PAECh. 6 - Prob. 6.52PAECh. 6 - Prob. 6.53PAECh. 6 - Prob. 6.54PAECh. 6 - 6.55 Explain why the s block of the periodic table...Ch. 6 - Prob. 6.56PAECh. 6 - Prob. 6.57PAECh. 6 - Prob. 6.58PAECh. 6 - Prob. 6.59PAECh. 6 - 6.60 Use the electron configurations of the alkali...Ch. 6 - 6.61 Using only a periodic table as a guide,...Ch. 6 - 6.62 Define the term ionization energy....Ch. 6 - 6.63 At which ionization for chlorine would you...Ch. 6 - 6.64 Arrange the following atoms in order of...Ch. 6 - Prob. 6.65PAECh. 6 - 6.66 Which element would you expect to have the...Ch. 6 - Prob. 6.67PAECh. 6 - 6.68 Indicate which species in each pair has the...Ch. 6 - 6.69 Compare the elements Na, B, Al, and C with...Ch. 6 - 6.70 Rank the following in order of decreasing...Ch. 6 - 6.71 Several excited states of the neon atom are...Ch. 6 - 6.72 LED bulbs offer a fairly new lighting...Ch. 6 - 6.73 How much energy could be saved each year by...Ch. 6 - Prob. 6.74PAECh. 6 - Prob. 6.75PAECh. 6 - Prob. 6.76PAECh. 6 - Prob. 6.77PAECh. 6 - Prob. 6.78PAECh. 6 - 6.79 How does the charge of electrons provide some...Ch. 6 - 6.80 Describe how valence electron configurations...Ch. 6 - 6.81 Why is there no element to the immediate...Ch. 6 - 6.82 A particular element has the following values...Ch. 6 - 6.83 The graph below shows the first three...Ch. 6 - 6.84 Which graph correctly depicts the first...Ch. 6 - 6.85 The visible lines in the hydrogen atom...Ch. 6 - 6.86 An excited He+ ion returns to the ground...Ch. 6 - Prob. 6.87PAECh. 6 - Prob. 6.88PAECh. 6 - Prob. 6.89PAECh. 6 - Prob. 6.90PAECh. 6 - 6.91 What is the only noble gas that does not have...Ch. 6 - 6.92 The photoelectric effect can he used to...Ch. 6 - 6.93 A mercury atom is initially in its lowest...Ch. 6 - Prob. 6.94PAECh. 6 - 6.95 A metallic sample is known to be barium,...Ch. 6 - 6.96 When a helium atom absorbs light at 58.44 nm,...Ch. 6 - 6.97 Arrange the members of each of the following...Ch. 6 - 6.98 Arrange the following sets of anions in order...Ch. 6 - 6.99 The photoelectric effect can he used in...Ch. 6 - 6.100 Some spacecraft use ion propulsion engines....Ch. 6 - 6.101 Laser welding is a technique in which a...Ch. 6 - Prob. 6.102PAECh. 6 - 6.103 Atomic absorption spectroscopy is based on...Ch. 6 - 6.104 The red color in fireworks is the result of...Ch. 6 - 6.105 When we say that the existence of atomic...Ch. 6 - 6.106 When Bohr devised his model for the atom,...Ch. 6 - Prob. 6.107PAE
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- Which of the following statements correctly describes the value of the effective nuclear charge. Z, felt by (a) the 2s electron at a large distance from a Li atom? (i) Z equals 1. (ii) Z is between 1 and 3. (iii) Z equals 3. (b) the 2s electron at its most probable distance from the nucleus of a Li atom? (i) Z equals 1. (ii) Z is between 1 and 3. (iii) Z equals 3.arrow_forwardGive the possible values of a. the principal quantum number, b. the angular momentum quantum number, c. the magnetic quantum number, and d. the spin quantum number.arrow_forwardThe second is defined as the time it takes for 9,192,631,770 wavelengths of a certain transition of the cesium-133 atom to pass a fixed point. What is the frequency of this electromagnetic radiation? What is the wavelength?arrow_forward
- What is the physical significance of the value of 2 at a particular point in an atomic orbital?arrow_forward6.86 An excited He+ ion returns to the ground state by emitting a series of three photons, with wavelengths of 26 nm, 469 nm, and 1014 nm. The process is represented in the energy level diagram below. Which arrow (A, B, or C) in the diagram represents the 1014-nm light?arrow_forwardCesium was discovered in natural mineral waters in 1860 by R. W. Bunsen and G. R. Kirchhoff, using the spectroscope they invented in 1859. The name came from the Latin caesius ("sky blue") because of the prominent blue line observed for this element at 455.5 nm. Calculate the frequency and energy of a photon of this light.arrow_forward
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- Silver and rubidium both form +1 ions, but silver is far lessreactive. Suggest an explanation, taking into account theground-state electron configurations of these elements andtheir atomic radii.arrow_forwardwhy is ionisation energy of 5d transition series higher than 3d and 4d?arrow_forwardElectron Configuration and Periodic Trend Properties Suppose you were trying to find a substitute for K+ in nerve signal transmission. where would you begin your search? In this regard, you should answer the following questions. However, if you need to review the topic, you can go over Electron Configuration and Periodic Trend in Atomic Radius, Ionization Energy and Metallic Character in Chapter 9. 1) What ion be most like K+? 2) For each ion you propose, explain the ways it would be similar to K+ and the ways it would be different. You should refer to periodic table in your discussion. Now in the second part of discussion, we will go over the electron configuration of another cation, and you will discuss the answer to the following question as a part of your discussion. 3) Write the electron configuration of six cations that form from sulfur by loss of one to six electrons. 4) For those cations that have unpaired electrons, write orbital diagram. In the third part of…arrow_forward
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