(a)
To determine: The reaction rate if the concentration of ethyl bromide is doubled.
Interpretation: If the concentration of ethyl bromide is doubled, then its effect on reaction rate is to be stated.
Concept introduction:
(b)
To determine: The reaction rate if the concentration of ethyl bromide is doubled and the concentration of potassium tert-butoxide is tripled.
Interpretation: If the concentration of ethyl bromide is doubled and the concentration of potassium tert-butoxide is tripled, then its effect on reaction rate is to be stated.
Concept introduction:
(c)
To determine: The effect of temperature increase on reaction rate.
Interpretation: The effect of temperature increase on reaction rate is to be stated.
Concept introduction:
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Chapter 6 Solutions
ORGANIC CHEMISTRY MASTERINGCHEM ACCESS
- Which reagent(s) are used in the following reaction? 1. Hg(OAc), HO 2. NaBH₁ 1. BH 2. HO, OH Ch HO HO H₂SO4 NaNH, کی سسکے -OH and OHarrow_forward4. A CHEM 245 student wants to synthesize some ethylene glycol to use as antifreeze in his radiator this winter. He proposes the following reaction to his instructor, who quickly explains that this reaction won't work as proposed due to the student's choice of reagent. 1) NaH 2) H20 OH Но a) Why can't sodium hydride (NaH) be used as the nucleophile in the reaction above? b) Propose an alternate reagent that COULD be used with the ethylene oxide to successfully give the desired ethylene glycol product.arrow_forward32. Which of the following reactions can be used to prepare 3-methyl-3-hexanol, OH I CH3CH2CCH2CH2CH3 ? 1 CH 3 A. B. CH3CH2CCH2CH2CH3 i CH3CCH2CH2CH3 i CH3CCH2CH3 1. CH3MgBr 2. H30 C. D. A and B E. A, B, and C 1. CH3CH2MgBr 2. H30 1. CH3CH2CH2MgBr 2. H30 33. Complete the following reaction sequence by supplying the missing information: (1) (2) 4. ? CH3OH (3) CH3Br CH3CH2OH 5. ? A. (1) NaBr; (2) Mg/ether; (3) CH3MgBr; (4) H2C=0; (5) H2O B. (1) HBr; (2) Mg/ether; (3) CH3MgBr; (4) H2C=0; (5) H2O c. (1) Br2; (2) Mg/ether; (3) CH3MgBr; (4) H2C=O; (5) H2O D. (1) HBr; (2) CH3MgBr; (3) Mg/ether; (4) H2C=O; (5) H2Oarrow_forward
- 5. Write the products for the following two reactions of pheno 1. NaOH 2. СН,CH Br HO 1. (CF,CO2) Hg /H2C-CH2 2. NaBH4arrow_forwardPick the reactant or solvent in each part that gives the faster elimination reaction.a. reaction of -OH with 1-chloro-1-methylcyclohexane or 1-chloro-3-methylcyclohexaneb. reaction of H2O with CH3CH(Cl)CH2CH3 or (CH3)2C(Cl)CH2CH3c. reaction of (CH3)3CCl with -OH in H2O or DMSOarrow_forwardComplete the following reactions by filling in any missing reactants, reagents or products. a) Zn(Hg) conc. HCl b) ОН ? с) ОН РСС CH,Cl,arrow_forward
- 7. What is the major organic product obtained from the following reaction? 1/20₂ SHarrow_forward1c. What is the nucleophile in the following reaction? .Br CH;CO0 Na LO OCCH3 NaBr ld. What is the electrophile in the following reaction? Br CH;COO Na L0OCCH3 NaBr +arrow_forward7. What is the major organic product obtained from the following reaction? Hg(OAc)2 H₂Oarrow_forward
- Complete the following reaction sequence with the missing major organic products. CH, NaOH CH,CH,CH,CHCH,CHCH,CEN H20 NaOH H,0 CH,CH,arrow_forwardPredict the major products of the reaction of acetone with each of the following reagents: a. C2H3OH + H+ , Δ b. Zn (Hg) + conc. HCl, heat c. HCNarrow_forwardPick the reagent of the following reaction. CH COOH 1. SOCI2 2. NH3 1. SOCI2 2. heat 1. CH3NH2 2. heat O 1. SOCI2 2. CH3CH2NH2 CH₂CONHCH,arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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