EBK CHEMISTRY
8th Edition
ISBN: 9780135216972
Author: Robinson
Publisher: PEARSON CO
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Textbook Question
Chapter 6, Problem 6.64SP
The first four ionization energies in kJ/mol of a certain secondrow element are 801, 2427, 3660, and 25,025. What is thelikely identity of the element?
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Consider an ionic compound, MX,, composed of generic metal M and generic, gaseous halogen X.
• The enthalpy of formation of MX, is AH;
-909 kJ/mol.
• The enthalpy of sublimation of M is AHsub = 143 kJ/mol.
• The first and second ionization energies of M are IE1
:759 kJ/mol and IE2 = 1407 kJ/mol.
• The electron affinity of X is AHEA = -339 kJ/mol. (Refer to the hint).
• The bond energy of X, is BE = 177 kJ/mol.
Determine the lattice energy of MX,.
ΔΗ,
kJ/mol
lattice
* TOOLS
х10
2
Consider an ionic compound, MX,, composed of generic metal M and generic gaseous halogen X.
• The enthalpy of formation of MX, is AH;
= -691 kJ/mol.
• The enthalpy of sublimation of M is AHsub = 141 kJ/mol.
• The first, second, and third ionization energies of M are IE1
= 689 kJ/mol, IE2
= 1583 kJ/mol, and IE3
= 2651 kJ/mol.
• The electron affinity of X is AHEA
= -347 kJ/mol. (Refer to the hint).
• The bond energy of X, is BE = 201 kJ/mol.
Determine the lattice energy of MX3.
AHjattice =
-2388
kJ/mol
Incorrect
Chapter 6 Solutions
EBK CHEMISTRY
Ch. 6 - Prob. 6.1PCh. 6 - APPLY 6.2 Which of the following sets of ions are...Ch. 6 - Which atom or ion has the largest radius:...Ch. 6 - Conceptual APPLY 6.4 Which of the following...Ch. 6 - Use the periodic table to order the elements from...Ch. 6 - Given the orbital filling diagrams for the valence...Ch. 6 - Which has the largest third ionization energy: Be,...Ch. 6 - Conceptual APPLY 6.8 The figure on the right...Ch. 6 - Order the following elements from least to most...Ch. 6 - Conceptual APPLY 6.10 Which of the indicated three...
Ch. 6 - What electron configuration does the strontium...Ch. 6 - Prob. 6.12ACh. 6 - Prob. 6.13PCh. 6 - APPLY 6.14 Calculate the energy of electrostatic...Ch. 6 - Which substance has the largest lattice energy:...Ch. 6 - One of the following pictures represents NaCl and...Ch. 6 - Prob. 6.17PCh. 6 - What structural features do ionic liquids havethat...Ch. 6 - PROBLEM 6.18 Compare the following two ionic...Ch. 6 - PROBLEM 6.19 An ionic liquid consisting of a bulky...Ch. 6 - Where on the periodic table would you find the...Ch. 6 - Which of the following spheres is likely to...Ch. 6 - Circle the approximate part or parts of the...Ch. 6 - Prob. 6.24CPCh. 6 - This figure represents the successive ionization...Ch. 6 - In the following drawings, red spheres represent...Ch. 6 - Which of the following drawings is more likely to...Ch. 6 - Prob. 6.28CPCh. 6 - Which of the following alkali metal halides has...Ch. 6 - Which of the following alkali metal halides has...Ch. 6 - Three binary compounds are represented on the...Ch. 6 - Prob. 6.32CPCh. 6 - Prob. 6.33CPCh. 6 - What is the difference between a covalent bond and...Ch. 6 - Prob. 6.35SPCh. 6 - What is the difference between a molecule and an...Ch. 6 - Prob. 6.37SPCh. 6 - How many protons and electrons are in each of the...Ch. 6 - What is the identity of the element X in the...Ch. 6 - Prob. 6.40SPCh. 6 - Prob. 6.41SPCh. 6 - Prob. 6.42SPCh. 6 - Prob. 6.43SPCh. 6 - What doubly positive ion has the following...Ch. 6 - Prob. 6.45SPCh. 6 - Prob. 6.46SPCh. 6 - Which element in the transition-metal series Sc...Ch. 6 - Prob. 6.48SPCh. 6 - Prob. 6.49SPCh. 6 - Order the following ions from smallest to largest:...Ch. 6 - Order the following ions from smallest to largest:...Ch. 6 - Which ion has a larger atomic radius, Cu+ or Cu2+...Ch. 6 - Which ion hasa larger atomic radius, Fe2+ or Fe3+...Ch. 6 - The following ions all have the same number of...Ch. 6 - Which of the ions Se2,F,O2 and Rb+ has the largest...Ch. 6 - Which group of elements in the periodic table has...Ch. 6 - Prob. 6.57SPCh. 6 - Which element in each of the following sets has...Ch. 6 - Order the elements in each set from the smallest...Ch. 6 - (a) Which has the smaller second ionization...Ch. 6 - (a) Which has the smaller fourth ionization...Ch. 6 - Three atoms have the following electron...Ch. 6 - Three atoms have the following electron...Ch. 6 - The first four ionization energies in kJ/mol of a...Ch. 6 - The first four ionization energies in kJ/mol of a...Ch. 6 - Prob. 6.66SPCh. 6 - Prob. 6.67SPCh. 6 - Prob. 6.68SPCh. 6 - Prob. 6.69SPCh. 6 - Why is energy usually released when an electron is...Ch. 6 - Why does ionization energy increase regularly...Ch. 6 - No element has a negative second electron...Ch. 6 - Why does phosphorus have a less negative electron...Ch. 6 - Prob. 6.74SPCh. 6 - What noble-gas configurations and charge are the...Ch. 6 - Each of the following pairs of elements will react...Ch. 6 - Each of the following pairs of elements will react...Ch. 6 - Element X reacts with element Y to give a product...Ch. 6 - Element X reacts with element Y to give a product...Ch. 6 - Calculate the energy change in kilojoules per mole...Ch. 6 - Prob. 6.81SPCh. 6 - Find the lattice energy of LiBr(s) in Table 6.3,...Ch. 6 - Look up the lattice energies in Table 6.3, and...Ch. 6 - Born-4-Iaber cycles, such as those shown in...Ch. 6 - Calculate a lattice energy for CaH2(s) in...Ch. 6 - Calculate the overall energy change in kilojoules...Ch. 6 - The estimated lattice energy for CsF2(s) is +2347...Ch. 6 - Calculate the overall energy change in kilojoules...Ch. 6 - Use the data in Problem 6.88 to calculate an...Ch. 6 - Use the data and the result in Problem 6.84 to...Ch. 6 - Prob. 6.91SPCh. 6 - Calculate overall energy changes in kilojoules per...Ch. 6 - Prob. 6.93SPCh. 6 - We saw in Section 6.7 that the reaction of solid...Ch. 6 - Draw a Born—Haber cycle for the reaction of sodium...Ch. 6 - Use the following information plus the data given...Ch. 6 - Prob. 6.97SPCh. 6 - Prob. 6.98SPCh. 6 - Order the following compounds according to their...Ch. 6 - Prob. 6.100MPCh. 6 - Heating elemental cesium and platinum together for...Ch. 6 - Given the following information, construct a...Ch. 6 - Consider the electronic structure of the element...Ch. 6 - Prob. 6.104MPCh. 6 - The ionization energy of an atom can be measured...
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- The lattice energy of an ionic solid such as NaCl is the enthalpy change H for the process in which the solid changes to ions. For example, NaCl(s)Na+(g)+Cl(g)H=786kJ/mol Assume that the ionization energy and electron a affinity are H values for the processes defined by those terms. The ionization energy of Na is 496 kJ/mol. Use this, the electron affinity from Table 8.4, and the lattice energy of NaCl to calculate H for the following process: Na(g)+Cl(g)NaCl(s)arrow_forwardrite the proper charges so that an alkali metal, a noble gas, and a halogen have the same electron configurations. What is the number of protons in each“? The number of electrons in each? Arrange them from smallest to largest radii and explain your ordering rationale.arrow_forwardMat type of bond is likely to form between one element with low ionization energy and another element with high electron affinity? Explain your answer.arrow_forward
- Consider an ionic compound, MX,, composed of generic metal M and generic gaseous halogen X. • The enthalpy of formation of MX, is AH; = -747 kJ/mol. • The enthalpy of sublimation of M is AHsub = 149 kJ/mol. • The first, second, and third ionization energies of M are IE = 589 kJ/mol, IE2 = 1653 kJ/mol, and IE3 = 2509 kJ/mol. • The electron affinity of X is AHEA = -335 kJ/mol. (Refer to the hint). • The bond energy of X, is BE = 191 kJ/mol. Determine the lattice energy of MX,. kJ/mol AHjattice privacy policy terms of use contact us help about us careers DELLarrow_forwardConsider an ionic compound, MX,, composed of generic metal M and generic gaseous halogen X. • The enthalpy of formation of MX, is AH; = -921 kJ/mol. • The enthalpy of sublimation of M is AHsub = 161 kJ/mol. • The first, second, and third ionization energies of M are IE1 = 619 kJ/mol, IE2 = 1717 kJ/mol, and IE3 = 2719 kJ/mol. • The electron affinity of X is AHEA = -367 kJ/mol. (Refer to the hint). • The bond energy of X, is BE = 191 kJ/mol. Determine the lattice energy of MX,. ΔΗlattice kJ/mol * TOOLS x10arrow_forwardConsider an ionic compound, MX₂, composed of generic metal M and generic, gaseous halogen X. • The enthalpy of formation of MX₂ is AH; = -905 kJ/mol. • The enthalpy of sublimation of M is AHsub = 111 kJ/mol. • The first and second ionization energies of M are IE₁ = 627 kJ/mol and IE₂ = 1362 kJ/mol. • The electron affinity of X is AHEA = -313 kJ/mol. (Refer to the hint). • The bond energy of X₂ is BE = 165 kJ/mol. Determine the lattice energy of MX₂. AH lattice = kJ/molarrow_forward
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