Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198727873
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 6, Problem 6C.11E
Interpretation Introduction

Interpretation:

The time required for the concentration of A to change from 0.460mol/dm3 to0.466mol/dm3 has to be calculated.

Concept Introduction:

The exponent of every reactant can be experimentally determined by the rate law that is called as order of reactant for that reactant.

The overall order of the reaction will be equal to the total orders of the reactant species in the rate law.  If the overall order of the reaction is three, the reaction is third order overall.

Integrated rate law for second order reactions:

Taking in the example of following reaction,

    aAproducts

And the reaction follows second order rate law,

Then the relationship between the concentration of A and time can be mathematically expressed as,

    1[A]t=kt+1[A]0

The above expression is called as integrated rate for second order reactions.

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Chapter 6 Solutions

Elements Of Physical Chemistry

Ch. 6 - Prob. 6C.4STCh. 6 - Prob. 6D.1STCh. 6 - Prob. 6D.2STCh. 6 - Prob. 6D.3STCh. 6 - Prob. 6E.1STCh. 6 - Prob. 6E.2STCh. 6 - Prob. 6F.1STCh. 6 - Prob. 6F.2STCh. 6 - Prob. 6G.1STCh. 6 - Prob. 6G.2STCh. 6 - Prob. 6G.3STCh. 6 - Prob. 6H.1STCh. 6 - Prob. 6I.1STCh. 6 - Prob. 6I.2STCh. 6 - Prob. 6A.1ECh. 6 - Prob. 6A.2ECh. 6 - Prob. 6A.3ECh. 6 - Prob. 6B.1ECh. 6 - Prob. 6B.2ECh. 6 - Prob. 6B.3ECh. 6 - Prob. 6B.4ECh. 6 - Prob. 6B.5ECh. 6 - Prob. 6C.1ECh. 6 - Prob. 6C.2ECh. 6 - Prob. 6C.3ECh. 6 - Prob. 6C.4ECh. 6 - Prob. 6C.5ECh. 6 - Prob. 6C.6ECh. 6 - Prob. 6C.7ECh. 6 - Prob. 6C.8ECh. 6 - Prob. 6C.9ECh. 6 - Prob. 6C.10ECh. 6 - Prob. 6C.11ECh. 6 - Prob. 6C.12ECh. 6 - Prob. 6D.1ECh. 6 - Prob. 6D.2ECh. 6 - Prob. 6D.3ECh. 6 - Prob. 6D.4ECh. 6 - Prob. 6D.5ECh. 6 - Prob. 6D.6ECh. 6 - Prob. 6D.7ECh. 6 - Prob. 6D.8ECh. 6 - Prob. 6D.9ECh. 6 - Prob. 6D.10ECh. 6 - Prob. 6D.11ECh. 6 - Prob. 6E.1ECh. 6 - Prob. 6E.2ECh. 6 - Prob. 6E.3ECh. 6 - Prob. 6F.1ECh. 6 - Prob. 6F.2ECh. 6 - Prob. 6F.3ECh. 6 - Prob. 6G.1ECh. 6 - Prob. 6G.2ECh. 6 - Prob. 6G.3ECh. 6 - Prob. 6G.5ECh. 6 - Prob. 6H.1ECh. 6 - Prob. 6H.2ECh. 6 - Prob. 6H.3ECh. 6 - Prob. 6H.4ECh. 6 - Prob. 6I.1ECh. 6 - Prob. 6I.2ECh. 6 - Prob. 6I.3ECh. 6 - Prob. 6.1DQCh. 6 - Prob. 6.2DQCh. 6 - Prob. 6.3DQCh. 6 - Prob. 6.4DQCh. 6 - Prob. 6.5DQCh. 6 - Prob. 6.6DQCh. 6 - Prob. 6.7DQCh. 6 - Prob. 6.8DQCh. 6 - Prob. 6.9DQCh. 6 - Prob. 6.10DQCh. 6 - Prob. 6.11DQCh. 6 - Prob. 6.12DQCh. 6 - Prob. 6.13DQCh. 6 - Prob. 6.14DQCh. 6 - Prob. 6.1PCh. 6 - Prob. 6.2PCh. 6 - Prob. 6.3PCh. 6 - Prob. 6.4PCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.6PCh. 6 - Prob. 6.9PCh. 6 - Prob. 6.10PCh. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Prob. 6.13PCh. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Prob. 6.17PCh. 6 - Prob. 6.19PCh. 6 - Prob. 6.20PCh. 6 - Prob. 6.21PCh. 6 - Prob. 6.22PCh. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - Prob. 6.29PCh. 6 - Prob. 6.30P
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