General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)
11th Edition
ISBN: 9780134097329
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Textbook Question
Chapter 6, Problem 83E
What are the ratios of rates for the pairs of gases (a) N2 and O2; (b) H2O and D2O (D = deuterium, i.e., 2H); (C) 14CO2 and 12CO2; (d) UFa and UFa?
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Nitric oxide reacts with hydrogen to release large amounts of chemiluminescence with the
characteristics of the highly cytotoxic species. The following data were measured for the
reaction of nitric oxide with hydrogen:
Data number
1
2
3
2 NO(g) + 2 H₂(g) → N₂(g) + 2 H₂O(g)
[NO] (M)
0.1
0.1
0.2
[H₂] (M)
0.1
0.2
0.1
Based on the data,
(a) Determine the rate law for this reaction.
(b) Calculate the rate constant.
(c) Calculate the rate when [NO] = 0.050 M and [H₂] = 0.150 M
Initial rate (M/S)
1.23 x 10-³
2.46 x 10-³
4.92 x 10-³
Can you please answer these sub questions 12.98 and 12.100 sub problem and show all of the steps to the solution
1a) The decomposition of ethanol at some constant temperature (above 500°C), over a copper surface,
C2H5OH(g)--> CH3CHO(g) + H2(g)
was studied by monitoring the total pressure with time.The following data were obtained:
t (s)
Ptotal (torr)
0
120
45
131
139
154
233
177
376
212
380
213
What will be the total pressure at t = 462 s?
1b) What is the rate constant (k)?(Include appropriate units.)
Chapter 6 Solutions
General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)
Ch. 6 - Convert each pressure to an equivalent pressure in...Ch. 6 - Prob. 2ECh. 6 - Calculate the height of a column of liquid benzene...Ch. 6 - Prob. 4ECh. 6 - Prob. 5ECh. 6 - What is the pressure (in mmHg) of the gas...Ch. 6 - At times, a pressure is stated in units of mass...Ch. 6 - Prob. 8ECh. 6 - A sample of O2(g) has a volume of 26.7 L at 762...Ch. 6 - An 886 mL sample of Ne(g) is at 752 mmHg 26 C....
Ch. 6 - Prob. 11ECh. 6 - We want to change the volume of a fixed amount of...Ch. 6 - Prob. 13ECh. 6 - A sample of N2(g) occupies a volume of 42.0 ml...Ch. 6 - Prob. 15ECh. 6 - Prob. 16ECh. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Prob. 19ECh. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - Prob. 22ECh. 6 - A sample of gas has a volume of 4.25 L at 25.6 C...Ch. 6 - A 10.0 sample of a gas has a volume of 5.25 L at...Ch. 6 - Prob. 25ECh. 6 - Prob. 26ECh. 6 - What is the volume, in liters, occupied by 89.2 g...Ch. 6 - Prob. 28ECh. 6 - Kr(g) in a 18.5 L cylinder exerts a pressure of...Ch. 6 - Prob. 30ECh. 6 - A laboratory high vacuum system is capable of...Ch. 6 - What is the pressure, in pascals, exerted by 1242...Ch. 6 - What is the molar volume of an ideal gas at (a) 25...Ch. 6 - Prob. 34ECh. 6 - A 0.418 g sample of gas has a volume of 115 mL at...Ch. 6 - What is the molar mass of a gas found to have a...Ch. 6 - Whatis the molecular formula of a gaseous fluoride...Ch. 6 - A 2.650 g sample of a gaseous compound occupies...Ch. 6 - A gaseous hydrocarbon webbing 0.231 g occupies a...Ch. 6 - Prob. 40ECh. 6 - Prob. 41ECh. 6 - Monochloroethylene gas is used to make...Ch. 6 - In order for a gas-filled balloon to rise in air,...Ch. 6 - Prob. 44ECh. 6 - The density of phosphorus vapor is 2.64 g/L at 310...Ch. 6 - A particular gaseous hydrocarbon that is 82.7% C...Ch. 6 - Prob. 47ECh. 6 - Prob. 48ECh. 6 - Prob. 49ECh. 6 - Prob. 50ECh. 6 - Prob. 51ECh. 6 - Hydrogen peroxide, H2O2, is used to disinfect...Ch. 6 - Calculate the volume of H2(g), measured at 26 C...Ch. 6 - The Haber process is the principal method for...Ch. 6 - What is the volume. in liters, occupied by a...Ch. 6 - Prob. 56ECh. 6 - A gas cylinder of 53.7 L volume contains N2(g) at...Ch. 6 - Prob. 58ECh. 6 - Which actions you take to establish a pressure of...Ch. 6 - Prob. 60ECh. 6 - Prob. 61ECh. 6 - The chemical composition of air that is exhaled...Ch. 6 - In the drawing below, 1.00 g H2(g) is maintained...Ch. 6 - In the drawing above, 1.00 g H2(g) at 300 K is...Ch. 6 - Prob. 65ECh. 6 - Prob. 66ECh. 6 - A 1.65 g sample of Al reacts with excess HCI, and...Ch. 6 - An 89.3 mL sample of wet O2(g) is collected over...Ch. 6 - A sampleof O2(g) is collected over water at 24 C....Ch. 6 - Prob. 70ECh. 6 - At elevated temperatures, solid sodium chlorate...Ch. 6 - Prob. 72ECh. 6 - CalculateUnta,in meters per second, for CI2(g)...Ch. 6 - Prob. 74ECh. 6 - Prob. 75ECh. 6 - Prob. 76ECh. 6 - Prob. 77ECh. 6 - Determine um, u, and Urmafor a group often...Ch. 6 - Prob. 79ECh. 6 - Prob. 80ECh. 6 - If 0.00484 mol N2O(g) effuses through an orifice...Ch. 6 - Prob. 82ECh. 6 - What are the ratios of rates for the pairs of...Ch. 6 - Prob. 84ECh. 6 - Prob. 85ECh. 6 - The molar mass of radon gas was first estimated by...Ch. 6 - Prob. 87ECh. 6 - Use both the deal gas equation and the van der...Ch. 6 - Prob. 89ECh. 6 - (a) Use the value of the van der Waals constant b...Ch. 6 - Prob. 91IAECh. 6 - Assume the following initial conditions for the...Ch. 6 - Consider the diagram to the right. The "initial"...Ch. 6 - Two evacuated bubs of equal volume are connected...Ch. 6 - Prob. 95IAECh. 6 - A 0.7178 g sample of a hydrocarbon occupies a...Ch. 6 - Prob. 97IAECh. 6 - Ammonium nitrite, NH4NO2,decomposes according to...Ch. 6 - A mature of 100 g H2 and 860 g O2, introduced into...Ch. 6 - Prob. 100IAECh. 6 - What is the partial pressure of CI2(g) , in...Ch. 6 - Prob. 102IAECh. 6 - When working with a mixture of gases, it is...Ch. 6 - Prob. 104IAECh. 6 - Gas cylinder A has e volume of 48.2 L and contains...Ch. 6 - Prob. 106IAECh. 6 - Producer gas is a type of fuel gas made by passing...Ch. 6 - Prob. 108IAECh. 6 - A mixture of H2(g) and O2(g) is prepared by...Ch. 6 - Prob. 110IAECh. 6 - Prob. 111IAECh. 6 - A breathing mixture is prepared which He is...Ch. 6 - Chlorine dioxide,CIO2, is sometimes used as a...Ch. 6 - The amount of ozone, O2,in a mixture of gases can...Ch. 6 - Prob. 115IAECh. 6 - Prob. 116IAECh. 6 - We have noted that atmospheric pressure depends on...Ch. 6 - Consider a sample ofO2(g) at 298 K and 1.0 atm....Ch. 6 - A nitrogen molecule (N2) having the average...Ch. 6 - Prob. 120IAECh. 6 - Prob. 121IAECh. 6 - Prob. 122IAECh. 6 - Prob. 123IAECh. 6 - A 0.156 g sample of magnesium-aluminum alloy...Ch. 6 - Prob. 125FPCh. 6 - Prob. 126FPCh. 6 - Prob. 127FPCh. 6 - Prob. 128FPCh. 6 - Prob. 129FPCh. 6 - Prob. 130SAECh. 6 - Briefly describe each concept or process: (a)...Ch. 6 - Prob. 132SAECh. 6 - Which exerts the greatest pressure. (a) a 75.0 cm...Ch. 6 - Prob. 134SAECh. 6 - Prob. 135SAECh. 6 - A fragile glass vessel will break if the internal...Ch. 6 - Which of the following choices represents the...Ch. 6 - The gas with the greatest density at STP is (a)...Ch. 6 - Precisely 1mol of helium and 1 mol of neon are...Ch. 6 - Prob. 140SAECh. 6 - Prob. 141SAECh. 6 - Prob. 142SAECh. 6 - Prob. 143SAECh. 6 - At 0 C and 0.500 atm, 4.48 L of gaseous NH2(a)...Ch. 6 - To establish a pressure of 2.00 atm in a 2.24 L...Ch. 6 - Carbon monoxide, CO, and hydrogenreact according...Ch. 6 - A mixture of 5.010-5molH2(g) and 5.010-5molSO2(g)...Ch. 6 - Prob. 148SAECh. 6 - Prob. 149SAECh. 6 - Prob. 150SAECh. 6 - A gaseous hydrocarbon that is 82.7% C and 17.3% H...Ch. 6 - Draw a box to represent a sample of air containing...Ch. 6 - Prob. 153SAE
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