EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 9781260475685
Author: SMITH
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 6.4, Problem 8P
Interpretation Introduction

(a)

Interpretation: The ΔH° value for the given oxidation reaction is to be calculated.

Concept introduction: The chemical reactions in which energy is released during the formation of products are known as exothermic reactions. The energy released during the reaction is denoted by ΔH°. Exothermic and endothermic reactions are opposite to each other. The value of ΔH° for exothermic and endothermic reactions is positive and negative respectively.

Interpretation Introduction

(b)

Interpretation: The ΔH° value for the given oxidation reaction is to be calculated.

Concept introduction: The chemical reactions in which energy is released during the formation of products known as exothermic reactions. The energy released during the reaction is denoted by ΔH°. Exothermic and endothermic reactions are opposite to each other. The value of ΔH° for exothermic and endothermic reactions is positive and negative respectively.

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Consider the following reaction:2CH3OH(g)→2 CH4(g) + O2(g) H=+252.8 kJ a. Is this reaction exothermic or endothermic? Explain briefly. b. Calculate the amount of heat transferred when 24.0 g of CH3OH(g) is decomposed by this reaction at constant pressure c. For a given sample of CH3OH, the enthalpy change during the reaction is 82.1 kJ. How many grams of methane, CH4, are produced? d. How many kilojoules of heat are released when 38.5 g of CH4 (g) reacts completely with O2 (g) to form CH3OH( g) at constant pressure?
22. Given that the enthalpy of neutralization for the reaction of HCl (a strong acid) and NaOH (a strong base) is always -55.90 kJ per mole of H2O formed, what is the concentration of a 65 mL sample of HCl if the enthalpy of neutralization for the reaction was found to be -5.38 kJ, assuming no heat is lost to the calorimeter?       0.96 M     1.48 M     1.60 M     0.38 M     4.63 M
Given the listed average bond energies (BE), calculate the enthalpy change for the production of one mole of methanol (CH3OH) by the following reaction. (There are two C=O double bonds in CO2) CO2(g) + 3 H2(g) → CH3OH(g) + H2O(g) B.E.C–O = 300 kJ/mol  B.E.C=O = 700 kJ/mol  B.E.H–H = 450 kJ/mol  B.E.H–O = 500 kJ/mol  B.E.H–C = 400 kJ/mol Select one: a. 250 kJ b. 950 kJ c. -250 kJ d. 50 kJ e. -950 kJ

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EBK ORGANIC CHEMISTRY

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