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Rank the species in each group in order of increasing nucleophilicity.
a.
b.
c.
d.
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Chapter 7 Solutions
ORGANIC CHEMISTRY
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- b. d. a. a 6. Draw the organic product formed for each reaction. COOH COOH A [1] LDA [2] CH3CH₂l [1] Br₂. CH3CO₂H [2] Li₂CO3. LiBr. DMF 12 (excess) TOH CN NaH Br₂ (excess) TOH + CHI3arrow_forward76% 4. Classify each structure below as a nucleophile or electrophile (or both) and briefly explain your choice. a. N31- (the azide ion) C. phenol b. H3O+ (the hydronium ion)arrow_forwardCreate product III a. H 1. PhCH2 PPh3/ NaOH 2. H3O+arrow_forward
- Determine which reactions would occur (substitution, elimination, both, or neither). CH;CH,OH a. SN1 O b. E1 C. SN1 & E1 O d. SN2 е. Е2 O f. SN2 & E2 g. No reactionarrow_forward4. Which is the major product of this reaction? а. b. C. OH d. 1. FeCl3, CI 2. Hа/Pdarrow_forwardDoes the equilibrium favor the reactants or products in each substitution reaction? a. CH;CH2-NH2 Br CH;CH2-Br + "NH2 b. "CN CN + I-arrow_forward
- Select the correct reaction. O a. O b. ос Od. o e. 1. LAH OH OH OH OH OH OH 2. PCC 3. CH3CH2Li 4. H3O+ 1. SOCI₂ 2. (CH3CH2)2CuLi 3. H3O+ 1. CH3CH2OH, HA 2. CH3CH2MgBr 3. H3O+ 1. CH3CH2NH2, DCC 2. LAH 1. SOCI₂ 2. CH3CH2Li 3. H3O+ OH of OH of OHarrow_forwardWhat is product D? HNO3 so, Cl2 1. Zn/HCI A B H,SO4 H,SO4 FeCl3 2. NaOH CI HO,S NO2 CI `NH2 CI HO;S NH2 CI HO3S. `NH2arrow_forwardWhat is the major product of this Michael reaction? A. B. O B D 1. NaOH 3. H3O+ 27 D. O ?arrow_forward
- What is/are the major product(s) of this reaction se 1. ВНЗ 2. H2O2, NaOH 3. PBR3 4. (CH3)3COK/(CH3)3COH +1arrow_forwardDraw the organic product(s) formed when CH3CH2CH2OH is treated with each reagent. a.H2SO4 b.NaH c.HCl + ZnCl2 d.HBr e.SOCl2, pyridine f.PBr3 g.TsCl, pyridine h. [1] NaH; [2] CH3CH2Br [1] i.TsCl, pyridine; [2] NaSH j.POCl3, pyridinearrow_forwardWhy does bromination reactions occur only on more stable radicals? O a. Br₂ is less reactive than Cl₂. O b. Br₂ is more reactive than Cl₂. O c. Br₂ is less selective than Cl₂. O d. Both a and c.arrow_forward
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