Organic Chemistry
Organic Chemistry
4th Edition
ISBN: 9780077479824
Author: SMITH, Janice Gorzynski/
Publisher: McGraw-Hill College
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Chapter 7, Problem 7.61P
Interpretation Introduction

(a)

Interpretation:

To classify each carbocation as 1°, 2°, or 3°.

Concept introduction:

SN2 reaction is a special type of reaction mechanism in organic chemistry. It is kind of nucleophilic substitution reaction. Nucleophilic substitutions are Lewis acid-base reactions. In this reaction the nucleophile donates its electron pair, the alkyl halide (Lewis acid) accepts it, and the C-X bond is heterolytically cleaved. Alkyl halides are organic molecules that contains a halogen atom X bonded to sp3 hybridized carbon atom. Alkyl halides are classified as primary (1°), secondary (2°), and tertiary (3°) depending on the number of carbons bonded to the carbon with the halogen. In this reaction carbocation cannot form because it is an intermediate formed in the SN1 reaction.

Interpretation Introduction

(b)

Interpretation:

To classify each carbocation as 1°, 2°, or 3°.

Concept introduction:

SN2 reaction is a special type of reaction mechanism in organic chemistry. It is kind of nucleophilic substitution reaction. Nucleophilic substitutions are Lewis acid-base reactions. In this reaction the nucleophile donates its electron pair, the alkyl halide (Lewis acid) accepts it, and the C-X bond is heterolytically cleaved. Alkyl halides are organic molecules that contains a halogen atom X bonded to sp3 hybridized carbon atom. Alkyl halides are classified as primary (1°), secondary (2°), and tertiary (3°) depending on the number of carbons bonded to the carbon with the halogen. In this reaction carbocation cannot form because it is an intermediate formed in the SN1 reaction.

Interpretation Introduction

(c)

Interpretation:

To classify each carbocation as 1°, 2°, or 3°.

Concept introduction:

SN2 reaction is a special type of reaction mechanism in organic chemistry. It is kind of nucleophilic substitution reaction. Nucleophilic substitutions are Lewis acid-base reactions. In this reaction the nucleophile donates its electron pair, the alkyl halide (Lewis acid) accepts it, and the C-X bond is heterolytically cleaved. Alkyl halides are organic molecules that contains a halogen atom X bonded to sp3 hybridized carbon atom. Alkyl halides are classified as primary (1°), secondary (2°), and tertiary (3°) depending on the number of carbons bonded to the carbon with the halogen. In this reaction carbocation cannot form because it is an intermediate formed in the SN1 reaction.

Interpretation Introduction

(d)

Interpretation:

To classify each carbocation as 1°, 2°, or 3°.

Concept introduction:

SN2 reaction is a special type of reaction mechanism in organic chemistry. It is kind of nucleophilic substitution reaction. Nucleophilic substitutions are Lewis acid-base reactions. In this reaction the nucleophile donates its electron pair, the alkyl halide (Lewis acid) accepts it, and the C-X bond is heterolytically cleaved. Alkyl halides are organic molecules that contains a halogen atom X bonded to sp3 hybridized carbon atom. Alkyl halides are classified as primary (1°), secondary (2°), and tertiary (3°) depending on the number of carbons bonded to the carbon with the halogen. In this reaction carbocation cannot form because it is an intermediate formed in the SN1 reaction.

Interpretation Introduction

(e)

Interpretation:

To classify each carbocation as 1°, 2°, or 3°.

Concept introduction:

SN2 reaction is a special type of reaction mechanism in organic chemistry. It is kind of nucleophilic substitution reaction. Nucleophilic substitutions are Lewis acid-base reactions. In this reaction the nucleophile donates its electron pair, the alkyl halide (Lewis acid) accepts it, and the C-X bond is heterolytically cleaved. Alkyl halides are organic molecules that contains a halogen atom X bonded to sp3 hybridized carbon atom. Alkyl halides are classified as primary (1°), secondary (2°), and tertiary (3°) depending on the number of carbons bonded to the carbon with the halogen. In this reaction carbocation cannot form because it is an intermediate formed in the SN1 reaction.

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Chapter 7 Solutions

Organic Chemistry

Ch. 7 - Prob. 7.11PCh. 7 - Prob. 7.12PCh. 7 - Does the equilibrium favor the reactants or...Ch. 7 - Prob. 7.14PCh. 7 - Prob. 7.15PCh. 7 - Classify each solvent as protic or aprotic. a. b....Ch. 7 - Prob. 7.17PCh. 7 - Prob. 7.18PCh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20PCh. 7 - Prob. 7.21PCh. 7 - Draw an energy diagram for the reaction in Problem...Ch. 7 - Draw the product of each SN2 reaction and indicate...Ch. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - What happens to the rate of an SN1 reaction under...Ch. 7 - Draw the products of each SN1 reaction and...Ch. 7 - Classify each carbocation as 1,2, or 3. a. b. c....Ch. 7 - Prob. 7.29PCh. 7 - Prob. 7.30PCh. 7 - Which alkyl halide in each pair reacts faster in...Ch. 7 - Prob. 7.32PCh. 7 - Problem 7.30 For each alkyl halide and...Ch. 7 - Prob. 7.34PCh. 7 - Prob. 7.35PCh. 7 - Prob. 7.36PCh. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - Prob. 7.39PCh. 7 - Prob. 7.40PCh. 7 - Prob. 7.41PCh. 7 - Give the IUPAC name for each compound, including...Ch. 7 - Draw the products formed when each alkyl halide is...Ch. 7 - Give the IUPAC name for each compound. a. c....Ch. 7 - Prob. 7.45PCh. 7 - Classify each alkyl halide in Problem 7.44 as 1 ,...Ch. 7 - Draw the eight constitutional isomers having the...Ch. 7 - Prob. 7.48PCh. 7 - Draw the substitution product that results when...Ch. 7 - Draw the products of each nucleophilic...Ch. 7 - Prob. 7.51PCh. 7 - Rank the species in each group in order of...Ch. 7 - Which of the following nucleophilic substitution...Ch. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - 7.53 Consider the following reaction. Draw a...Ch. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Draw the products of each SN2 reaction and...Ch. 7 - Prob. 7.61PCh. 7 - Prob. 7.62PCh. 7 - Prob. 7.63PCh. 7 - Consider the following SN1 reaction. a.Draw a...Ch. 7 - Prob. 7.65PCh. 7 - Prob. 7.66PCh. 7 - Draw the products of each SN1 reaction and...Ch. 7 - Prob. 7.68PCh. 7 - Prob. 7.69PCh. 7 - Diphenhydramine, the antihistamine in Benadryl,...Ch. 7 - Draw a stepwise, detailed mechanism for the...Ch. 7 - When a single compound contains both a nucleophile...Ch. 7 - Prob. 7.73PCh. 7 - Prob. 7.74PCh. 7 - Draw a stepwise, detailed mechanism f or the...Ch. 7 - Prob. 7.76PCh. 7 - Fill in the appropriate reagent or starting...Ch. 7 - Devise a synthesis of each compound from an alkyl...Ch. 7 - Prob. 7.79PCh. 7 - Suppose you have compounds A-D at y our disposal....Ch. 7 - Prob. 7.81PCh. 7 - Prob. 7.82PCh. 7 - Prob. 7.83PCh. 7 - Prob. 7.84PCh. 7 - 7.80 As we will learn in Chapter 9, an epoxide is...Ch. 7 - Prob. 7.86PCh. 7 - In some nucleophilic substitutions under SN1...
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