Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Question
Chapter 7, Problem 77QAP
Interpretation Introduction
(a)
Interpretation:
The meaning of the term ‘expanded octet’ needs to be explained.
Concept introduction:
- The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.
Interpretation Introduction
(b)
Interpretation:
The meaning of the term ‘resonance’ needs to be explained.
Concept introduction:
- In a given molecule, there are bonding electrons as well as in certain cases non-bonding or lone pairs of electrons. The phenomenon in which these electrons show a tendency to delocalize or move around the molecule thereby giving rise to intermediate structures is referred to as resonance.
Interpretation Introduction
(c)
Interpretation:
The meaning of the term ‘unshared electron pair’ needs to be explained.
Concept introduction:
- The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.
- The electrons around an atom can either be involved in bonding or remain non-bonding
Interpretation Introduction
(d)
Interpretation:
The meaning of the term ‘odd electron species’ needs to be explained
Concept introduction:
- The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.
- Species with unpaired electrons are exceptions to the octet rule, these are odd electron species
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Chapter 7 Solutions
Chemistry: Principles and Reactions
Ch. 7 - Prob. 1QAPCh. 7 - Prob. 2QAPCh. 7 - Follow the directions of Question 1 for (a) IO2-...Ch. 7 - Follow the directions of Question 1 for (a) CIF4-...Ch. 7 - Follow the directions of Question 1 for (a) OCl2...Ch. 7 - Follow the directions of Question 1 for (a) C22-...Ch. 7 - Oxalic acid, H2C2O4, is a poisonous compound found...Ch. 7 - Radio astronomers have detected the isoformyl ion,...Ch. 7 - Draw Lewis structures for the following species....Ch. 7 - Follow the directions of Question 9 for the...
Ch. 7 - Dinitrogen pentoxide, N2O5, when bubbled into...Ch. 7 - Formic acid is the irritating substance that gets...Ch. 7 - Two different molecules have the formula C2H2Cl2....Ch. 7 - Two different molecules have the formula C2H6O....Ch. 7 - Prob. 15QAPCh. 7 - Prob. 16QAPCh. 7 - Write a Lewis structure for (a) XeF3+ (b) PCl4+...Ch. 7 - Write a Lewis structure for (a) BCl4 (b) ClO- (c)...Ch. 7 - Write reasonable Lewis structures for the...Ch. 7 - Write reasonable Lewis structures for the...Ch. 7 - Prob. 21QAPCh. 7 - Draw resonance structures for (a) SeO3 (b) CS32-...Ch. 7 - Prob. 23QAPCh. 7 - Prob. 24QAPCh. 7 - The skeleton structure for disulfur dinitride,...Ch. 7 - Borazine, B3N3H6, has the skeleton Draw the...Ch. 7 - What is the formal charge on the indicated atom in...Ch. 7 - Prob. 28QAPCh. 7 - Below are two different Lewis structures for...Ch. 7 - Below are two different Lewis structures for the...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Give all the ideal bond angles (109.5, 120, or...Ch. 7 - Prob. 38QAPCh. 7 - Prob. 39QAPCh. 7 - An objectionable component of smog is acetyl...Ch. 7 - The uracil molecule is one of the bases in DNA....Ch. 7 - Niacin is one of the B vitamins (B3). Estimate the...Ch. 7 - Which of the species with octets in Question 31...Ch. 7 - Which of the species with octets in Question 32...Ch. 7 - Which of the species with octets in Question 33...Ch. 7 - Prob. 46QAPCh. 7 - There are three compounds with the formula...Ch. 7 - There are two different molecules with the formula...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - In each of the following polyatomic ions, the...Ch. 7 - Follow the directions of Question 55 for the...Ch. 7 - Give the hybridization of each atom (except H) in...Ch. 7 - Acrylonitrile, C3H3N is the building mer Orlon....Ch. 7 - What is the hybridization of nitrogen inCh. 7 - What is the hybridization of carbon inCh. 7 - Give the hybridization of the central atom...Ch. 7 - Give the hybridization of the central atom...Ch. 7 - Give the number of sigma and pi bonds in the...Ch. 7 - Give the number of sigma and pi bonds in the...Ch. 7 - Give the number of sigma and pi bonds in each...Ch. 7 - Give the number of sigma and pi bonds in each...Ch. 7 - In which of the following molecules does the...Ch. 7 - Consider the pyrosulfate ion, S2O72-. It has no...Ch. 7 - Consider acetyl salicylic acid, better known as...Ch. 7 - Complete the table on next page.Ch. 7 - Given the following electro negativities...Ch. 7 - Based on the concept of formal charge, what is the...Ch. 7 - Describe the geometry of the species in which...Ch. 7 - Consider the following molecules: SiH4, PH3, H2S....Ch. 7 - Prob. 75QAPCh. 7 - In each of the following molecules, a central atom...Ch. 7 - Prob. 77QAPCh. 7 - A compound of chlorine and fluorine, CIFx, reacts...Ch. 7 - Draw the Lewis structure and describe the geometry...Ch. 7 - Consider the polyatomic ion IO65-. How many pairs...Ch. 7 - It is possible to write a simple Lewis structure...Ch. 7 - Phosphoryl chloride, POCl3, has the skeleton...
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- Draw Lewis diagrams for the following compounds. In the formula the symbol of the central atom is given first. (Hint: The valence octet may be expanded for the central atom.) (a) PF5 (b) SF4 (c) XeO2F2arrow_forwardWhich of the following atoms could not accommodate an expanded octet (i.e., more than eight valence electrons)?arrow_forwardWhich labeled atom(s) in the following compound is (are) in violation of the octet rule?arrow_forward
- Give the number of valence electrons in N, As, Br, andSe. Predict the number of covalent bonds needed foreach of these elements to satisfy the octet rule.arrow_forwardDoes the periodic trend of electronegativity match the periodic trend of ionization energy?arrow_forwardIgnoring tables of electronegativity values and guided onlyby the periodic table, arrange these atoms in order ofincreasing electronegativity: S, Cl, Sb, Se, In. Briefly explainyour reasoning.arrow_forward
- Ignoring tables of electronegativity values and guided onlyby the periodic table, arrange these atoms in order ofincreasing electronegativity: O, F, S, Si, K. Briefly explainyour reasoningarrow_forwardBased on your knowledge of electronegativity and the Periodic Table, explain by calculating, what type of bonds are formed by these four elements with each other: Ag, F, O and Br.(Show the resulting formulas and names). Only compounds dealt with in the unit are accepted.arrow_forwardWhich of the following nitrogen containing compounds contains only covalent bonds?arrow_forward
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