ORGANIC CHEM. - ACCESS PKG+MODELING KIT
4th Edition
ISBN: 9781119838746
Author: Klein
Publisher: WILEY
expand_more
expand_more
format_list_bulleted
Question
Chapter 7, Problem 99IP
Interpretation Introduction
Interpretation:
Two different syntheses must be provided considering two logical bond formations for the given ether. The efficient synthesis must be identified.
Concept introduction:
Ether can be synthesized using alkoxide and
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Consider the given reaction in which NC−NC− is the nucleophile and CH3CNCH3CN is the solvent. The reactant molecule has a structure with solid and dashed wedge bonds. A solid wedge () is used to show the bond that is above the plane of the paper, and a dashed wedge () is used to show the bond that is behind the plane of the paper.
Draw the product of the following reaction:
Consider this reaction:
Br
CH;OH
Br-Br
H3CO
The mechanism proceeds through a first cationic intermediate, intermediate 1. Nucleophilic attack leads to intermediate 2, which goes on to form the final product. In cases that involve a
negatively charged nucleophile, the attack of the nucleophile leads directly to the product.
Br
+ CH3OH
Br
Intermediate 1
Intermediate 2
(product)
In a similar fashion, draw intermediate 1 and intermediate 2 (final product) for the following reaction.
OH
+ Br2
+ HBr
Br
racemic mixture
Predict the product of the following organic reaction:
CH₂
CH
O
||
C–CH2–CH=CH—(CH2)3 CH3
(CH₂)3 CH=CH- - CH₂
CH3
+ 4 H₂
Ni
CH,−O -C–CH2–CH=CH–CH=CH–CH2–CH3
Specifically, in the drawing area below, draw the chemical structure of the product P. If there is no product, because this reaction won't happen, check the No
reaction box under the drawing area.
Click and drag to start drawing a structure.
×
Ś
+
Chapter 7 Solutions
ORGANIC CHEM. - ACCESS PKG+MODELING KIT
Ch. 7.2 - Prob. 1CCCh. 7.3 - Prob. 2CCCh. 7.3 - Prob. 1LTSCh. 7.3 - Prob. 3PTSCh. 7.3 - Prob. 4ATSCh. 7.3 - Prob. 2LTSCh. 7.3 - Prob. 5PTSCh. 7.3 - Prob. 6ATSCh. 7.3 - Prob. 7CCCh. 7.4 - Prob. 8CC
Ch. 7.5 - Prob. 9CCCh. 7.6 - Prob. 10CCCh. 7.6 - Prob. 11CCCh. 7.7 - Prob. 12PTSCh. 7.7 - Prob. 13PTSCh. 7.7 - Prob. 14ATSCh. 7.7 - Prob. 4LTSCh. 7.7 - Prob. 16ATSCh. 7.7 - Prob. 17CCCh. 7.7 - Prob. 18CCCh. 7.7 - Prob. 5LTSCh. 7.7 - Prob. 19PTSCh. 7.7 - Prob. 20ATSCh. 7.8 - Prob. 21PTSCh. 7.8 - Prob. 22ATSCh. 7.8 - Prob. 23CCCh. 7.8 - Prob. 24CCCh. 7.8 - Prob. 25CCCh. 7.8 - Prob. 26CCCh. 7.8 - Prob. 27CCCh. 7.9 - Prob. 7LTSCh. 7.9 - Prob. 29ATSCh. 7.9 - Prob. 30ATSCh. 7.9 - Prob. 31ATSCh. 7.10 - Prob. 32CCCh. 7.10 - Prob. 33CCCh. 7.10 - Prob. 34CCCh. 7.11 - Prob. 8LTSCh. 7.11 - Prob. 35PTSCh. 7.11 - Prob. 36PTSCh. 7.11 - Prob. 37ATSCh. 7.11 - Prob. 9LTSCh. 7.11 - Prob. 40PTSCh. 7.11 - Prob. 41ATSCh. 7.12 - Prob. 42CCCh. 7.12 - Prob. 43CCCh. 7.12 - Prob. 44CCCh. 7.12 - Prob. 45CCCh. 7.12 - Prob. 46CCCh. 7 - Prob. 47PPCh. 7 - Prob. 48PPCh. 7 - Prob. 49PPCh. 7 - Prob. 50PPCh. 7 - Prob. 51PPCh. 7 - Prob. 52PPCh. 7 - Prob. 53PPCh. 7 - Prob. 54PPCh. 7 - Prob. 55PPCh. 7 - Prob. 56PPCh. 7 - Prob. 57PPCh. 7 - Prob. 58PPCh. 7 - Prob. 59PPCh. 7 - Prob. 60PPCh. 7 - Prob. 61PPCh. 7 - Prob. 64PPCh. 7 - Indicate whether you would use NaOEt or tBuOK to...Ch. 7 - Prob. 68PPCh. 7 - Draw a plausible mechanism for each of the...Ch. 7 - Prob. 70PPCh. 7 - Prob. 71PPCh. 7 - Prob. 72PPCh. 7 - Prob. 73PPCh. 7 - Prob. 74PPCh. 7 - Prob. 77PPCh. 7 - Prob. 78PPCh. 7 - Prob. 81ASPCh. 7 - Prob. 87ASPCh. 7 - Prob. 90ASPCh. 7 - Prob. 91IPCh. 7 - Prob. 92IPCh. 7 - Prob. 93IPCh. 7 - Prob. 94IPCh. 7 - Prob. 95IPCh. 7 - Prob. 96IPCh. 7 - Prob. 97IPCh. 7 - Prob. 98IPCh. 7 - Prob. 99IPCh. 7 - Prob. 100IPCh. 7 - Prob. 101IPCh. 7 - Prob. 102IPCh. 7 - Prob. 103IPCh. 7 - Prob. 105IPCh. 7 - Prob. 106IPCh. 7 - Prob. 107IPCh. 7 - Prob. 109IPCh. 7 - Prob. 110CPCh. 7 - Prob. 112CPCh. 7 - Prob. 114CP
Knowledge Booster
Similar questions
- N,N-diethyl-m-toluamide (DEET) is the active ingredient in many insect repellent preparations. Following is one of the steps in its synthesis. In the box below draw the structure of the product of this reaction. H3C MgBr 1. CO2 2. H30* product • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Draw the Grignard reagent as a covalent magnesium bromide. P ору aste O O O- []# Previous Next Email Instructor Save and Exitarrow_forward1. 2-Chloro-2-methylpropene reacts with water in three steps to yield 2-methyl-2-propanol. The first step is slower than the second, which in turn is much slower that the third. The reaction takes place slowly at room temperature, and the equilibrium constant is approximately 1. Which of the energy diagrams for the reaction are drawn and labeled correctly. Make sure the energy levels are consistent with the information given.arrow_forwardConsider this reaction: Br CH3OH Br-Br H3CO The mechanism proceeds through a first cationic intermediate, intermediate 1. Nucleophilic attack leads to intermediate 2, which goes on to form the final product. In cases that involve a negatively charged nucleophile, the attack of the nucleophile leads directly to the product. H. Br + CH;OH Br Intermediate 2 (product) Intermediate 1 In a similar fashion, draw intermediate 1 and intermediate 2 (final product) for the following reaction. OH + Br2 + HBr Br racemic mixturearrow_forward
- N,N-diethyl-m-toluamide (DEET) is the active ingredient in many insect repellent preparations. Following is one of the steps in its synthesis. In the box below draw the structure of the product of this reaction. MgBr H3C 0 ▾ + 1. CO₂ 2. H3O+ • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Draw the Grignard reagent as a covalent magnesium bromide. n [ ]# product ChemDoodleⓇ 28arrow_forward7. The reaction of methoxide anion with bromoethane to yield the ether ethyl methyl ether and the bromide anon (Br-) is an excellent example of a general reaction type called Sy2 (substitution nucleophilic bimolecular): CH,0+ CH,СH-Br a CH3-0-CH,СH; + Br- a. Change in enthalpy is -103 kJ/mol; the change in entropy is + 0.025 kJ/mol-K. Calculate DG at 300K. b. Is the reaction endergonic or exergonic? c. Is the reaction endothermic or exothermic? d. Use curved arrows to show the complete mechanism. Reaction of 2-methyl-1-butene with H-Cl could yield TWO alkyl chloride products. Draw and name 8. them.arrow_forwardThe compound below is treated with chlorine in the presence of light. CH3 CH3CHCH₂CH3 Draw the structure for the organic radical species produced by reaction of the compound with a chlorine atom. Assume reaction occurs at the weakest C-H bond. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. n [ ]# ?arrow_forward
- 7. The following scheme shows the intermediates in the mechanism for the synthesis of isoamyl acetate, an ester with a characteristic banana flavor. Classify steps 1, 2, 3, and 4 as addition, elimination, substitution, or acid base reactions. lo ОН gor H2SO4 2 HO HO QH₂ H2SO4 1 .H ОН له عليه ملا 4 HO 3 لیڈ جل OH HO OH + H2O Harrow_forwardList 2 chemical reactions that can produce chemical products ( by-products or main products) with little to no economic value that we can refine and make these chemical products useful to a country's economy. For each product, show the reaction (including reaction mechanism with least 3 reactions and solid catalyst) that can make the chemical product useful to society's economy.arrow_forwardPredict the products of this organic reaction: المعاد + NaOH Specifically, in the drawing area below draw the structure of the product, or products, of this reaction. If there's more than one product, draw them in any arrangement you like, so long as they aren't touching. If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area.arrow_forward
- Explain why methyl alcohol reacts with HBr faster than other primary alcohols?arrow_forward1) Find AH for the synthesis of B₂H6, diborane: 2B(s) + 3H2(g) → B₂H6(g) Given: 2 B(s) + 1/2O2(g) → B2O3(s) B₂H6(g) + 3 O2(g) →B2O3(s) + 3 H₂O(g) H2(g) + 1/2O2(g) → H₂O(1) H₂O(1)→ H₂O(g) AH₁ = -1273 kJ/mole AH₂=-2035 kJ/mole AH3= -286 kJ/mole 44 kJ/mole AH4=arrow_forward1. Predict the product(s) and propose a mechanism of the following nucleophilic substitution reaction. Remember that a mechanism should contain arrows to show movement of electrons, all intermediates and appropriate formal charges. Br + H₂O →arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning