Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 7.4, Problem 5PPB
For which molecule(s) can we not use
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- What are the bond angles predicted by the VSEPR model about the carbon atom in the formate ion, HCO2? Considering that the bonds to this atom are not identical, would you expect the experimental values to agree precisely with the VSEPR values? How might they differ?arrow_forwardA neutral molecule is identified as a tetrafluoride, XF4, where X is an unknown atom. If the molocule has a dipole moment of 0.63 D, can you give some possibilities for the identity of X?arrow_forwardThe bond length in C2 is 131 pm. Compare this with the bond lengths in C2H2 (120 pm), C2H4 (134 pm), and C2H6 (153 pm). What bond order would you predict for C2 from its bond length? Does this agree with the molecular orbital configuration you would predict for C2?arrow_forward
- In each of the following molecules, a central atom is surrounded by a total of three atoms or unshared electron pairs: SnCl2, BCl3, SO2. In which of these molecules would you expect the bond angle to be less than 120? Explain your reasoning.arrow_forwardConsider the following molecules: SiH4, PH3, H2S. In each case, a central atom is surrounded by four electron pairs. In which of these molecules would you expect the bond angle to be less than 109.5? Explain your reasoning.arrow_forwardPredict the valence electron molecular orbital configurations for the following, and state whether they will be stable or unstable ions. (a) Na,2+ (b) Mg,2 (c) AI,2 (d) Si,2 (e) p2+ (f) s,2 (g) F,2 (h) Ar,2 40. Predict the valence electron molecular orbital configurations for the following, and state whether they will be stable or unstable ions. (a) Na22+ (b) Mg22+ (c) Al22+ (d) Si22+ (e) P22+ (f) S22+ (g) F22+ (h) Ar22+arrow_forward
- Electrons in bonding molecular orbitals are most likely to be found in the region between the two bonded atoms. Why does this arrangement favor bonding? In a antibonding orbital, where are the electrons most likely to be found in relation to the nuclei in a bond?arrow_forwardWhich of these molecules have an odd number of valence electrons: NO2, SCl2, NH3, NO3?arrow_forwardIt is possible to write a simple Lewis structure for the SO42- ion, involving only single bonds, which follows the octet rule. However, Linus Pauling and others have suggested an alternative structure, involving double bonds, in which the sulfur atom is surrounded by six electron pairs. (a) Draw the two Lewis structures. (b) What geometries are predicted for the two structures? (c) What is the hybridization of sulfur in each case? (d) What are the formal charges of the atoms in the two structures?arrow_forward
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