Interpretation:
The structures of the products formed when 1-methylcyclopentene reacts with the given reagents are to be written.
Concept Introduction:
Hydroboration-oxidation: An organic reaction in which the double bonds of
Reduction is a process in which hydrogen atoms are added to a compound.
Usual reagents used in the reduction process are
Ozonolysis: An organic reaction in which the double bonds of alkenes, alkynes, or azo compounds are broken by ozone. In this reaction, the multiple carbon–carbon bond has been replaced by a carbonyl group while azo compounds form nitrosamines.
Oxymercuration-demercuration: An organic reaction in which the double bonds of alkenes or alkynes are broken by
Alkenes or alkynes undergo halogenation reaction in the presence of halides like
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Chapter 8 Solutions
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
- The heat of combustion of decahydronaphthalene(C10H18) is -6286 kJ/mol. The heat of combustion ofnaphthalene (C10H8) is -5157 kJ/mol. (In both casesCO2(g) and H2O(l) are the products.) Calculate the heat of hydrogenationand the resonance energy of naphthalene.arrow_forwardH H Write the structures of the alkenes that would yield the following carbonyl compounds PRACTICE PROBLEM 8.22 when treated with ozone and then with dimethyl sulfide. (a) and (c) EO and `H oalio (2 mol is produced from 1 mol of alkene) (b) H.arrow_forward1.Would the dehydration of 2-methylcyclohexanol yield a single alkene? Explain using equations with details.arrow_forward
- 2. Would the dehydration of 2-methylcyclohexanol yield a single alkene? Explain using equations with details.arrow_forward5.) cyclopentane Why slightly soluble in water? Why insoluble in HCl? Why completely soluble in NaOH? Why insoluble in NaHCO?arrow_forwardThe energy difference between cis- and trans-but-2-ene is about 4 kJ/mol; however, the trans isomer of 4,4-dimethylpent2-ene is nearly 16 kJ/mol more stable than the cis isomer. Explain this large difference.7arrow_forward
- 2. Please draw out structure of the following compounds. 1) 2,3-Methyl-1,4-pentadiene 2) (2E,4E)-2,4-heptadiene 3) (2Z,4Z)-3-Methyl-2,4-hexadienearrow_forward12.) If the enthalpy of the reaction was at 298 K, what would be the enthalpy of hydrogenation of ethylene to ethane at 373 K? A.) -1.48 kJ/mol B.) +1.48 kJ/mol C.) -138.42 kJ/mol D.) -135.46 kJ/mol E.) +135.46 kJ/molarrow_forwardA.) On any clean sheet of paper, draw both the condensed and line-bond structure of the following compounds: 7) 4-ethylcycloheptene 8) 4,4-dimethylpent-2-ene 9) 3-chloro-2,7-dimethylnon-4-yne (Cl- Chloro branch) 10) 1-cyclohexylbut-2-ynearrow_forward
- Define about Reactions of Dihalocarbenes ?arrow_forwardThe heat of combustion of decahydronaphthalene (C10H18) is -6286 kJ/mol. The heat of combustion of naphthalene 1C10H82 is -5157 kJ/mol. (In both cases CO2(g) and H2O(l) are the products). Calculate the heat of hydrogenation and the resonance energy of naphthalene.arrow_forwardDehydrohalogenation of 1-chloro-1-methylcyclopropane affords two alkenes (A and B) as products. Explain why A is the major product despite the fact that it contains the less substituted double bond.arrow_forward
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