Solution Manual for Quantitative Chemical Analysis
Solution Manual for Quantitative Chemical Analysis
9th Edition
ISBN: 9781464175633
Author: Daniel Harris
Publisher: Palgrave Macmillan Higher Ed
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Chapter 8, Problem 8.14P
Interpretation Introduction

Interpretation:

The activity coefficient of SO42- ion has to be calculated at 50.00oC.

Concept introduction:

Temperature-dependent extended Debye-Huckel equation:

The relationship between activity coefficient, temperature and the ionic strength is given by temperature-dependent extended Debye-Huckel equation.

logγ=(-1.825×106)(εT)-3/2z2μ1μ/(2.00εT)where,γ-activitycoefficientoftheionμ-ionicstrengthofthesolutionα-sizeoftheion;z-chargeoftheionandε-dielectricconstant.

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