CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
8th Edition
ISBN: 9780135204634
Author: Robinson
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Question
Chapter 8, Problem 8.34CP
Interpretation Introduction
Interpretation:
The observed polarity in ethyl acetate needs to be explained.
Concept introduction:
The molecule is said to be polar if there is an electronegative difference between two atoms in the molecule. The more electronegative atom gets partial negative charge and less electronegative atom gets a partial positive charge.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Rubbing alcohol is the common name for 2-propanol (iso- propanol), C3H7OH. (a) Draw
the three-dimensional structure of the 2-propanol molecule and predict the geometry
around each carbon atom. (b) Is the 2-propanol molecule polar or nonpolar? (c) What
kinds of intermolecular attractive forces exist between the 2-propanol molecules? (d) The
isomer 1-propanol has the same molecular weight as 2-propanol, yet 2-propanol boils at
82.6 °C and 1-propanol boils at 97.2 °C. Explain the difference.
Predict the main type of intermolecular force that would exist between molecules of the following hypothetical compounds, based upon its polarity:
molecules of carbon monosulfide, C―S
molecules of phosphorus monochloride, P―Cl
molecules of hydrogen monophosphide, H―P
What types of intermolecular forces are present in each compound: (a) HCl; (b) C 2H 6 (ethane); (c) NH 3?
Chapter 8 Solutions
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
Ch. 8 - Prob. 8.1PCh. 8 - What is the number and geometric arrangement of...Ch. 8 - PRACTICE 8.3 Acetic acid, CH3CO2H , is the main...Ch. 8 - APPLY 8.4 Benzene, C6H6 , is a cyclic molecule in...Ch. 8 - PRACTICE 8.5 Identify the orbitals that overlap to...Ch. 8 - APPLY 8.6 Describe the bonding in propane, C3H8 ,...Ch. 8 - PRACTICE 8.7 Describe the hybridization of the...Ch. 8 - Describe the hybridization of each carbon atom in...Ch. 8 - Which orbitals overlap to form the sigma and pi...Ch. 8 - APPLY 8.10 Describe the hybridization of the...
Ch. 8 - Prob. 8.11PCh. 8 - Conceptual APPLY 8.12 Match the following...Ch. 8 - Prob. 8.13PCh. 8 - Prob. 8.14ACh. 8 - Prob. 8.15PCh. 8 - Prob. 8.16ACh. 8 - Prob. 8.17ACh. 8 - Prob. 8.18ACh. 8 - The B2 molecule has a MO diagram similar to that...Ch. 8 - Prob. 8.20ACh. 8 - PRACTICE 8.23 Draw two resonance structures for...Ch. 8 - APPLY 8.24 Draw two resonance structures for the...Ch. 8 - Prob. 8.23PCh. 8 - Prob. 8.24PCh. 8 - Caffeine is the most widely used stimulant...Ch. 8 - Prob. 8.26PCh. 8 - What is the geometry around the central atom in...Ch. 8 - What is the geometry around the central atom in...Ch. 8 - Three of the following molecular models have a...Ch. 8 - Identify each of the following sets of hybrid...Ch. 8 - The VSEPR model is a simple predictive tool that...Ch. 8 - The following ball-and-stick molecular model is a...Ch. 8 - The following ball-and-stick molecular model is a...Ch. 8 - Prob. 8.34CPCh. 8 - The dipole moment of methanol is =1.70D . Use...Ch. 8 - Methylarnine, CH3NH2 , is responsible for the odor...Ch. 8 - Prob. 8.37CPCh. 8 - Prob. 8.38SPCh. 8 - What shape do you expect for molecules that meet...Ch. 8 - How many charge clouds are there around the...Ch. 8 - Prob. 8.41SPCh. 8 - What shape do you expect for each of the following...Ch. 8 - What shape do you expect for each of the following...Ch. 8 - What shape do you expect for each of the following...Ch. 8 - Prob. 8.45SPCh. 8 - Prob. 8.46SPCh. 8 - What shape do you expect for each of the following...Ch. 8 - What bond angles do you expect for each of the...Ch. 8 - What bond angles do you expect for each of the...Ch. 8 - Acrylonitrile is used as the starting material for...Ch. 8 - Predict values for all bond angles in dimethyl...Ch. 8 - Oceanographers study the mixing of water masses by...Ch. 8 - A potential replacement for the chlorofluorocarbon...Ch. 8 - Explain why cyclohexane, a substance that contains...Ch. 8 - Like cyclohexane (Problem 8.54), benzene also...Ch. 8 - Use VSEPR theory to answer the following...Ch. 8 - Draw an electron-dot structure for each of the...Ch. 8 - What is the difference in spatial distribution...Ch. 8 - The average CC bond dissociation energy (D) is 350...Ch. 8 - What hybridization do you expect for atoms that...Ch. 8 - What spatial arrangement of charge clouds...Ch. 8 - What hybridization would you expect for the...Ch. 8 - What hybridization would you expect for the...Ch. 8 - Oxaloacetic acid is an intermediate involved in...Ch. 8 - The atoms in the amino acid glycine are connected...Ch. 8 - Describe the hybridization of the carbon atom in...Ch. 8 - Describe the hybridization of each carbon atom in...Ch. 8 - Bupropion, marketed as Wellbutr in, is a heavily...Ch. 8 - Efavirenz, marketed as Sustiva, is a medication...Ch. 8 - What is the hybridization of the B and N atoms in...Ch. 8 - Prob. 8.71SPCh. 8 - Aspirin has the following connections among atoms....Ch. 8 - The cation [HCNXeF]+ is entirely linear. Draw an...Ch. 8 - Acrylonitrile (C3H3N) is a molecule that is...Ch. 8 - The odor of cinnamon oil is due to cinnamaldehyde,...Ch. 8 - The following molecular model is a representation...Ch. 8 - Prob. 8.77SPCh. 8 - Which of the following substances would you expect...Ch. 8 - Which of the following substances would you expect...Ch. 8 - Why is the dipole moment of SO2 1.63 D hut that of...Ch. 8 - Prob. 8.81SPCh. 8 - The class of ions PtX42 , where X is a halogen,...Ch. 8 - Prob. 8.83SPCh. 8 - Prob. 8.84SPCh. 8 - Prob. 8.85SPCh. 8 - Prob. 8.86SPCh. 8 - Prob. 8.87SPCh. 8 - What are the most important kinds of...Ch. 8 - Of the substances Xe, CH3Cl , and HF which has:...Ch. 8 - Methanol (CH3OH;bp=65C) boils nearly 230 °C higher...Ch. 8 - Prob. 8.91SPCh. 8 - Prob. 8.92SPCh. 8 - Prob. 8.93SPCh. 8 - A liquid sample contains methylamine (CH3NH2)...Ch. 8 - Prob. 8.95SPCh. 8 - What is the difference in spatial distribution...Ch. 8 - Prob. 8.97SPCh. 8 - Use the MO energy diagram in Figure 8.22b to...Ch. 8 - Use the MO energy diagram in Figure 8.22 a to...Ch. 8 - The C2 molecule can be represented by an MO...Ch. 8 - Prob. 8.101SPCh. 8 - Prob. 8.102SPCh. 8 - Prob. 8.103SPCh. 8 - Draw a molecular orbital energy diagram for Li2 ....Ch. 8 - Calcium carbide, CaC2 , reacts with water to...Ch. 8 - At high temperatures, sulfur vapor is...Ch. 8 - Carbon monoxide is produced by incomplete...Ch. 8 - Make a sketch showing the location and geometry of...Ch. 8 - Make a sketch showing the location and geometry of...Ch. 8 - Prob. 8.110MPCh. 8 - Prob. 8.111MPCh. 8 - Prob. 8.112MPCh. 8 - Prob. 8.113MPCh. 8 - Just as individual bonds in a molecule are often...Ch. 8 - Cyclooctatetraenedian ion, C8H82 , is an organic...
Knowledge Booster
Similar questions
- Halothane, which had been used as an anesthetic, has the molecular formula CHBrClCF3. Write the Lewis structure for halothane. Is halothane a polar molecule? Explain your answer. Can hydrogen bonding occur in halothane? Explain.arrow_forwardUse molecular structures and noncovalent interactions to explain why dimethyl ether, (CH3)2O, is completely miscible in water, but dimethylsulfide, (CH3)2S, is only slightly water soluble.arrow_forwardFor each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name compound hydrogen bromide hypochlorous acid ethane formula or Lewis structure HBr HCIO H H I I HC C-H | | H H Between molecules of the compound? O C yes no yes no O yes no hydrogen-bonding force Between molecules of the compound and molecules of water? 00 00 yes no yes no yes no Xarrow_forward
- For each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name N-chloromethylamine methanimine compound bromomethane formula or Lewis structure H | H-C H H | - CI: H | H-C=N-H CH₂ Br Between molecules of the compound? O O ΟΟ yes no yes no yes hydrogen-bonding force no Between molecules of the compound and molecules of water? O O ОО yes no yes no yes no X 5arrow_forwardConsider the following chemical reaction between component A and B: A(?) + 2B(g) → C(g)+ 3D(l) …..ΔH°r = −2253.2 kJ i. State whether the reaction is exothermic or endothermic. ii. Based on the value of heat of reaction, explain the chemical reaction above in terms of the energy associated with breaking or formation of molecular bonds. iii. Consider a similar reaction of A and B as the one shown above. However, the reaction now generates D in vapor form instead of liquid. Explain how the heat of reaction value differs from the one shown above. iv. If the above reaction occurs in an isothermal system where there is no work interaction and both kinetic and potential energy changes are too small such that they are negligible, write the energy balance for the system.arrow_forwardFor each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name hydrogen compound hypobromous acid ethane formula or Lewis structure H₂ HBrO H 1 HC T H H 1 C-H | H Between molecules of the compound? yes no yes O no yes hydrogen-bonding force Ono Between molecules of the compound and molecules of water? O yes O no O yes O no O yes O noarrow_forward
- For each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name acetic acid ammonia compound dibromomethane. formula or Lewis structure H :O: | || H-C-C-0-H 1 H ΝΗ, CH₂Br₂ Between molecules of the compound? O yes O no 10000 O yes O no hydrogen-bonding force O yes O no Between molecules of the compound and molecules of water? O yes O no O yes O no O yes O no X 3arrow_forwardDepict H-bonding between the molecule CH3OCH3 and waterarrow_forwardShown below are interactions that occur between ions and polar compounds (cyclopentyl alcohol, dimethyl ether, dimethyl sulfide, and water). Examine the types of intermolecular forces in which each of the following molecules participate, then rank the following interactions between molecules and ions from the weakest to the strongest based on those intermolecular forces and trends in electronegativity.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co