CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
8th Edition
ISBN: 9780135204634
Author: Robinson
Publisher: PEARSON
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Question
Chapter 8, Problem 8.18A
Interpretation Introduction
Interpretation:
The bond present in
Concept introduction:
The electronic structures of the compounds are described by drawing the molecular orbitals. Molecular orbitals are formed from the combination of atomic orbitals.
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Chapter 8 Solutions
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
Ch. 8 - Prob. 8.1PCh. 8 - What is the number and geometric arrangement of...Ch. 8 - PRACTICE 8.3 Acetic acid, CH3CO2H , is the main...Ch. 8 - APPLY 8.4 Benzene, C6H6 , is a cyclic molecule in...Ch. 8 - PRACTICE 8.5 Identify the orbitals that overlap to...Ch. 8 - APPLY 8.6 Describe the bonding in propane, C3H8 ,...Ch. 8 - PRACTICE 8.7 Describe the hybridization of the...Ch. 8 - Describe the hybridization of each carbon atom in...Ch. 8 - Which orbitals overlap to form the sigma and pi...Ch. 8 - APPLY 8.10 Describe the hybridization of the...
Ch. 8 - Prob. 8.11PCh. 8 - Conceptual APPLY 8.12 Match the following...Ch. 8 - Prob. 8.13PCh. 8 - Prob. 8.14ACh. 8 - Prob. 8.15PCh. 8 - Prob. 8.16ACh. 8 - Prob. 8.17ACh. 8 - Prob. 8.18ACh. 8 - The B2 molecule has a MO diagram similar to that...Ch. 8 - Prob. 8.20ACh. 8 - PRACTICE 8.23 Draw two resonance structures for...Ch. 8 - APPLY 8.24 Draw two resonance structures for the...Ch. 8 - Prob. 8.23PCh. 8 - Prob. 8.24PCh. 8 - Caffeine is the most widely used stimulant...Ch. 8 - Prob. 8.26PCh. 8 - What is the geometry around the central atom in...Ch. 8 - What is the geometry around the central atom in...Ch. 8 - Three of the following molecular models have a...Ch. 8 - Identify each of the following sets of hybrid...Ch. 8 - The VSEPR model is a simple predictive tool that...Ch. 8 - The following ball-and-stick molecular model is a...Ch. 8 - The following ball-and-stick molecular model is a...Ch. 8 - Prob. 8.34CPCh. 8 - The dipole moment of methanol is =1.70D . Use...Ch. 8 - Methylarnine, CH3NH2 , is responsible for the odor...Ch. 8 - Prob. 8.37CPCh. 8 - Prob. 8.38SPCh. 8 - What shape do you expect for molecules that meet...Ch. 8 - How many charge clouds are there around the...Ch. 8 - Prob. 8.41SPCh. 8 - What shape do you expect for each of the following...Ch. 8 - What shape do you expect for each of the following...Ch. 8 - What shape do you expect for each of the following...Ch. 8 - Prob. 8.45SPCh. 8 - Prob. 8.46SPCh. 8 - What shape do you expect for each of the following...Ch. 8 - What bond angles do you expect for each of the...Ch. 8 - What bond angles do you expect for each of the...Ch. 8 - Acrylonitrile is used as the starting material for...Ch. 8 - Predict values for all bond angles in dimethyl...Ch. 8 - Oceanographers study the mixing of water masses by...Ch. 8 - A potential replacement for the chlorofluorocarbon...Ch. 8 - Explain why cyclohexane, a substance that contains...Ch. 8 - Like cyclohexane (Problem 8.54), benzene also...Ch. 8 - Use VSEPR theory to answer the following...Ch. 8 - Draw an electron-dot structure for each of the...Ch. 8 - What is the difference in spatial distribution...Ch. 8 - The average CC bond dissociation energy (D) is 350...Ch. 8 - What hybridization do you expect for atoms that...Ch. 8 - What spatial arrangement of charge clouds...Ch. 8 - What hybridization would you expect for the...Ch. 8 - What hybridization would you expect for the...Ch. 8 - Oxaloacetic acid is an intermediate involved in...Ch. 8 - The atoms in the amino acid glycine are connected...Ch. 8 - Describe the hybridization of the carbon atom in...Ch. 8 - Describe the hybridization of each carbon atom in...Ch. 8 - Bupropion, marketed as Wellbutr in, is a heavily...Ch. 8 - Efavirenz, marketed as Sustiva, is a medication...Ch. 8 - What is the hybridization of the B and N atoms in...Ch. 8 - Prob. 8.71SPCh. 8 - Aspirin has the following connections among atoms....Ch. 8 - The cation [HCNXeF]+ is entirely linear. Draw an...Ch. 8 - Acrylonitrile (C3H3N) is a molecule that is...Ch. 8 - The odor of cinnamon oil is due to cinnamaldehyde,...Ch. 8 - The following molecular model is a representation...Ch. 8 - Prob. 8.77SPCh. 8 - Which of the following substances would you expect...Ch. 8 - Which of the following substances would you expect...Ch. 8 - Why is the dipole moment of SO2 1.63 D hut that of...Ch. 8 - Prob. 8.81SPCh. 8 - The class of ions PtX42 , where X is a halogen,...Ch. 8 - Prob. 8.83SPCh. 8 - Prob. 8.84SPCh. 8 - Prob. 8.85SPCh. 8 - Prob. 8.86SPCh. 8 - Prob. 8.87SPCh. 8 - What are the most important kinds of...Ch. 8 - Of the substances Xe, CH3Cl , and HF which has:...Ch. 8 - Methanol (CH3OH;bp=65C) boils nearly 230 °C higher...Ch. 8 - Prob. 8.91SPCh. 8 - Prob. 8.92SPCh. 8 - Prob. 8.93SPCh. 8 - A liquid sample contains methylamine (CH3NH2)...Ch. 8 - Prob. 8.95SPCh. 8 - What is the difference in spatial distribution...Ch. 8 - Prob. 8.97SPCh. 8 - Use the MO energy diagram in Figure 8.22b to...Ch. 8 - Use the MO energy diagram in Figure 8.22 a to...Ch. 8 - The C2 molecule can be represented by an MO...Ch. 8 - Prob. 8.101SPCh. 8 - Prob. 8.102SPCh. 8 - Prob. 8.103SPCh. 8 - Draw a molecular orbital energy diagram for Li2 ....Ch. 8 - Calcium carbide, CaC2 , reacts with water to...Ch. 8 - At high temperatures, sulfur vapor is...Ch. 8 - Carbon monoxide is produced by incomplete...Ch. 8 - Make a sketch showing the location and geometry of...Ch. 8 - Make a sketch showing the location and geometry of...Ch. 8 - Prob. 8.110MPCh. 8 - Prob. 8.111MPCh. 8 - Prob. 8.112MPCh. 8 - Prob. 8.113MPCh. 8 - Just as individual bonds in a molecule are often...Ch. 8 - Cyclooctatetraenedian ion, C8H82 , is an organic...
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- Predict the valence electron molecular orbital configurations for the following, and state whether they will be stable or unstable ions. (a) Na,2+ (b) Mg,2 (c) AI,2 (d) Si,2 (e) p2+ (f) s,2 (g) F,2 (h) Ar,2 40. Predict the valence electron molecular orbital configurations for the following, and state whether they will be stable or unstable ions. (a) Na22+ (b) Mg22+ (c) Al22+ (d) Si22+ (e) P22+ (f) S22+ (g) F22+ (h) Ar22+arrow_forwardUse the MO model to explain the bonding in BeH2. When constructing the MO energy-level diagram, assume that the Bes 1s electrons are not involved in bond formation.arrow_forwardIt is possible to write a simple Lewis structure for the SO42- ion, involving only single bonds, which follows the octet rule. However, Linus Pauling and others have suggested an alternative structure, involving double bonds, in which the sulfur atom is surrounded by six electron pairs. (a) Draw the two Lewis structures. (b) What geometries are predicted for the two structures? (c) What is the hybridization of sulfur in each case? (d) What are the formal charges of the atoms in the two structures?arrow_forward
- Shown below is the molecular orbital diagram for N2. Does N2+ have a shorter or longer bond length?arrow_forwardConsider a heteronuclear diatomic molecule, AB, where A and B are period 2 elements. Using the following pieces of information, provide details on the molecular orbital diagram of AB: Clue 1: The MO diagram of AB does not contain non- bonding electrons. Clue 2: The s and p orbital energies of both atoms are quite close to one another that interactions between different orbital types occur. Clue 3: AB" is more stable than AB, but AB2 is less stable than AB". Clue 4: The potential energies of the atomic orbitals of A are higher than the potential energies of the atomic orbitals of B. Table 1. Atomic orbital energies of period 2 elements. Atom Orbital energy Orbital energy (2s) (2p) Li -5.45 Ве -9.30 B -14.0 -8.30 C -19.5 -10.7 -25.5 -13.1 -32.3 -15.9 F -46.4 -18.7 Ne -48.5 -21.5arrow_forwardHow many electron groups does the central atom of CH2O have according to VSEPR theory?arrow_forward
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