EBK ORGANIC CHEMISTRY AS A SECOND LANGU
EBK ORGANIC CHEMISTRY AS A SECOND LANGU
4th Edition
ISBN: 9781119234715
Author: Klein
Publisher: VST
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Chapter 8.5, Problem 11ATS

(a)

Interpretation Introduction

Interpretation: The conversion of compound 1 to compound 4 occurs with the formation of carbocation as an intermediate. The curved arrows for the given conversion of compound 1 to compound 4 is to be interpreted.

  EBK ORGANIC CHEMISTRY AS A SECOND LANGU, Chapter 8.5, Problem 11ATS , additional homework tip  1

Concept introduction:

Alkenes are the unsaturated hydrocarbon that contains at least one double bond between the carbon atoms. The presence of pi bonds in these molecules makes them more reactive compared to saturated hydrocarbons; alkanes. The most common chemical reaction of alkenes is the addition reactions that mainly occur with the formation of a carbocation.

(b)

Interpretation Introduction

Interpretation: The conversion of compound 1 to compound 4 occurs with the formation of carbocation as an intermediate. The reason for the rearrangement of tertiary carbocation (structure 2) to secondary carbocation (structure 3) is to be interpreted.

  EBK ORGANIC CHEMISTRY AS A SECOND LANGU, Chapter 8.5, Problem 11ATS , additional homework tip  2

Concept introduction:

Alkenes are the unsaturated hydrocarbon that contains at least one double bond between the carbon atoms. The presence of pi bonds in these molecules makes them more reactive compared to saturated hydrocarbons; alkanes. The most common chemical reaction of alkenes is the addition reaction that mainly occurs with the formation of a carbocation.

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#16f. Provide the missing reactants, reagents, or products for the following reaction sequences below.
c) Complete the following reaction scheme for structures E, F, G, H and I. F Br2 / H20 Cl i. BH3, THF ii. H2O2 / H* КОН E G i. Оз ii. (CH3)2S H + I
2. The structures of alkenes can affect their reactivity in the reaction with H-Br. H;C H H;C H H H H `H H;C `H H `H A B (a) Arrange the reactivity of above alkenes (A, B and C) in an increasing order. AL (b) Use the carbocation formation to show the ease of alkenes to accept a proton from HBr.
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