The product of given oxymercuration-demercuration has to be identified. Concept Introduction: Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride. The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

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Answer 1

Question

Chapter 8.6, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

(b)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

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Answer 2

Question

Chapter 8.6, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

(b)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

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Answer 3

Question

Chapter 8.6, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

(b)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

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Answer 4

Question

Chapter 8.6, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

(b)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

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Answer 5

Chapter 8.6, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

(b)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

Answer 6

Chapter 8.6, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

Answer 7

Chapter 8.6, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The product of given oxymercuration-demercuration has to be identified.

Concept Introduction:

Oxymercuration-Demercuration: In this reaction, alkene undergoes oxymercuration to form mercurinium ion intermediate. This intermediate reacts with nucleophile and mercury can be removed by sodium borohydride.

The intermediate (mercurinium ion) obtained in this reaction does not undergo rearrangement because of partial positive charge on more substituted carbon. Hence, the product is obtained without any rearrangement.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 8.4 - Prob. 1CC Ch. 8.4 - Prob. 2CC Ch. 8.4 - Draw a mechanism for the following...Ch. 8.4 - Prob. 3PTS Ch. 8.4 - Prob. 4ATS Ch. 8.4 - Prob. 5CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 6PTS Ch. 8.5 - Prob. 8CC Ch. 8.5 - Prob. 9CC

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