Concept explainers
(a)
To determine: The conversion of
Interpretation: The conversion of the given reactions is to be stated.
Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of
Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in
(b)
To determine: The conversion of
Interpretation: The conversion of the given reactions is to be stated.
Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.
According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in
The general steps followed by Oxymercuration-demercuration reaction are stated below:
- Formation of mercurinium ion.
- Attack of water on mercurinium ion to give alcohol.
- Demercuration
(c)
To determine: The conversion of
Interpretation: The conversion of the given reactions is to be stated.
Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti- Markovnikov’s rule.
Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in
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EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
- Convert propan-2-ol [(CH3)2CHOH] to each compound. You may use any other organic or inorganic compounds.arrow_forwardName each alkyne. a. CH=C-CH-CH3 CH3 b. CH3-C=C-CH-CH-CH,-CH, CH3 CH3 c. CHEC-C-CH,-CH3 CH2 ČH, CH3 d. CH;-C=C-CH-C-CH, CH2 CH3 ČH3arrow_forwardThe following reaction is a/an example of H2 I H₂ ó H₂CCCC. H2 Addition Condensation Elimination Substitution Oxidation Cl H2 Cl₂and light H₂C-CH CC + HC CH3 CH3 H2 other + chlorinated productsarrow_forward
- CH2 H3C H3C COOH Reagents e. PB13 f. NaCN then H3O* g. NBS, CCI4 h. CrO3, H2SO4 а. HBr b. Mg, ether c. CO2, ether then H3O* d. BH3, THF then H2O2, OH"arrow_forwardWhat about the second step in the electrophilic addition of HCl to an alkene-the reaction of chloride ion with the carbocation intermediate? Is this step exergonic or endergonic? Does the transition state for this second step resemble the reactant (carbocation) or the product (alkyl chloride)? Make a rough diagram of what the transition state may look like?arrow_forwardB. Draw structures for the products in the following reactions. my NH₂ NH₂ 1. LIAIH4 2. H₂O* xs EtBr 1. Mel 2. Ag₂O, H,O, heat acetone, formaldehyde cat. HCIarrow_forward
- The major organic product of the following reaction is HC=CH2 H2/ Ni-Cat. HC=C-CH2 HC=CH2 H2 1. H3C-C -CH2 H2C-CH3 H2 H3C-C-CH2 HC=CH2 H3C-C-CH2 HC=CH2 H2C=C-CH2 H. H2C-CH3 HC=C-CH2arrow_forward1. What is it's type of reaction (Sn1, Sn2, E1, E2, Nucleophilic Addition, Nucleophilic Acyl Substition or Redox reaction). 2.What is it's major product.arrow_forwardWhich alcohols can be prepared as a single product by hydroboration– oxidation of an alkene? Which alcohols can be prepared as a single product by the acid-catalyzed addition of H2O to an alkene?arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning