The synthetic route for the preparation of given transformation should be determined. Concept Introduction : Hydrogenation reaction : The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated. Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene. Soda amide: The NaNH 2 /NH 3 is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

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Answer 1

Question

Chapter 9, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

Soda amide: The NaNH2/NH3 is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

(b)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Anti- Markovnikov addition: These rules describe the regiochemistry where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

(c)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of H-X becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

(d)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Metal and ammonia reaction: The alkyne involves sodium (Na)/NH₃. This end up reducing to alkyne to give the trans (E) alkene.

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Answer 2

Question

Chapter 9, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

Soda amide: The NaNH2/NH3 is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

(b)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Anti- Markovnikov addition: These rules describe the regiochemistry where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

(c)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of H-X becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

(d)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Metal and ammonia reaction: The alkyne involves sodium (Na)/NH₃. This end up reducing to alkyne to give the trans (E) alkene.

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Answer 3

Question

Chapter 9, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

Soda amide: The NaNH2/NH3 is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

(b)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Anti- Markovnikov addition: These rules describe the regiochemistry where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

(c)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of H-X becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

(d)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Metal and ammonia reaction: The alkyne involves sodium (Na)/NH₃. This end up reducing to alkyne to give the trans (E) alkene.

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Answer 4

Question

Chapter 9, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

Soda amide: The NaNH2/NH3 is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

(b)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Anti- Markovnikov addition: These rules describe the regiochemistry where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

(c)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of H-X becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

(d)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Metal and ammonia reaction: The alkyne involves sodium (Na)/NH₃. This end up reducing to alkyne to give the trans (E) alkene.

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Answer 5

Chapter 9, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

Soda amide: The NaNH2/NH3 is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

(b)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Anti- Markovnikov addition: These rules describe the regiochemistry where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

(c)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of H-X becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

(d)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Metal and ammonia reaction: The alkyne involves sodium (Na)/NH₃. This end up reducing to alkyne to give the trans (E) alkene.

Answer 6

Chapter 9, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

Soda amide: The NaNH2/NH3 is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

Answer 7

Chapter 9, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Hydrogenation reaction: The hydrogenation is a reduction reaction which results in an addition of hydrogen. Several organic compounds is hydrogenated, it becomes more saturated.

Linder’s catalyst: The alkyne reduced to alkenes to give the cis (Z) alkene.

Soda amide: The NaNH2/NH3 is a strong base and excellent nucleophile. It’s used deprotonated of weak acids and also for elimination reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Anti- Markovnikov addition: These rules describe the regiochemistry where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Anti- Markovnikov addition: These rules describe the regiochemistry where the substituent is bonded to a less substituted carbon, rather than the more substituted carbon. This placed is quite unusual as carbon cations which are commonly formed during alkene or alkyne reactions tend to favor the more substituted carbon.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of H-X becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Markovnikov addition: The addition reaction of parotic acids to a different alkene or alkyne, the hydrogen atom of H-X becomes bonded to the carbon atom that the greatest number of hydrogen atoms in the starting alkene or alkyne.

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Metal and ammonia reaction: The alkyne involves sodium (Na)/NH₃. This end up reducing to alkyne to give the trans (E) alkene.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The synthetic route for the preparation of given transformation should be determined.

Concept Introduction:

Soda amide: The NaNH₂/NH₃is a strong base and excellent nucleophile. Its used deprotonated of weak acids and also for elimination reaction.

Metal and ammonia reaction: The alkyne involves sodium (Na)/NH₃. This end up reducing to alkyne to give the trans (E) alkene.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 9.2 - Prob. 1LTS Ch. 9.2 - Prob. 1PTS Ch. 9.2 - Prob. 2PTS Ch. 9.2 - Prob. 3PTS Ch. 9.2 - (+)-Citronella is the main compound responsible...Ch. 9.3 - Prob. 2LTS Ch. 9.3 - Prob. 5PTS Ch. 9.3 - Prob. 6ATS Ch. 9.4 - Prob. 7CC Ch. 9.4 - Prob. 8CC

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