General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Textbook Question
Chapter 9, Problem 61IAE
Refer only to the periodic table on the inside front cover, and arrange the following ionization energies in order of increasing value: the first ionization energy of F; the second ionization energy of Ba; the third ionization energy of Sc; the second ionization energy of Na; the third ionization energy of Mg. Explain the basis of any uncertainties.
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General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 9 - Prob. 1ECh. 9 - Suppose that lanthanum (Z = 57) were a newly...Ch. 9 - The following densities, in grams per cubic...Ch. 9 - The blowing melting points are in degrees Celsius....Ch. 9 - Mendeleev's periodic table did not preclude the...Ch. 9 - Prob. 6ECh. 9 - Prob. 7ECh. 9 - Concerning the incomplete seventh period of the...Ch. 9 - For each of the following pairs, indicate the atom...Ch. 9 - Indicate the smallest and the largest species...
Ch. 9 - Explain why the radii of atoms do not simply...Ch. 9 - The masses of individual atoms can be determined...Ch. 9 - Which is (a) the smallest atom in group 13; (b)...Ch. 9 - How would you expect the sizes of the hydrogen...Ch. 9 - Prob. 15ECh. 9 - Explain why the generalizations presented in...Ch. 9 - Among the following ions, several pairs are...Ch. 9 - Prob. 18ECh. 9 - All the isoelectronic species illustrated in the...Ch. 9 - Prob. 20ECh. 9 - Use principles established in this chapter to...Ch. 9 - Are there any atoms for which the second...Ch. 9 - Some electron affinities are negative quantities,...Ch. 9 - How much energy, in pules, must be absorbed to...Ch. 9 - How much energy, in kilojoules, is required to...Ch. 9 - Prob. 26ECh. 9 - The production of gaseous bromide ions from...Ch. 9 - Use ionization energies and electron affinities...Ch. 9 - The Naa ion and the Ne atom are isoelectronic. The...Ch. 9 - Prob. 30ECh. 9 - Compare the elements Al, Si, S, and Cl. a. Place...Ch. 9 - Compare the elements Na, Mg, O, and P. a. Place...Ch. 9 - Unpaired electrons are found in only one of the...Ch. 9 - Which of the following species has the greatest...Ch. 9 - Which of the following species would you expect to...Ch. 9 - Write electron configurations consistent with the...Ch. 9 - Must all atoms with an odd atomic number be...Ch. 9 - Neither Co24 nor Co24 has 4s electrons in its...Ch. 9 - Use ideas presented in this chapter to indicate...Ch. 9 - Arrange the following atoms in order of increasing...Ch. 9 - Arrange the following species in order of...Ch. 9 - For the following groups of elements, select the...Ch. 9 - Prob. 43ECh. 9 - Of the species Naa, Na, F, and F-, which has the...Ch. 9 - Match each of the lettered items on the left with...Ch. 9 - Prob. 46ECh. 9 - Which of the following ions are unlikely to be...Ch. 9 - Which of the following ions are likely to be found...Ch. 9 - Four atoms and/or ions are sketched below in...Ch. 9 - Prob. 50IAECh. 9 - In Mendeleev's time, indium oxide, which is 82.5%...Ch. 9 - Instead of accepting the atomic mass of indium...Ch. 9 - Refer to Figure 9-11 and explain why the...Ch. 9 - Explain why the third ionization energy of Li(g)...Ch. 9 - Prob. 55IAECh. 9 - Prob. 56IAECh. 9 - Studies done in 1880 showed that a chloride of...Ch. 9 - Assume that atoms are herd spheres, and use the...Ch. 9 - When sodium chloride is strongly heated in a...Ch. 9 - Use information from Chapters 8 and 9 to calculate...Ch. 9 - Refer only to the periodic table on the inside...Ch. 9 - Refer to the footnote on page 393. Then use values...Ch. 9 - Prob. 63IAECh. 9 - Prob. 64IAECh. 9 - The work functions for a number of metals are...Ch. 9 - The following are a few elements and their...Ch. 9 - Gaseous sodium atoms absorb quanta with the...Ch. 9 - A method for estimating electron affinities is to...Ch. 9 - We have seen that the wave functions of...Ch. 9 - In your own words, define the following terms (a)...Ch. 9 - Briefly describe each of the following ideas or...Ch. 9 - Explain the important distinctions between each...Ch. 9 - Prob. 73SAECh. 9 - Prob. 74SAECh. 9 - Prob. 75SAECh. 9 - Prob. 76SAECh. 9 - Prob. 77SAECh. 9 - An ion that is isoelectronic with Se2- is (a) S2-...Ch. 9 - Write electron configurations to show the first...Ch. 9 - Explain why the first ionization energy of Mg is...Ch. 9 - Prob. 81SAECh. 9 - Prob. 82SAECh. 9 - Find three pairs of elements that are out of order...Ch. 9 - Prob. 84SAECh. 9 - Prob. 85SAECh. 9 - Prob. 86SAECh. 9 - Prob. 87SAECh. 9 - Prob. 88SAECh. 9 - In multielectron atoms many of the periodic trends...Ch. 9 - Consider a nitrogen atom in the ground state and...Ch. 9 - Prob. 91SAECh. 9 - Describe how the ionization energies of the ions...Ch. 9 - Prob. 93SAECh. 9 - Prob. 94SAECh. 9 - When compared to a nonmetal of the same period, a...Ch. 9 - Prob. 96SAECh. 9 - Which of the following has a smaller radius than a...Ch. 9 - Prob. 98SAECh. 9 - The electrons lost when Fe ionizes to Fe2- are (a)...Ch. 9 - Prob. 100SAE
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- r Questions 11—13, you will need to consider ionizations beyond the first ionization energy. For example, the second ionization energy is the energy to remove a second electron from an element. Compare the first ionization energy of helium to its second ionization energy, remembering that both electrons come from the 1s orbital. l> X Y First 170 200 second 350 400 Third 1800 3500 fouth 2500 5000 entify the elements X and Y. There may be more than one answer. so explain completely.arrow_forward6.82 A particular element has the following values for its first four ionization energies: 900, 1760, 14, 850, and 21,000 kJ/mol. Without consulting a list of ionization energy values, determine what group in the periodic table this element belongs in.arrow_forwardThe first ionization energy of helium is 2370kJmol1 , the highest for any element. (a) Define ionization energy and discuss why for helium it should be so high. (b) Which element would you expect to have the highest second ionization energy? Why? (c) Suppose that you wished to ionize some helium by shining electromagnetic radiation on it. What is the maximum wavelength you could use?arrow_forward
- For each of the following pairs of atoms or ions, state which you expect to have the larger radius. (a) Sm or Sm3+ (b) Mg or Ca (c) I orXe (d) Ge or As (e) Sr+ or Rbarrow_forwardBased on their positions in the periodic table, predict which has the largest first ionization energy: Mg, Ba, B, O, Te.arrow_forwardAnswer the following questions about first ionization energies. (a) Generally ionization energies increase on proceeding across a period, but this is not true for magnesium (738 kJ/mol) and aluminium (578 kJ/mol). Explain this observation. (b) Explain why the ionization energy of phosphorus (1012 kJ/mol) is greater than that of sulphur (1000 kJ/mol) when the general trend in ionization energies in a period would predict the opposite.arrow_forward
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