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Chapter 9, Problem 66P

When equivalent amounts of methyl bromide nod sodium iodide are dissolved in methonal, the concentration of iodide ion quickly decrease and then slowly returns to its original concentration. Account for this observation.

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2.1g of sample are dissolved in methylene chloride and the sample is extracted with an aqueous solution of acid and base. Three compounds are isolated - 0.7g of ethyl p-aminobenzoate, 0.6 g of acetanilide, and 0.5 g of benzoic acid. Calculate the % composition of ethyl p-aminobenzoate in the recovered mixture. (Round the answer to 1 significant figure. Give just the number, not a % sign.)
1. In between water and 10% HCl, aniline and diethylamine is more soluble in what solvent? Explain and show the chemical reaction involved. 2. In between water and 10% NaOH, benzoic acid and phenol is more soluble in what solvent? Explain and show the chemical reaction involved.
why is benzoic acid insoluble in pure water but soluble in NaOH solution?

Chapter 9 Solutions

Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)

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