Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 9, Problem 9.18E
Interpretation Introduction
Interpretation:
The correct formula, structure and the possible isomers of the complex
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Many transition metals and their compounds are used as catalysts. Given MnO2, FeCl3, Pt, and Ni, which would you select for producing CCl4 from CS2 and Cl2?
Mention the types of structural isomerism present in metal complexes and indicate to which of them the following compound pair belongs:
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When cobalt(II) chloride is treated, under certain condition, with the bidentate ligand, NH2CH2CH2NH2, (which can be represented by the symbol “en”), the compound [CoC12(en)2]Cl is formed.
a. What is the oxidation state of cobalt in the compound formed?
b. What is meant by the term ‘bidentate’ as applied to a ligand?
Chapter 9 Solutions
Chemical Principles: The Quest for Insight
Ch. 9 - Prob. 9A.1ASTCh. 9 - Prob. 9A.1BSTCh. 9 - Prob. 9A.1ECh. 9 - Prob. 9A.2ECh. 9 - Prob. 9A.3ECh. 9 - Prob. 9A.4ECh. 9 - Prob. 9A.5ECh. 9 - Prob. 9A.6ECh. 9 - Prob. 9A.7ECh. 9 - Prob. 9A.8E
Ch. 9 - Prob. 9A.9ECh. 9 - Prob. 9A.10ECh. 9 - Prob. 9A.11ECh. 9 - Prob. 9A.12ECh. 9 - Prob. 9A.13ECh. 9 - Prob. 9A.14ECh. 9 - Prob. 9B.1ASTCh. 9 - Prob. 9B.1BSTCh. 9 - Prob. 9B.2ASTCh. 9 - Prob. 9B.2BSTCh. 9 - Prob. 9B.1ECh. 9 - Prob. 9B.2ECh. 9 - Prob. 9B.3ECh. 9 - Prob. 9B.4ECh. 9 - Prob. 9B.5ECh. 9 - Prob. 9B.6ECh. 9 - Prob. 9B.7ECh. 9 - Prob. 9B.8ECh. 9 - Prob. 9B.9ECh. 9 - Prob. 9B.10ECh. 9 - Prob. 9B.11ECh. 9 - Prob. 9B.12ECh. 9 - Prob. 9B.13ECh. 9 - Prob. 9B.14ECh. 9 - Prob. 9B.15ECh. 9 - Prob. 9B.16ECh. 9 - Prob. 9C.1ASTCh. 9 - Prob. 9C.1BSTCh. 9 - Prob. 9C.2ASTCh. 9 - Prob. 9C.2BSTCh. 9 - Prob. 9C.3ASTCh. 9 - Prob. 9C.3BSTCh. 9 - Prob. 9C.4ASTCh. 9 - Prob. 9C.4BSTCh. 9 - Prob. 9C.1ECh. 9 - Prob. 9C.2ECh. 9 - Prob. 9C.3ECh. 9 - Prob. 9C.4ECh. 9 - Prob. 9C.5ECh. 9 - Prob. 9C.6ECh. 9 - Prob. 9C.7ECh. 9 - Prob. 9C.8ECh. 9 - Prob. 9C.9ECh. 9 - Prob. 9C.10ECh. 9 - Prob. 9C.11ECh. 9 - Prob. 9C.12ECh. 9 - Prob. 9C.13ECh. 9 - Prob. 9C.14ECh. 9 - Prob. 9C.15ECh. 9 - Prob. 9C.16ECh. 9 - Prob. 9C.17ECh. 9 - Prob. 9C.18ECh. 9 - Prob. 9C.19ECh. 9 - Prob. 9C.20ECh. 9 - Prob. 9D.1ASTCh. 9 - Prob. 9D.1BSTCh. 9 - Prob. 9D.2ASTCh. 9 - Prob. 9D.2BSTCh. 9 - Prob. 9D.3ASTCh. 9 - Prob. 9D.3BSTCh. 9 - Prob. 9D.4ASTCh. 9 - Prob. 9D.4BSTCh. 9 - Prob. 9D.1ECh. 9 - Prob. 9D.2ECh. 9 - Prob. 9D.3ECh. 9 - Prob. 9D.4ECh. 9 - Prob. 9D.5ECh. 9 - Prob. 9D.6ECh. 9 - Prob. 9D.7ECh. 9 - Prob. 9D.8ECh. 9 - Prob. 9D.9ECh. 9 - Prob. 9D.10ECh. 9 - Prob. 9D.11ECh. 9 - Prob. 9D.12ECh. 9 - Prob. 9D.13ECh. 9 - Prob. 9D.14ECh. 9 - Prob. 9D.15ECh. 9 - Prob. 9D.16ECh. 9 - Prob. 9D.17ECh. 9 - Prob. 9D.18ECh. 9 - Prob. 9D.19ECh. 9 - Prob. 9D.20ECh. 9 - Prob. 9D.21ECh. 9 - Prob. 9D.22ECh. 9 - Prob. 9D.23ECh. 9 - Prob. 9D.24ECh. 9 - Prob. 9D.25ECh. 9 - Prob. 9D.26ECh. 9 - Prob. 9D.27ECh. 9 - Prob. 9D.28ECh. 9 - Prob. 9D.29ECh. 9 - Prob. 9D.30ECh. 9 - Prob. 9D.31ECh. 9 - Prob. 9D.32ECh. 9 - Prob. 9D.33ECh. 9 - Prob. 9D.34ECh. 9 - Prob. 9.1ECh. 9 - Prob. 9.2ECh. 9 - Prob. 9.3ECh. 9 - Prob. 9.4ECh. 9 - Prob. 9.5ECh. 9 - Prob. 9.6ECh. 9 - Prob. 9.7ECh. 9 - Prob. 9.8ECh. 9 - Prob. 9.9ECh. 9 - Prob. 9.10ECh. 9 - Prob. 9.11ECh. 9 - Prob. 9.12ECh. 9 - Prob. 9.13ECh. 9 - Prob. 9.14ECh. 9 - Prob. 9.15ECh. 9 - Prob. 9.16ECh. 9 - Prob. 9.17ECh. 9 - Prob. 9.18ECh. 9 - Prob. 9.19ECh. 9 - Prob. 9.20ECh. 9 - Prob. 9.21ECh. 9 - Prob. 9.23ECh. 9 - Prob. 9.25E
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- (a) Name this coordination compound: [Ag(NH3)2]NO3. (b) Write the formula of pentaaquaisothiocyanatoiron(III) chloride.arrow_forwardExplain how experimental determination of the number of geometric isomers of [Co(NH3)4Cl]2+ would enable you to demonstrate that the coordination geometry is octahedral and not trigonal prismatic.arrow_forwardWhen cobalt(II) chloride is treated, under certain condition, with the bidentate ligand, NH2CH2CH2NH2, (which can be represented by the symbol “en”), the compound [CoC12(en)2]Cl is formed. a. What is the coordination number of cobalt in this compound?arrow_forward
- Consider the compound (C8H8)Ru(CO)3 which is likely to be the best description of the C8H8 ligand ?arrow_forwardTrue or false: a. The metal center in cisplatin, cis-[PtCl2(NH3)2], has an oxidation state of 0 and a coordination number of 4. b. Thiocyanate (SCN–) and oxalate (C2O42–) ions are examples of bidentate ligands. c. Dichloridobis(ethylenediamine)chromium(III) has three stereoisomers but no structural isomers.arrow_forwardWrite the names of [Co(NH3)4CO3]NO3 . Write the name of the counter ion . What kind of isomerism is possible for a complex with the formula [Co(NH3)4Cl2]Cl?. Draw the structure of isomerism Give the name of [Co(NH3)5Cl]Cl2 and find out the oxidation number of central metal ion.arrow_forward
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- Determine the name of the following complexes and give the coordination number of the central metal atom.(a) Na2[PtCl6](b) K3[Fe(C2O4)3](c) [Co(NH3)5Cl]Cl2arrow_forwardWhen cobalt (II) chloride is treated, under certain conditions, with the bidentate ligand, NH2CH2CH2NH2, (which can be represented by the symbol “en”), the compound [CoC12(en)2] Cl is formed. i) What is the oxidation state of cobalt in the compound formed? ii) When this compound is treated with aqueous silver nitrate, only one mole of silver chloride is produced per mole of compound. Explain this observation.arrow_forward
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