(a)
Interpretation:
The member that rapidly undergoes
Concept Introduction:
The
The first step of
Frist step is the slow step also rate determining step so the rate of the reaction is depends on the concentration of substrate only.
Nucleophile attacks the both front and back side of carbocation in
Order of the substrate that favored in
(a)
Answer to Problem 9.25P
The member that rapidly undergoes
Explanation of Solution
Given:
In
2-chloro-2 methyl propane gives more stable carbocation than 1-chlorobutane.
Hence, the member that rapidly undergoes
(b)
Interpretation:
The member that rapidly undergoes
Concept Introduction:
The rate of the reaction is depends on a single reactant in reaction is known as
The first step of
Frist step is the slow step also rate determining step so the rate of the reaction is depends on the concentration of substrate only.
Nucleophile attacks the both front and back side of carbocation in
Order of the substrate that favored in
(b)
Answer to Problem 9.25P
The member that rapidly undergoes
Explanation of Solution
Given:
Bromine is better leaving group than chlorine.
Hence, the member that rapidly undergoes
(c)
Interpretation:
The member that rapidly undergoes
Concept Introduction:
The rate of the reaction is depends on a single reactant in reaction is known as
The first step of
Frist step is the slow step also rate determining step so the rate of the reaction is depends on the concentration of substrate only.
Nucleophile attacks the both front and back side of carbocation in
Order of the substrate that favored in
(c)
Answer to Problem 9.25P
The member that rapidly undergoes
Explanation of Solution
Given:
In
Allyl cation is more stable than primary cation.
Hence, the member that rapidly undergoes
(d)
Interpretation:
The member that rapidly undergoes
Concept Introduction:
The rate of the reaction is depends on a single reactant in reaction is known as
The first step of
Frist step is the slow step also rate determining step so the rate of the reaction is depends on the concentration of substrate only.
Nucleophile attacks the both front and back side of carbocation in
Order of the substrate that favored in
(d)
Answer to Problem 9.25P
The member that rapidly undergoes
Explanation of Solution
Given:
In
Substuted allyllic cation is more stable than allylic cation.
Hence, the member that rapidly undergoes
(e)
Interpretation:
The member that rapidly undergoes
Concept Introduction:
The rate of the reaction is depends on a single reactant in reaction is known as
The first step of
Frist step is the slow step also rate determining step so the rate of the reaction is depends on the concentration of substrate only.
Nucleophile attacks the both front and back side of carbocation in
Order of the substrate that favored in
(e)
Answer to Problem 9.25P
The member that rapidly undergoes
Explanation of Solution
Given:
In
2-chloropentane gives more stable carbocation than 1-chloropentane.
Hence, the member that rapidly undergoes
(f)
Interpretation:
The member that rapidly undergoes
Concept Introduction:
The rate of the reaction is depends on a single reactant in reaction is known as
The first step of
Frist step is the slow step also rate determining step so the rate of the reaction is depends on the concentration of substrate only.
Nucleophile attacks the both front and back side of carbocation in
Order of the substrate that favored in
(f)
Answer to Problem 9.25P
The member that rapidly undergoes
Explanation of Solution
Given:
In
Allylic cation is more stable than vinyl cation.
Hence, the member that rapidly undergoes
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Chapter 9 Solutions
EP ORGANIC CHEMISTRY-OWL V2 ACCESS
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- Rank the attached alkyl halides in order of increasing reactivity in E2elimination. Then do the same for E1 eliminationarrow_forwardWhich of the following reacts fastest with methanol by the SN1 mechanism?arrow_forwardWhich of the following will react fastest with sodium cyanide in an SN2 reaction?arrow_forward
- For each pair, predict the stronger nucleophile in the SN2 reaction (using an alcohol asthe solvent). Explain your prediction.(a) (CH3CH2)3N or (CH3CH2)2NHarrow_forwardWhich halide in the attached marine natural product reacts fastest in the SN1 reaction?arrow_forwardRank the alkyl halides in the following marine natural product in order of increasing reactivity in the SN1 reaction.arrow_forward
- Does ether cleavage following SN1 or SN2 ? Give your explanation.arrow_forwardwhat structure show the transition state for the rate determining step in the sn1 reaction with this picture?arrow_forwardcould someone help me by telling me which out of both of these pairs would react the fastest with an SN2 reaction and why? Thank you, I just need help with an explanation :)arrow_forward
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