Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 9, Problem 9.35E

Determine the speed of an electron being emitted by rubidium ( ϕ = 2 .16 eV ) when light of the following wavelengths is shined on the metal in vacuum: (a) 550 nm, (b) 450 nm, (c) 350 nm .

(a)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is to be stated.

Concept introduction:

The emission of electrons when the light is shone upon a material is called the photoelectric effect. The electrons emitted by such a method are also known as photo-electrons. The process basically involves shining light of frequency υ, on a metal surface to remove the electrons with a kinetic energy of 12mv2.

Answer to Problem 9.35E

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 1.8×105msec1.

Explanation of Solution

The given value of work function ϕ is 2.16 eV and λ is 550nm.

The formula to calculate the velocity of an electron is given below.

hcλ=ϕ+12mv2(1)

Where,

 h is the Planck’s Constant (6.6×1034 J sec)

 c is the speed of light (3.8×108 m sec1)

λ is the wavelength

 m is the mass of an electron

 v is the velocity of the emitted electron

 ϕ is the work function

It is known that, 1eV=1.6×1031J

Therefore,

2.16eV×1.6×1031J1eV=3.456×1019J

It is known that,

1nm =109m

Therefore,

550nm×1091nm=550×109nm

Rearrange equation (1) to calculate the value of velocity.

v=2m(hcλϕ)

Substitute the values of work function ϕ, Planck’s constant h, speed of light c, wavelength λ and mass of electron m in the above equation.

v=2(6.6×1034Jsec × 3×108msec1550×109m3.456×1019J)9.1×1031kgv=2(0.036×1017J0.03456×1017J)9.1×1031kgv=3.1536×1010m2sec2v=1.7758×105msec11.8×105

Therefore, the value of speed is 1.8×105 m sec1.

Conclusion

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 1.8×105 m sec1.

(b)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is to be stated.

Concept introduction:

The emission of electrons or other free electrons when the light is shone upon a material is called the photoelectric effect. The electrons emitted by such a method are also known as photo-electrons. The process basically, involves shining light of frequency υ, on a metal surface to remove the electrons with a kinetic energy of 12mv2.

Answer to Problem 9.35E

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 4.537×105 m sec1.

Explanation of Solution

The given value of work function ϕ is 2.16 eV and λ is 450nm.

The formula to calculate the velocity of an electron is given below.

hcλ=ϕ+12mv2(2)

Where,

 h is the Planck’s Constant (6.6×1034 J sec)

 c is the speed of light (3.8×108 m sec1)

 λ is the wavelength

 m is the mass of an electron

 v is the velocity of the emitted electron

 ϕ is the work function

It is known that,

1eV =1.6×1031 J

Therefore,

2.16 eV×1.6×1031 J1 eV=3.456×1019 J

It is known that,

1nm =109 m

Therefore,

450 nm ×1091 nm=450 ×109 nm

Rearrange equation (2) to calculate the value of velocity.

v=2m(hcλϕ)

Substitute the values of work function ϕ, Planck’s constant h, speed of light c, wavelength λ and mass of electron m in the above equation, we get-

v=2(6.6×1034 J sec × 3×108 m sec1450×109 m3.456×1019 J)9.1×1031kgv=2(0.044×1017 J0.03456×1017 J)9.1×1031 kgv=20.586×1010 m2 sec2v=4.537 × 105 m sec1

Therefore, the value of speed is 4.537×105 m sec1.

Conclusion

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 4.537×105 m sec1

(c)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is to be stated.

Concept introduction:

The emission of electrons when the light is shone upon a material is called the photoelectric effect. The electrons emitted by such a method are also known as photo-electrons. The process basically involves shining light of frequency υ, on a metal surface to remove the electrons with a kinetic energy of 12mv2.

Answer to Problem 9.35E

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 6.86×105 m sec1

Explanation of Solution

The given value of work function ϕ is 2.16 eV and λ is 350nm.

The formula to calculate the velocity of an electron is given below.

hcλ=ϕ+12mv2(3)

Where,

 h is the Planck’s Constant (6.6×1034 J sec)

 c is the speed of light (3.8×108 m sec1)

 λ is the wavelength

 m is the mass of an electron v is the velocity of the emitted electron

 ϕ is the work function

It is known that,

1eV =1.6×1031 J

Therefore,

2.16eV×1.6×1031 J1 eV=3.456×1019 J

It is known that,

1nm =109m

Therefore,

350 nm×1091 nm=350×109 nm

Rearrange equation (3) to calculate the value of velocity.

v=2m(hcλϕ)

Substitute the values of work function ϕ, Planck’s constant h, speed of light c, wavelength λ and mass of electron m in the above equation.

v=2(6.6×1034 J sec × 3×108 m sec1350×109 m3.456×1019 J)9.1×1031 kgv=2(0.05657×1017 J0.03456×1017 J)9.1×1031 kgv=48.37×1010 m2 sec2v=6.95×105 m sec17×105 m sec1

Therefore, the value of speed is 7×105msec1.

Conclusion

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 7×105 m sec1

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Chapter 9 Solutions

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