Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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You have 500 g of dry ice at a temperature of 50 K. How much energy would it take to produce carbon dioxide gas heated to a temperature of 400оC?
Specific heat of CO2(s) = 0.709 J/g K Specific heat of H2O(s) = 2.040 J/g K Specific heat of CO2(g) = 0.850 J/g K
Specific heat of H2O(l) = 4.184 J/g K
Specific heat of H2O(g) = 2.010 J/g K
Freezing point (CO2) = -78.5оC Freezing point (H2O) = 273.15 K
Latent heat of sublimation (CO2) = 199 J/g
Latent heat of fusion (H2O) = 334 J/g
Latent heat of vaporization (H2O) = 2260 J/g
. Based on what you have studied about intermolecular forces, predict which of the following liquid has the highest boiling point and why. All three compounds have comparable molecular weights.
Butane, C4H10 Propanol, C3H7OH . Acetone, CH3COCH3
You have samples of four compounds: dimethyl ether, methane, difluoromethane, and ethanol. You measure the boiling points of the compounds as -128 °C, -52 °C, -25 °C, and 78 °C, but then lose the labels for each sample. Make the following predictions Which compound boils at -128 °C?
Chapter 9 Solutions
Chemistry: An Atoms-Focused Approach
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- You have samples of four compounds: dimethyl ether, methane, difluoromethane, and ethanol. You measure the boiling points of the compounds as -128 °C, -52 °C, -25 °C, and 78 °C, but then lose the labels for each sample. Make the following predictions Which boils at 75°C?arrow_forwardNaphthalene is the main ingredient in mothballs and gives mothballs their characteristic smell. Mothballs are used to keep moths from eating wool. Naphthalene has an enthalpy of sublimation of 73 kJ/mol. If the mothballs are exposed to 25000 J of heat how many grams of naphthalene will be sublimed? (Molar Mass of naphthalene is 128.17 g/mol)arrow_forwardIt requires ____ kJ of heat to boil 7.5 grams of methanol (CH3OH) at its boiling point. The ΔHvap of methanol at its boiling point is 35.21 kJ/mol.arrow_forward
- Predict the relative boiling points of the substances in Figure 9 and rank these boiling points from the highest to the lowest. [The sign ~means approximately equal.] * a) B > D > A > C b) D > B > A > C c) C > B > A > D d) B > A ~ D > C e) The boiling points of these compounds cannot be compared with our current model.arrow_forwardThe following information is given for ethanol at 1 atm: Boiling point = 78.40°C Heat of vaporization = 200.0 cal/g Melting point = –114.5°C Heat of fusion = 26.04 cal/g Specific heat gas = 0.3418 cal/g°C Specific heat liquid = 0.5880 cal/g°C A 22.80 g sample of liquid ethanol is initially at –68.20°C. How many kcal of energy must be added to the sample to raise its temperature to 94.20°C? Energy added = kcalarrow_forwardWhat types of intermolecular forces are present in each compound: (a) HCl; (b) C 2H 6 (ethane); (c) NH 3?arrow_forward
- How much heat is needed to warm 250 g of water from 22°C to near its boiling point, 98°C? The specific heat of water is 4.184 J/g°Carrow_forwardHow many joules of heat are required to heat 25.2 g of ethyl alcohol from the prevailing room temperature, 22.5 oC, to its boiling point, 78.5 oC?arrow_forwardWhich of the following substances is a liquid at room temperature? A) CH₃CH₃ B) CH₃OH C) CH₄ D) HCl E) CF₄arrow_forward
- How much heat must be absorbed to warm 25.0g of liquid methanol (C= 2.53 J g/k) from 30° to its boiling point (64.6°C) and then to vaporize the methanol completely at its boiling point. Lv formethanol = 2.00x10^3 J/g.arrow_forwardExplain the term London forces.arrow_forwardUse the information provided to calculate the quantity of heat (in kJ) required to convert 70.912 g of substance B from an initial temperature of 134.625ºC to a final temperature of 71.6ºC. Report your answer to the tenths place and do not include units.Do not include a sign in your answer. The molar mass of the substance is 37.08 g/mol. melting point of B = 8.579ºC heat of fusion = 8.04 kJ/mol boiling point of B = 110.6ºC heat of vaporization = 63.48 kJ/mol solid liquid gas specific heat (J/gºC) 2.475 4.552 6.565arrow_forward
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