Concept explainers
(a)
Interpretation:
For the given reaction, the major product is to be determined. The complete, detailed mechanism is to be drawn.
Concept introduction:
When the attacking species is an alcohol which is a weak base and weak nucleophile, it favors
Answer to Problem 9.81P
The complete, detailed mechanism and the major product for the given reaction is shown below:
Explanation of Solution
The given reacting species are shown below:
In the given reaction, attacking species is an alcohol which is a weak nucleophile. Also, the leaving group can be water under acidic conditions which is an excellent leaving group. Also, the solvent is an alcohol. Therefore, the given reaction favors
The complete, detailed mechanism and the major product for the given reaction is drawn on the basis of reacting species.
(b)
Interpretation:
For the given reaction, the major product is to be determined. The complete, detailed mechanism is to be drawn.
Concept introduction:
When attacking species is an alcohol which is a weak base and weak nucleophile, it favors
Answer to Problem 9.81P
The complete, detailed mechanism and the major product for the given reaction is shown below:
Explanation of Solution
The given reacting species are shown below,
In the given reaction, attacking species is an alcohol which is a weak nucleophile. Also, the leaving group can be water under acidic conditions which is an excellent leaving group. Also, the solvent is an alcohol. Therefore, the given reaction favors
The complete, detailed mechanism and the major product for the given reaction are drawn on the basis of reacting species.
(c)
Interpretation:
For the given reaction, the major product is to be determined. The complete, detailed mechanism is to be drawn.
Concept introduction:
When attacking species is an alcohol which is a weak base and weak nucleophile, it favors
Answer to Problem 9.81P
The complete, detailed mechanism and the major product for the given reaction is shown below:
Explanation of Solution
The given reacting species are shown below,
In the given reaction, attacking species is an alcohol which is a weak nucleophile. Also, the leaving group can be water under acidic conditions which is an excellent leaving group. Also, the solvent is an alcohol. Therefore, the given reaction favors
The complete, detailed mechanism and the major product for the given reaction are drawn on the basis of reacting species.
(d)
Interpretation:
The major product of the given reaction is to be determined. The complete, detailed mechanism is to be drawn.
Concept introduction:
When attacking species is an alcohol which is a weak base and weak nucleophile, it favors
Answer to Problem 9.81P
The complete, detailed mechanism and the major product for the given reaction is shown below,
Explanation of Solution
The given reacting species are shown below,
In the given reaction, attacking species is an alcohol which is a weak nucleophile. Also, the leaving group can be water under acidic conditions which is an excellent leaving group. Also, the solvent is an alcohol. Therefore, the given reaction favors
The complete, detailed mechanism and the major product for given reaction are drawn on the basis of reacting species.
(e)
Interpretation:
For the given reaction, the major product is to be determined. The complete, detailed mechanism is to be drawn.
Concept introduction:
The strong nucleophile and weak base favors
Answer to Problem 9.81P
The complete, detailed mechanism and product of the given reaction is as shown below:
Explanation of Solution
The given reacting species are shown below,
The Br- is a strong nucleophile but a weak base that favors
The complete, detailed mechanism and the major product for the given reaction are drawn on the basis of reacting species.
(f)
Interpretation:
For the given reaction, the major product is to be determined. The complete, detailed mechanism is to be drawn.
Concept introduction:
If the attacking species is a strong bulky base but has low concentration it favors
Answer to Problem 9.81P
The complete, detailed mechanism and the products of the given reaction are shown below,
Explanation of Solution
The given reacting species are shown below,
In the given reaction, the attacking species is a strong bulky base so it favors
The complete, detailed mechanism and the major product for the given reaction is drawn on the basis of reacting species.
(g)
Interpretation:
For the given reaction, the major product is to be determined. The complete, detailed mechanism is to be drawn.
Concept introduction:
When attacking species is an alcohol which is a weak base and weak nucleophile, it favors
Answer to Problem 9.81P
The complete, detailed mechanism and the major product for the given reaction is shown below,
Explanation of Solution
The given reacting species are shown below:
In the given reaction, attacking species is a weak nucleophile and weak base. Also, the leaving group
The complete, detailed mechanism and the major product for the given reaction are drawn on the basis of reacting species.
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Chapter 9 Solutions
ORGANIC CHEMISTRY:PRINCIPLES...(CL)
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- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning