GEN, ORG & BIOL CHEM: CUSTOM SSC
GEN, ORG & BIOL CHEM: CUSTOM SSC
5th Edition
ISBN: 9781307274448
Author: SMITH
Publisher: MCG CUSTOM
Question
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Chapter 9, Problem 9.9P

(a)

Interpretation Introduction

Interpretation:

Considering vapor-compression refrigeration cycle and different thermodynamic processes taking place between two stages, the circulation rate of refrigerant, the heat transfer rate in the condenser, the power requirement, the coefficient of performance of the cycle and the coefficient of performance of a Carnot refrigeration cycle are to be calculated.

Concept introduction:

Below shown diagram represents vapor-compression refrigeration cycle on a TS diagram which include four steps of the cycle. Line 12 shows a liquid which is evaporating at constant pressure and providing a means for heat absorption at constant low temperature. The vapor thus produced is then compressed to a higher pressure. It is then cooled and condensed at higher temperature by heat rejection. By an expansion process, the liquid from the condenser is returned to its original pressure. This process is carried out by throttling through a partly open valve. Due to the fluid friction in the valve there is pressure drop in this irreversible process.

The line 41 represents throttling process which occurs at constant enthalpy. The path of isentropic compression is shown by line 23' and the actual compression is shown by the line 23 where the direction of slope is in increasing enthalpy which reflects inherent irreversibility.

GEN, ORG & BIOL CHEM: CUSTOM SSC, Chapter 9, Problem 9.9P , additional homework tip  1

The equations used to calculate the heat absorbed in evaporator and the heat rejected in condenser are:

|QC|=H2H1 ...... (1)

  |QH|=H3H4 ...... (2)

The work of compression is:

W=H3H2 ...... (3)

The coefficient of performance is:

ω=H2H1H3H2 ...... (4)

The rate of circulation of refrigerant, m˙ is determined from the rate of heat absorption in the evaporator given by the equation:

m˙=|Q˙C|H2H1 ...... (5)

For Carnot refrigeration cycle, highest possible value of ω is attained at the given values of TC and TH . Due to irreversible expansion in a throttle valve and irreversible compression in the vapor-compression cycle, lower values of ω is obtained.

(a)

Expert Solution
Check Mark

Answer to Problem 9.9P

  m˙=3.689 kg/sQ˙H=849.28 kJ/sW˙=249.34 kWω=2.406ωCarnot=10.51

Explanation of Solution

Given information:

The refrigerant is tetrafluoroethene.

Evaporation T=0C

Condensation T=26C

η=0.79 for compressor

Refrigeration rate is 600 kJ/s

The given data for the vapor-compression cycle are:

  TC=0C=273.15 KTH=26C=299.15 Kη=0.79Q˙C=600 kJ/s

From table 9.1, the values of H2, and S2 for the saturated tetrafluoroethene are:

  H2=398.60 kJ/kgS2=1.727 kJ/(kgK)

For isentropic compression,

  S3=S2=1.727 kJ/(kgK)

The saturation pressure at point 4 is the pressure at which the vapor condenses which is TH=26C and H4 at this point is:

  Psat=6.854 barH4=235.97 kJ/kg

At point 3 , the thermodynamic state properties are defines using the saturation pressure. From figure F.2 of appendix F, follow the constant enthalpy curve of 1.727 kJ/(kgK) to get the enthalpy H3 at pressure 6.854 bar as:

  H3=452 kJ/kg

Calculate the value of ΔH23 as:

  ΔH23= H 3H2η=452398.600.79=67.59 kJ/kg

Now, calculate H3 as:

  H3=H2+ΔH23=398.60+67.59=466.19 kJ/kg

Also,

  H1=H4=235.97 kJ/kg

Use equation (5) to calculate the value of m˙ as:

  m˙=| Q ˙ C|H2H1=|600|398.60235.97=3.689 kg/s

Use equation (2) to calculate the value of Q˙H as:

  Q˙H=m˙(H3H4)=(3.689)(466.19235.97)=849.28 kJ/s

Since, Q˙H is the heat rejected, negative sign is used. Thus,

  Q˙H=849.28 kJ/s

The work done is calculated as:

  W˙=m˙×ΔH23=3.689×67.59=249.34 kW

Use equation (5) to calculate the coefficient of performance for vapor-compression cycle as:

  ω=H2H1H3H2=398.60235.97466.19398.60=2.406

For Carnot cycle, the coefficient of performance is calculated as:

  ωCarnot=TCTHTC=273.15299.15273.15=10.51

(b)

Interpretation Introduction

Interpretation:

Considering vapor-compression refrigeration cycle and different thermodynamic processes taking place between two stages, the circulation rate of refrigerant, the heat transfer rate in the condenser, the power requirement, the coefficient of performance of the cycle and the coefficient of performance of a Carnot refrigeration cycle are to be calculated.

Concept introduction:

Below shown diagram represents vapor-compression refrigeration cycle on a TS diagram which include four steps of the cycle. Line 12 shows a liquid which is evaporating at constant pressure and providing a means for heat absorption at constant low temperature. The vapor thus produced is then compressed to a higher pressure. It is then cooled and condensed at higher temperature by heat rejection. By an expansion process, the liquid from the condenser is returned to its original pressure. This process is carried out by throttling through a partly open valve. Due to the fluid friction in the valve there is pressure drop in this irreversible process.

The line 41 represents throttling process which occurs at constant enthalpy. The path of isentropic compression is shown by line 23' and the actual compression is shown by the line 23 where the direction of slope is in increasing enthalpy which reflects inherent irreversibility.

GEN, ORG & BIOL CHEM: CUSTOM SSC, Chapter 9, Problem 9.9P , additional homework tip  2

The equations used to calculate the heat absorbed in evaporator and the heat rejected in condenser are:

|QC|=H2H1 ...... (1)

  |QH|=H3H4 ...... (2)

The work of compression is:

W=H3H2 ...... (3)

The coefficient of performance is:

ω=H2H1H3H2 ...... (4)

The rate of circulation of refrigerant, m˙ is determined from the rate of heat absorption in the evaporator given by the equation:

m˙=|Q˙C|H2H1 ...... (5)

For Carnot refrigeration cycle, highest possible value of ω is attained at the given values of TC and TH . Due to irreversible expansion in a throttle valve and irreversible compression in the vapor-compression cycle, lower values of ω is obtained.

(b)

Expert Solution
Check Mark

Answer to Problem 9.9P

  m˙=3.01 kg/sQ˙H=689.561 kJ/sW˙=189.63 kWω=2.363ωCarnot=13.958

Explanation of Solution

Given information:

The refrigerant is tetrafluoroethene.

Evaporation T=6C

Condensation T=26C

η=0.78 for compressor

Refrigeration rate is 500 kJ/s

The given data for the vapor-compression cycle are:

  TC=6C=279.15 KTH=26C=299.15 Kη=0.78Q˙C=500 kJ/s

From table 9.1, the values of H2, and S2 for the saturated tetrafluoroethene are:

  H2=402.06 kJ/kgS2=1.724 kJ/(kgK)

For isentropic compression,

  S3=S2=1.724 kJ/(kgK)

The saturation pressure at point 4 is the pressure at which the vapor condenses which is TH=26C and H4 at this point is:

  Psat=6.854 barH4=235.97 kJ/kg

At point 3 , the thermodynamic state properties are defines using the saturation pressure. From figure F.2 of appendix F, follow the constant enthalpy curve of 1.724 kJ/(kgK) to get the enthalpy H3 at pressure 6.854 bar as:

  H3=451.2 kJ/kg

Calculate the value of ΔH23 as:

  ΔH23= H 3H2η=451.2402.060.78=63 kJ/kg

Now, calculate H3 as:

  H3=H2+ΔH23=402.06+63=465.06 kJ/kg

Also,

  H1=H4=235.97 kJ/kg

Use equation (5) to calculate the value of m˙ as:

  m˙=| Q ˙ C|H2H1=|500|402.06235.97=3.01 kg/s

Use equation (2) to calculate the value of Q˙H as:

  Q˙H=m˙(H3H4)=(3.01)(465.06235.97)=689.561 kJ/s

Since, Q˙H is the heat rejected, negative sign is used. Thus,

  Q˙H=689.561 kJ/s

The work done is calculated as:

  W˙=m˙×ΔH23=3.01×63=189.63 kW

Use equation (5) to calculate the coefficient of performance for vapor-compression cycle as:

  ω=H2H1H3H2=402.06235.97465.06402.06=2.636

For Carnot cycle, the coefficient of performance is calculated as:

  ωCarnot=TCTHTC=279.15299.15279.15=13.958

(c)

Interpretation Introduction

Interpretation:

Considering vapor-compression refrigeration cycle and different thermodynamic processes taking place between two stages, the circulation rate of refrigerant, the heat transfer rate in the condenser, the power requirement, the coefficient of performance of the cycle and the coefficient of performance of a Carnot refrigeration cycle are to be calculated.

Concept introduction:

Below shown diagram represents vapor-compression refrigeration cycle on a TS diagram which include four steps of the cycle. Line 12 shows a liquid which is evaporating at constant pressure and providing a means for heat absorption at constant low temperature. The vapor thus produced is then compressed to a higher pressure. It is then cooled and condensed at higher temperature by heat rejection. By an expansion process, the liquid from the condenser is returned to its original pressure. This process is carried out by throttling through a partly open valve. Due to the fluid friction in the valve there is pressure drop in this irreversible process.

The line 41 represents throttling process which occurs at constant enthalpy. The path of isentropic compression is shown by line 23' and the actual compression is shown by the line 23 where the direction of slope is in increasing enthalpy which reflects inherent irreversibility.

GEN, ORG & BIOL CHEM: CUSTOM SSC, Chapter 9, Problem 9.9P , additional homework tip  3

The equations used to calculate the heat absorbed in evaporator and the heat rejected in condenser are:

|QC|=H2H1 ...... (1)

  |QH|=H3H4 ...... (2)

The work of compression is:

W=H3H2 ...... (3)

The coefficient of performance is:

ω=H2H1H3H2 ...... (4)

The rate of circulation of refrigerant, m˙ is determined from the rate of heat absorption in the evaporator given by the equation:

m˙=|Q˙C|H2H1 ...... (5)

For Carnot refrigeration cycle, highest possible value of ω is attained at the given values of TC and TH . Due to irreversible expansion in a throttle valve and irreversible compression in the vapor-compression cycle, lower values of ω is obtained.

(c)

Expert Solution
Check Mark

Answer to Problem 9.9P

  m˙=2.572 kg/sQ˙H=634.875 kJ/sW˙=234.954 kWω=1.702ωCarnot=6.87

Explanation of Solution

Given information:

The refrigerant is tetrafluoroethene.

Evaporation T=12C

Condensation T=26C

η=0.77 for compressor

Refrigeration rate is 400 kJ/s

The given data for the vapor-compression cycle are:

  TC=12C=261.15 KTH=26C=299.15 Kη=0.77Q˙C=400 kJ/s

From table 9.1, the values of H2, and S2 for the saturated tetrafluoroethene are:

  H2=391.46 kJ/kgS2=1.735 kJ/(kgK)

For isentropic compression,

  S3=S2=1.735 kJ/(kgK)

The saturation pressure at point 4 is the pressure at which the vapor condenses which is TH=26C and H4 at this point is:

  Psat=6.854 barH4=235.97 kJ/kg

At point 3 , the thermodynamic state properties are defines using the saturation pressure. From figure F.2 of appendix F, follow the constant enthalpy curve of 1.735 kJ/(kgK) to get the enthalpy H3 at pressure 6.854 bar as:

  H3=461.8 kJ/kg

Calculate the value of ΔH23 as:

  ΔH23= H 3H2η=461.8391.460.77=91.351 kJ/kg

Now, calculate H3 as:

  H3=H2+ΔH23=391.46+91.351=482.811 kJ/kg

Also,

  H1=H4=235.97 kJ/kg

Use equation (5) to calculate the value of m˙ as:

  m˙=| Q ˙ C|H2H1=|400|391.46235.97=2.572 kg/s

Use equation (2) to calculate the value of Q˙H as:

  Q˙H=m˙(H3H4)=(2.572)(482.811235.97)=634.875 kJ/s

Since, Q˙H is the heat rejected, negative sign is used. Thus,

  Q˙H=634.875 kJ/s

The work done is calculated as:

  W˙=m˙×ΔH23=2.572×91.351=234.954 kW

Use equation (5) to calculate the coefficient of performance for vapor-compression cycle as:

  ω=H2H1H3H2=391.46235.97482.811391.46=1.702

For Carnot cycle, the coefficient of performance is calculated as:

  ωCarnot=TCTHTC=261.15299.15261.15=6.87

(d)

Interpretation Introduction

Interpretation:

Considering vapor-compression refrigeration cycle and different thermodynamic processes taking place between two stages, the circulation rate of refrigerant, the heat transfer rate in the condenser, the power requirement, the coefficient of performance of the cycle and the coefficient of performance of a Carnot refrigeration cycle are to be calculated.

Concept introduction:

Below shown diagram represents vapor-compression refrigeration cycle on a TS diagram which include four steps of the cycle. Line 12 shows a liquid which is evaporating at constant pressure and providing a means for heat absorption at constant low temperature. The vapor thus produced is then compressed to a higher pressure. It is then cooled and condensed at higher temperature by heat rejection. By an expansion process, the liquid from the condenser is returned to its original pressure. This process is carried out by throttling through a partly open valve. Due to the fluid friction in the valve there is pressure drop in this irreversible process.

The line 41 represents throttling process which occurs at constant enthalpy. The path of isentropic compression is shown by line 23' and the actual compression is shown by the line 23 where the direction of slope is in increasing enthalpy which reflects inherent irreversibility.

GEN, ORG & BIOL CHEM: CUSTOM SSC, Chapter 9, Problem 9.9P , additional homework tip  4

The equations used to calculate the heat absorbed in evaporator and the heat rejected in condenser are:

|QC|=H2H1 ...... (1)

  |QH|=H3H4 ...... (2)

The work of compression is:

W=H3H2 ...... (3)

The coefficient of performance is:

ω=H2H1H3H2 ...... (4)

The rate of circulation of refrigerant, m˙ is determined from the rate of heat absorption in the evaporator given by the equation:

m˙=|Q˙C|H2H1 ...... (5)

For Carnot refrigeration cycle, highest possible value of ω is attained at the given values of TC and TH . Due to irreversible expansion in a throttle valve and irreversible compression in the vapor-compression cycle, lower values of ω is obtained.

(d)

Expert Solution
Check Mark

Answer to Problem 9.9P

  m˙=1.976 kg/sQ˙H=509.08 kJ/sW˙=209.08 kWω=1.43ωCarnot=5.799

Explanation of Solution

Given information:

The refrigerant is tetrafluoroethene.

Evaporation T=18C

Condensation T=26C

η=0.76 for compressor

Refrigeration rate is 300 kJ/s

The given data for the vapor-compression cycle are:

  TC=18C=255.15 KTH=26C=299.15 Kη=0.76Q˙C=300 kJ/s

From table 9.1, the values of H2, and S2 for the saturated tetrafluoroethene are:

  H2=387.79 kJ/kgS2=1.740 kJ/(kgK)

For isentropic compression,

  S3=S2=1.740 kJ/(kgK)

The saturation pressure at point 4 is the pressure at which the vapor condenses which is TH=26C and H4 at this point is:

  Psat=6.854 barH4=235.97 kJ/kg

At point 3 , the thermodynamic state properties are defines using the saturation pressure. From figure F.2 of appendix F, follow the constant enthalpy curve of 1.740 kJ/(kgK) to get the enthalpy H3 at pressure 6.854 bar as:

  H3=468.2 kJ/kg

Calculate the value of ΔH23 as:

  ΔH23= H 3H2η=468.2387.790.76=105.81 kJ/kg

Now, calculate H3 as:

  H3=H2+ΔH23=387.79+105.81=493.6 kJ/kg

Also,

  H1=H4=235.97 kJ/kg

Use equation (5) to calculate the value of m˙ as:

  m˙=| Q ˙ C|H2H1=|300|387.79235.97=1.976 kg/s

Use equation (2) to calculate the value of Q˙H as:

  Q˙H=m˙(H3H4)=(1.976)(493.6235.97)=509.08 kJ/s

Since, Q˙H is the heat rejected, negative sign is used. Thus,

  Q˙H=509.08 kJ/s

The work done is calculated as:

  W˙=m˙×ΔH23=1.976×105.81=209.08 kW

Use equation (5) to calculate the coefficient of performance for vapor-compression cycle as:

  ω=H2H1H3H2=387.79235.97493.6387.79=1.43

For Carnot cycle, the coefficient of performance is calculated as:

  ωCarnot=TCTHTC=255.15299.15255.15=5.799

(e)

Interpretation Introduction

Interpretation:

Considering vapor-compression refrigeration cycle and different thermodynamic processes taking place between two stages, the circulation rate of refrigerant, the heat transfer rate in the condenser, the power requirement, the coefficient of performance of the cycle and the coefficient of performance of a Carnot refrigeration cycle are to be calculated.

Concept introduction:

Below shown diagram represents vapor-compression refrigeration cycle on a TS diagram which include four steps of the cycle. Line 12 shows a liquid which is evaporating at constant pressure and providing a means for heat absorption at constant low temperature. The vapor thus produced is then compressed to a higher pressure. It is then cooled and condensed at higher temperature by heat rejection. By an expansion process, the liquid from the condenser is returned to its original pressure. This process is carried out by throttling through a partly open valve. Due to the fluid friction in the valve there is pressure drop in this irreversible process.

The line 41 represents throttling process which occurs at constant enthalpy. The path of isentropic compression is shown by line 23' and the actual compression is shown by the line 23 where the direction of slope is in increasing enthalpy which reflects inherent irreversibility.

GEN, ORG & BIOL CHEM: CUSTOM SSC, Chapter 9, Problem 9.9P , additional homework tip  5

The equations used to calculate the heat absorbed in evaporator and the heat rejected in condenser are:

|QC|=H2H1 ...... (1)

  |QH|=H3H4 ...... (2)

The work of compression is:

W=H3H2 ...... (3)

The coefficient of performance is:

ω=H2H1H3H2 ...... (4)

The rate of circulation of refrigerant, m˙ is determined from the rate of heat absorption in the evaporator given by the equation:

m˙=|Q˙C|H2H1 ...... (5)

For Carnot refrigeration cycle, highest possible value of ω is attained at the given values of TC and TH . Due to irreversible expansion in a throttle valve and irreversible compression in the vapor-compression cycle, lower values of ω is obtained.

(e)

Expert Solution
Check Mark

Answer to Problem 9.9P

  m˙=1.356 kg/sQ˙H=269.63 kJ/sW˙=69.64 kWω=2.87ωCarnot=4.87

Explanation of Solution

Given information:

The refrigerant is tetrafluoroethene.

Evaporation T=25C

Condensation T=26C

η=0.75 for compressor

Refrigeration rate is 200 kJ/s

The given data for the vapor-compression cycle are:

  TC=25C=248.15 KTH=26C=299.15 Kη=0.75Q˙C=200 kJ/s

From table 9.1, the values of H2, and S2 for the saturated tetrafluoroethene are:

  H2=383.45 kJ/kgS2=1.746 kJ/(kgK)

For isentropic compression,

  S3=S2=1.746 kJ/(kgK)

The saturation pressure at point 4 is the pressure at which the vapor condenses which is TH=26C and H4 at this point is:

  Psat=6.854 barH4=235.97 kJ/kg

At point 3 , the thermodynamic state properties are defines using the saturation pressure. From figure F.2 of appendix F, follow the constant enthalpy curve of 1.727 kJ/(kgK) to get the enthalpy H3 at pressure 6.854 bar as:

  H3=421.97 kJ/kg

Calculate the value of ΔH23 as:

  ΔH23= H 3H2η=421.97383.450.75=51.36 kJ/kg

Now, calculate H3 as:

  H3=H2+ΔH23=383.45+51.36=434.81 kJ/kg

Also,

  H1=H4=235.97 kJ/kg

Use equation (5) to calculate the value of m˙ as:

  m˙=| Q ˙ C|H2H1=|200|383.45235.97=1.356 kg/s

Use equation (2) to calculate the value of Q˙H as:

  Q˙H=m˙(H3H4)=(1.356)(434.81235.97)=269.63 kJ/s

Since, Q˙H is the heat rejected, negative sign is used. Thus,

  Q˙H=269.63 kJ/s

The work done is calculated as:

  W˙=m˙×ΔH23=1.356×51.36=69.64 kW

Use equation (5) to calculate the coefficient of performance for vapor-compression cycle as:

  ω=H2H1H3H2=383.45235.97434.81383.45=2.87

For Carnot cycle, the coefficient of performance is calculated as:

  ωCarnot=TCTHTC=248.15299.15248.15=4.87

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