Concept explainers
(a)
Interpretation:
From the given species better nucleophile in the given solvent has to be identified.
Concept Introduction:
- Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
- Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen.
- The stronger base is always a better nucleophile in an aprotic solvent.
(b)
Interpretation:
From the given species better nucleophile in the given solvent has to be identified.
Concept Introduction:
- Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
- Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen.
- The stronger base is always a better nucleophile in an aprotic solvent.
(c)
Interpretation:
From the given species better nucleophile in the given solvent has to be identified.
Concept Introduction:
- Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
- Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
- The stronger base is always a better nucleophile in an aprotic solvent.
(d)
Interpretation:
From the given species better nucleophile in the given solvent has to be identified.
Concept Introduction:
- Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
- Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
- The stronger base is always a better nucleophile in an aprotic solvent.
(e)
Interpretation:
From the given species better nucleophile in the given solvent has to be identified.
Concept Introduction:
- Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
- Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
- The stronger base is always a better nucleophile in an aprotic solvent.
(f)
Interpretation:
From the given species better nucleophile in the given solvent has to be identified.
Concept Introduction:
- Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
- Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
- The stronger base is always a better nucleophile in an aprotic solvent.
(g)
Interpretation:
From the given species better nucleophile in the given solvent has to be identified.
Concept Introduction:
- Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
- Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
- The stronger base is always a better nucleophile in an aprotic solvent.
(h)
Interpretation:
From the given species better nucleophile in the given solvent has to be identified.
Concept Introduction:
- Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
- Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen
- The stronger base is always a better nucleophile in an aprotic solvent.
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Check out a sample textbook solutionChapter 9 Solutions
Organic Chemistry (8th Edition)
- Rank the nucleophiles in each group in order of increasing nucleophilicity.a. -OH, -NH2, H2Ob. -OH, Br-, F- (polar aprotic solvent)c. H2O, -OH, CH3CO2-arrow_forwardRank the nucleophiles in each group in order of increasing nucleophilicity. a.−OH, −NH2, H2O b.−OH, Br−, F− (polar aprotic solvent) c.H2O, −OH, CH3CO2−arrow_forwardFrom each pair, select the stronger nucleophile. Q.)Cl- or I- in DMSOarrow_forward
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