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EBK ORGANIC CHEMISTRY
12th Edition
ISBN: 9781119233664
Author: Snyder
Publisher: VST
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Textbook Question
Chapter E, Problem 7PP
Practice Problem E.7
A typical polyurethane can be made in the following way. Adipic acid is
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PROBLEM F.3 Draw the structure for each of the following molecules.
(a) 4-chlorocarbonylbutanoic acid; (b)
(c) (Z)-2,3-dimethylhex-2-enedinitrile;
(R)-4-hydroxy-N-methyl-5-phenylpentanamide;
(d) 2-carboxy-1,4-butanedioic acid
PROBLEM F.9 Draw the molecules that correspond to the following IUPAC
names. (a) Pentyl pentanoate; (b) propyl butanoate; (c) ethyl methanoate;
(d) ethyl (Z)-3-methylpent-2-enoate; (e) (R)-3-chlorobutyl (S)-2-hydroxypropanoate
List the following group of monomers in order of decreasing ability to undergo cationic polymerization.
Chapter E Solutions
EBK ORGANIC CHEMISTRY
Ch. E - Prob. 1PPCh. E - Practice Problem E.2
Transesterifications are...Ch. E - Practice Problem E.3
Kodel is another polyester...Ch. E - Practice Problem E.4 Heating phthalic anhydride...Ch. E - Prob. 5PPCh. E - Practice Problem E.6
The familiar “epoxy resins”...Ch. E - Practice Problem E.7 A typical polyurethane can be...Ch. E - Practice Problem E.8
Using a para-substituted...Ch. E - Practice Problem E.9
Outline a general mechanism...
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- What product is obtained from ring-opening metathesis polymerization of each of the following compounds? (Hint: In each case, the product is an unsaturated hydrocarbon with a high molecular weight.)arrow_forwardRank the following groups of monomers from most able to least able to undergo anionic polymerizationarrow_forwardA3 Anionic polymerization of styrene is generally known to produce polymers with a narrow molecular weight distribution. Explain the reason for this.arrow_forward
- 6. Dacron is the brand name for the polymer that is made from ethane-1,2-diol and benzene-1,4-dicarboxylic acid. (a) When the two monomers combine, what type of reaction do they undergo and what molecule is eliminated? [1] (b) What is the name for the linkages that join the monomers together? [1] (c) Draw the monomers and the polymer of the reaction to create Dacron. [3]arrow_forwardCompound A underwent the three reactions as shown in the scheme below to form the products B, C and D. The formula for each compound is given underneath the letter. Draw the structures for each compound, A, B, C and D.arrow_forward(a) Explain why poly(vinyl alcohol) cannot be prepared by the radical polymerization of vinyl alcohol (CH2=CHOH). (b) Devise a stepwise synthesis of poly(vinyl alcohol) from vinyl acetate (CH2=CHOCOCH3). (c) How can poly(vinyl alcohol) be converted to poly(vinyl butyral), a polymer used in windshield safety glass?arrow_forward
- Draw the structure of each of the following molecules. (a) cyclohexyl butanoate; (b) 1,1-dimethylethyl hexanoate; (c) phenyl 4,4-dinitroheptanoatearrow_forwardPredict the product of the following polymerization reactions. (Show only one repeating unit of the polymer in each reaction.)arrow_forward(a) Draw a specific organic reaction for the hydration addition reaction of alkenes. (b) Also write the reagents involved in the reaction (c) and name and identify its major and minor product by writing its IUPAC name.arrow_forward
- devise synthesiz fllowing compounds. assum that the izomer can be separatedarrow_forward(a) Draw a specific organic reaction for the hydrohalogenation addition reaction of alkenes. (b) Also write the reagents involved in the reaction (c) and name and identify its major and minor product by writing its IUPAC name.arrow_forwardExcercise 2 Chloromethane reacts with hydroxide ion to form methanol as shown in the equation below. OH + CH3CI - CH3OH + CI- (a) Identify the nucleophile and electrophile. (b) State the type of reaction.arrow_forward
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