(a) Interpretation: The structure from the given IUPAC name with appropriate stereochemistry is to be drawn. Concept introduction: The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group . The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms. The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1 → 2 → 3 is clockwise, the absolute configuration is R , and if it is counterclockwise, the absolute configuration is S .

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Answer 1

Question

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Draw the structures for each of the following molecules. (a) 2-fluorotoluene; (b) 4-ethoxytoluene; (c) 2-ethoxyanisole;(d) 1,3-diphenylheptane; (e) 4,4-diphenyl-1-octene; (f) benzylbenzene

Draw the structure that corresponds to each of the following names. (a) 4-methyl-1-neopentylcyclohexane;(b) isobutylcyclobutane; (c) 5-sec-butylnonane

Given each of the IUPAC names provided, draw the corresponding structure. (a) 1-ethoxy-3-methoxyhexane;(b) 1,5-dipropoxypentane; (c) 4-butoxy-1,2-dimethoxyheptane

Answer 2

Question

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Answer 3

Question

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Answer 4

Question

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

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Answer 5

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 6

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 7

Chapter E, Problem E.15P

Interpretation Introduction

(a)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name, in the given IUPAC name, suggests that the main chain or ring of carbon atoms in the compound. The suffix to the root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in parenthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of atomic number of directly bonded atoms. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name with appropriate stereochemistry is to be drawn.

Concept introduction:

The root name in the given IUPAC name suggests that the main chain or ring of carbon atoms in the compound. The suffix to root name indicates the highest priority functional group. The prefix with locant number indicates the number of substituents and their respective position at the main chain or at a ring of carbon atoms.

The stereochemical designation and the locators are enclosed in paranthesis at the very beginning of the name. The stereochemistry at the chiral center is determined by assigning the priorities to the groups attached to chiral center on the basis of the atomic number of directly bonded atom. If the sequence of priority order 1→2→3 is clockwise, the absolute configuration is R, and if it is counterclockwise, the absolute configuration is S.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The structure of the given IUPAC name with appropriate stereochemistry is drawn. The root name indicates the main chain or ring of carbon atoms in the compound.

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Chapter E Solutions