ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
12th Edition
ISBN: 9781119664635
Author: Solomons
Publisher: WILEY
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter FRP, Problem 3P
Interpretation Introduction
Interpretation:
The products formed from each of the given acid–base reactions are to be written.
Concept introduction:
舧 Acids are the substance that accepts a proton and form conjugate base.
舧 Bases are the substance that donates a proton and form conjugate acid.
舧 In acid–base reaction, acid and base react to form salt and water.
舧 The
舧 When sodium ethoxide reacts with phenol in acidic medium to form sodium phenoxide and ethanol as a side product.
舧 When sodium hydroxide reacts with phenol, formation of sodium phenoxide and water as a side product takes place.
舧 When sodium phenoxide reacts with the hydrochloric acid, formation of phenol and sodium chloride takes place.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
(a) Give chemical tests to distinguish between the following pairs of compounds :(i) Ethanal and Propanal (ii) Phenol and Benzoic acid(b) How will you bring about the following conversions?(i) Benzoic acid to benzaldehyde (ii) Ethanal to but-2-enal (iii) Propanone to propeneGive complete reaction in each case.
1) The carbon-oxygen double bond present in aldehydes and ketones is very polar. What does this mean and how does it arise?
2) The carbon-oxygen double bond is readily attacked by nucleophiles like cyanide ions or ammonia.
(i) What do you understand by the term nucleophile?
(ii) Which part of the carbon-oxygen double bond is attractive to nucleophiles?
3) Why is there a difference between aldehydes and ketones in their response to oxidizing agents such as potassium dichromate(VI) solution acidified with dilute sulfuric acid?
(a) Give chemical tests to distinguish between(i) Phenol and Benzoic acid (ii) Benzophenone and Acetophenone
Chapter FRP Solutions
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
Ch. FRP - Prob. 1PCh. FRP - 2. Which member of these pairs is the more polar?...Ch. FRP - Prob. 3PCh. FRP - Describe how solubility could be used to...Ch. FRP - 5. Though they each contain only one type of...Ch. FRP - Predict the products from each of the following...Ch. FRP - Prob. 7PCh. FRP - Prob. 8PCh. FRP - Prob. 9PCh. FRP - Prob. 10P
Ch. FRP - Predict the products from each of the following...Ch. FRP - Prob. 12PCh. FRP - 13. Starting with propyne and using any other...Ch. FRP - Bromination of 2-methylbutane yields predominantly...Ch. FRP - Prob. 15PCh. FRP - Account for the following observations with...Ch. FRP - Prob. 17PCh. FRP - Prob. 18PCh. FRP - Heating 1, 1,1-triphenylmethanol with ethanol...Ch. FRP - (a) Which of the following halides would you...Ch. FRP - An alkane (A) with the formula C6H14 reacts with...Ch. FRP - Prob. 22PCh. FRP - Prob. 23PCh. FRP - Dehydrohalogenation of meso-1, 2-dibromo-1,...Ch. FRP - Prob. 25PCh. FRP - Prob. 26PCh. FRP - 27. (R)-3-Methyl-1-pentene is treated separately...Ch. FRP - Prob. 28PCh. FRP - Prob. 29PCh. FRP - Prob. 30PCh. FRP - Prob. 31PCh. FRP - Synthesize the following compound by a method that...Ch. FRP - Provide three methods that employ Grignard...Ch. FRP - 34. Compound Yexhibits one NMR signal at (a...Ch. FRP - Prob. 35PCh. FRP - 36. Compound X shows a strong IR absorption band...Ch. FRP - Prob. 37PCh. FRP - 38. In addition to more highly fluorinated...Ch. FRP - Fluorination of (R)-2-flurobutane yields a mixture...Ch. FRP - Prob. 40PCh. FRP - Prob. 41P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Give the chemical tests to distinguish between following pair of compounds : (i) Propanol and propanone (ii) Ethyl acetate and methyl acetate (iii) Benzaldehyde and benzoic acid (iv) Benzaldehyde and acetaldehyde (v) Formic acid and acetic acid (vi) Propanal and propanol (vii) Ethanoic acid and ethylethanoatearrow_forwardIn addition: can u give the names of evey compounds in the question solutionarrow_forwardDimethyl disulfide, CH,S–SCH3, found in the vaginal secretions of female hamsters, acts as a sexual attractant for the male hamster. Write an equation for its synthesis from methanethiol.arrow_forward
- (a) Account for the following :(i) Cl – CH2COOH is a stronger acid than CH3COOH.(ii) Carboxylic acids do not give reactions of carbonyl group.(b) Write the chemical equations to illustrate the following name reactions:(i) Rosenmund reduction (ii) Cannizzaro’s reaction(c) Out of CH3CH2 – CO – CH2 – CH3 and CH3CH2 – CH2 – CO – CH3, which gives iodoform test?arrow_forwardDescribe concisely a chemical test to distinguish between the following pairs of compounds.(a) Propanal and propanone(b) Phenol and benzoic acid(c) Hexan-3-one and hexan-2-onearrow_forwardThe name of the parent six-membered sulfur-containing heterocycle is thiane. It is numbered beginning at sulfur. Multiple incorporation of sulfur in the ring is indicated by the prefixes di-, tri-, and so on. (a) How many methyl-substituted thianes are there? Which ones are chiral? (b) Write structural formulas for 1,4-dithiane and 1,3,5-trithiane. (c) Which dithiane isomer (1,2-, 1,3-, or 1,4-) is a disulfide?(d) Draw the two most stable conformations of the sulfoxide derived from thiane.arrow_forward
- (b) 3-methyl-2-butanol reacts with concentrated sulphuric acid to form 2-methyl-2- butene. Write the mechanism for the reaction.arrow_forwardPredict the major products formed when benzoyl chloride (PhCOCl) reacts with the following reagents.(a) ethanol (b) sodium acetate (c) anilinearrow_forwardWhich of the following is true for the reactions of alkyl halides? (a) The characteristic reactions of alkyl halides are oxidation and reduction.(b) The characteristic reactions of alkyl halides are elimination and substitutionc. The characteristic reactions of alkyl halides are addition and substitutiond. Characteristic reactions of alkyl halides are addition and elimination.arrow_forward
- Chlorination of 2-butanone yields two isomeric products, each having the molecular formula C4H7ClO. (a) What are these two compounds? (b) Write structural formulas for the enol intermediates that lead to each of these compounds. (c) Using curved arrows, show the flow of electrons in the reaction of each of the enols with Cl2.arrow_forwardIdentify (A) in the following reaction. 2H2 Pt (A) KMNO4 Warm conc. || С — С — о—н |CO,H + HO CO2H cis-cyclo hexane 1,2-dicarboxylic acid (a) (b) (c) (d)arrow_forward(a) How will you carry out the following conversions?(i) Acetylene to Acetic acid (ii) Toluene to m-nitrobenzoic acid(iii) Ethanol to Acetone(b) Give reasons :(i) Chloroacetic acid is stronger than acetic acid.(ii) pH of reaction should be carefully controlled while preparing ammonia derivatives of carbonyl compounds.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
