Organic Chemistry, 12e Study Guide/Student Solutions Manual
12th Edition
ISBN: 9781119077329
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Question
Chapter H, Problem 8PP
Interpretation Introduction
Interpretation:
The structure of heroin is to be determined, which formed when morphine reacts with two moles of acetic anhydride.
Concept Introduction:
>Morphine is found naturally in a number of plants and animals. It acts directly on the central nervous system to decrease the feeling of pain. It can be taken for both acute pain and chronic pain.
>Alkaloids are a huge and complex group of cyclic compounds that contain N-atom. Morphine is an example of alkaloid.
>Acetic anhydride is an acetylating agent.
>The reaction of morphine with acetic anhydride as the acetylating agent leads to the formation of 3-acetylmorphine, which on further treatment with acetic anhydride, leads to the formation of heroin.
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Practice
Supply the missing products, reagents or starting materials as necessary.
1) NaCN
2) НCI
а.
OH
b.
1) NABD4
2) HC, H-О
с.
Problem 3.18
More Practice:
Problem 3.19
(a) At which sites can C hydrogen bond to another molecule like itself? (b) At which sites can
D hydrogen bond to water?
с
norethindrone
(oral contraceptive component)
Try Problems 3.39; 3.40; 3.61a, b; 3.62c; 3.63c, d.
a.
Br
Which of the following molecules can hydrogen bond to another molecule like itself? Which can
hydrogen bond to water?
Br
OH
Br
b.
O
NH₂
D
arachidonic acid
(fatty acid)
d.
OH
O
Practice Question:
Outline all the necessary reactions with the minimum number of steps required to synthesize tert-butyl pentanoate from alkenes. Show the different organic reactions needed, starting from the reaction of an alkene. There is 5 reactions.
For each reaction, you must name the type of reaction, the reactant(s), and the product(s).
Chapter H Solutions
Organic Chemistry, 12e Study Guide/Student Solutions Manual
Ch. H - Prob. 1PPCh. H - Prob. 2PPCh. H - Prob. 3PPCh. H - Practice Problem H.4
In 1891 G. Merling...Ch. H - Practice Problem H.5
Many alkaloids appear to be...Ch. H - Practice Problem H.6 Papaverine has been...Ch. H - Practice Problem H.7
One of the important steps in...Ch. H - Prob. 8PPCh. H - Practice Problem H.9 Gramine has been synthesized...
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- QUESTION The major product of the following reaction is: :0 N H₂SO4 H₂Oarrow_forwardProblem 2 Give IUPAC names for the following compounds: (a) CI Br (b) CH3 (c) „NH2 CH2CH;ĊHCH3 (d) CI CH3 (e) CH2CH3 (T) CH3 CH3 'CI O,N NO2 H3C `CH3arrow_forwardCH16 PE3 Please help Organic Chemistry problemarrow_forward
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