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Lab Report
Experiment 11 – Spectrophotometric determination of %Co in purple Co compound
Chemical reaction:
Strong heating
Co(III)(NH
3
)
x
Cl
y
(s)
Co(II)Cl
2
+ NH
3
(g) + N
2
(g) + NH
4
Cl
(purple Co compd.)
Note: In this reaction, the oxidation number of Co in the purple compound was converted from
+3 to +2 after heating.
Data Table:
1. Calibration curve – absorbance vs molarities of Co(II) standards
Table 1: Beer’s law data
C
stock
=
0.09998M (from EDTA titration)
max
= 511 nm (from spectrum)
Solution #
V
s
(mL)
V
t
(mL)
Dilution
factor (DF)
C
f
= C
s
x DF
Absorbance
1
5
25
1/5
0.01998
0.0883
2
10
25
2/5
0.03998
0.1877
3
15
25
3/5
0.05998
0.2867
4
20
25
4/5
0.07998
0.3856
Stock
25
25
5/5
Stock
0.4846
Sample calculation of the concentration of diluted solution:
Solution #1:
1/5*0.09998=0.019996M
Figure 1:
Calibration graph (Beer’s law graph):
Abs. vs. concentration (attach the graph)
Fitting equation:
4.9525x-0.0105
Slope of the line:
4.9525
olar extinction coefficient (
including the units) = 4.9525
2. Determine % Co in the Purple Co Compound
Table 2:
%Co in purple Co compound
# of Trials
1
2
3
Mass of purple Co weighed (g)
0.3905
0.3960
0.3910
Absorbance of Co solution
0.3258
0.3062
0.3156
Molar conc. of Co from
calibration curve
0.06790
0.06394
0.06572
mol of Co = MV (v = 25 mL)
0.001697
0.001598
0.001643
Mass (g) of Co in purple Co =
mole x AM
1.000*10^-1
9.420&10^-2
9.682*10^-2
% Co in purple Co compound
25.61%
24.15%
24.76%
Average % and sd
24.84%
0.733
Sample calculation of % Co:
0.3905*0.025L= 0.001697
0.001697*58.93= 1.000*10^-1
1.000*10^-1/0.3905= 25.61%
(25.61%+24.15%+24.76%)/3= 24.84%
√
(
25.61
−
24.84
)
2
+(
24.15
−
24.84
)
2
+(
24.76
−
24.84
)
2
3
−
1
=
0.733
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Answer number 1,2,3,4,6 only.
True or false
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99.725
a. Is this dissolution reaction exothermic? es
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The ran reultd in heet increese
H0.
of the
ti= 23.7%
っ 』C
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joules
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tion
pus page
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Jump to.
You are logged in as Helena Agyemang Log.out)
S21 CHEM 161
P Type here to search
Cbp
%24
8.
9.
backspace
11
Y.
D
F
H.
J
K
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KEŚLER
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Draw a model
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OUTPUTIllustrate It!
STATION
atoms in the
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