CHEM 110L - Experiment 10 It's Back
.pdf
keyboard_arrow_up
School
University of Phoenix *
*We aren’t endorsed by this school
Course
110
Subject
Chemistry
Date
Apr 3, 2024
Type
Pages
2
Uploaded by HighnessRockOryx35
Experiment 10 It’s Back… Titration Total Points: 40 Student’s Name:
Lab Section: NOTE: You must show your work for all calculations; no work, no credit. Mass of Na
2
S
2
O
3
______2.503g_______ (2 pts) Molarity of Na
2
S
2
O
3
_____0.010073M_________ (Show your calculation) 2.503g x 1mol Na2S2O3/248.18g/1L = 0.010073 (1 pt) Density of Bleach _____0.10262_________ g/mL (Show your calculation) 31.625g-21.363g/100mL = 0.10262 Initial Samples 20 mL Diluted Bleach Treated with KI Volume of Na
2
S
2
O
3 Used During Sample Titration (3 pts) Titrant Added (mL) to: After Starch Added Titrant Added (mL) to: Total Volume Color: Brown Initial Buret Volume, mL Light Orange/ Dark Yellow Dark Blue End Point: Colorless (mL) Sample 1 0 10.15 18.86 29.01 Sample 2 0 8.820 8.080 16.90 1.
Calculate the following for each trial. Make sure to show all your work to receive credit. a.
(2 pts) Moles of Na
2
S
2
O
3 used to titrate the bleach solution. S1: 0.010073M x 0.2901L = 0.00292 moles S2: 0.010073M x 0.1690L = 0.001702 moles b.
(2 pts) Moles of I
2
formed by reaction with bleach. S1: 0.00292mol/2 = 0.001461 moles S2: 0.001702mol/2 = 8.512E-4 moles c.
(4 pts) Molarity of OCl
-
present in the bleach solution. (Remember to account for the dilution of the original sample.) S1: (0.001461mol)(1mol OCl-/1mol I2)/(0.02L)(10)= 0.73054M S2: (8.512E-4)(1mol OCl-/1mol I2)/(0.02L)(10)= 0.42558M d.
(2 pts) Grams of NaOCl present in the bleach (in g/mL): S1: (0.73054M)(74.44g/mol) = 54.382g/L -> 0.054382g/mL S2: (0.42558M)(74.44g/mol)= 31.680g/L -> 0.031680g/mL e.
(2 pts) Percent NaOCl present in the bleach: S1: (0.054382g/mL)/(0.10262g/mL) x 100 = 52.99% S2: (0.031680g/mL)/(0.10262g/mL) x 100 = 30.87%
Experiment 10 It’s Back… Titration Total Points: 40 2.
(6 pts) Use the following equation to answer the following questions: I
2
-starch complex
(aq)
+ 2 S
2
O
2-
3(aq)
→
starch + 2 I
-
(aq)
+ S
4
O
6
2-
(aq) What is being reduced? ____Iodine I2_____________________________ What is the oxidizing agent? ______Iodine I2_______________________ How many electrons are being gamed by each iodine atom? _1 e-__ Post-lab Questions NOTE: You must show your work for all calculations; no work, no credit. 1.
(6 pts) Balance the redox reaction first (it is in basic medium). OCl
-
(aq)
+ CrO
2
-
(aq)
→
Cl
-
(aq)
+ CrO
4
2-
(aq)
2OH- + 3ClO- + 2CrO
2
2- →
3Cl- + 2CrO
4
2- + H2O 2.
(4 pts) A titration experiment is set up to use 0.777M bleach (NaOCl) to analyze CrO
2
-
. If 50.0 mL of the CrO
2
-
(aq)
solution required 12.27 mL of bleach to react to completion, what would you calculation as the molarity of the CrO
2
-
solution? 0.777M x 0.1227L = 0.93379 mol NaCl 2mol/3mol x 0.93379 mol NaCl = 0.635586 mol/0.50L = 0.127M 3.
(6 pts) Excess I
2
can be used to determine vitamin C levels in solution. Vitamin C (ascorbic acid) reacts in the following manner: C
6
H
8
O
6(aq)
+ I
2
→
C
6
H
6
O
6(aq)
+ 2 H
+
(aq)
+ 2 I
-
(aq)
The I
2
that did not
react with ascorbic acid is then determined in a thiosulfate reaction as you did in this experiment. If 22.07 mL of 0.8310 M I
2
was added to a sample containing vitamin C, the unused I
2
required 20.00 mL of 0.143 M S
2
O
3
2-
to react. How many moles of vitamin C were originally present? I2 + 2 S2O3 -> 2I + S4O6 I2= 0.8310M x 0.2207L = 0.1834017 mol S203= 0.143M x 0.2000L = 0.0286mol /2mol = 0.0143mol 0.1834017mol –
0.0143mol = 0.1691017 moles of Vitamin C
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
- Access to all documents
- Unlimited textbook solutions
- 24/7 expert homework help
Related Questions
The flask contains 10.0 mL of HCl and a few drops of
phenolphthalein indicator. The buret contains
0.140 M NAOH. It requires 16.4 mL of the NAOH solution
to reach the end point of the titration.
What is the initial concentration of HCl?
concentration:
M HCI
about us
careers
privacy policy
terms of use
contact us
help
docx
DII
F5
PrtScn 8
Home
F9
End
F10
PgUp
F11
F4
F6
F7
arrow_forward
Quantity of Acetic Acid in Salad Dressing
Titration Results: 1000
μL aliquots of salad dressing against a sodium hydroxide solution
Please only fill in 3 concordant results!
Titration number:
1
2
3
Error
Final burette reading (mL)
7.9
15
22.2
±0.05 mL
Initial burette reading (mL)
0.9
7.9
17
±0.05 mL
Titre (mL)
7
7.1
7.2
±0.10 mL
Average (mean) volume of concordant titres: 7.1
Concentration of Acetic Acid (M) (to 3 sig figs): 6.88
mL
IM
Concentration of Acetic Acid (as %w/v) (to 3 sig figs):
%
Note: %w/v = (g/mL) x 100%
arrow_forward
14.00
4. A student titrates 20.0 ml of an acid
pH vs. Volume NaOH Added
13.00
solution with 0.500 M NaOH and gets the
graph shown below.
12.00
Determine the
11.00
concentration of the acid.
10.00
pH 9.00
8.00
7.00
6.00
5.00
4.00
0.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
Volume of 0.500 M NaOH Added
arrow_forward
Calculate the Molarity
arrow_forward
3. A student titrates 20.0 ml of an acid solution with 0.500 M NaOH and gets the graph shown below. Determine the concentration of the acid.
arrow_forward
A 10.0 mL sample of H₂SO4 is titrated
with 0.685 M NaOH. The initial buret
volume is 0.10 mL and the final buret
volume is 28.92 mL. What is the
concentration (mol/L) of the H₂SO4
sample? Answer to 3 decimal places with
no units.
Your Answer:
Answer
arrow_forward
From the titrations below, calculate the molarity of the NaOH solution in each of the f ollowing? Make sure you balance the equations.
a) NaOH + HCl → NaCl + H2O 32.00 ml of NaOH is required to completely react with 25.00 ml of 0.150 M HCl. ___________
b) NaOH + H2SO4 → Na2SO4 + H2O 42.00 ml of NaOH is required to completely react with 18.00 ml of 0.10M H 2SO4 . __________
arrow_forward
Part A: Standardization of a Sodium Hydroxide Solution
Titration 1
Titration 2
Titration 3
Mass of 125 mL flask
45.849g
46.715g
44.953g
Mass of flask and KHP
46.849g
47.745g
46.003g
Initial buret reading (mL)
0.5 ml
0.5 ml
0.5 ml
Final buret reading (mL)
27.8 ml
26.5 ml
26.7 ml
Volume of NaOH used (mL)
45.11 ml
45.06 ml
45.14 ml
Calculations
Titration 1
Titration 2
Titration 3
Moles of KHP
Moles of NaOH
Molarity of NaOH
Average Molarity of NaOH: _______________
arrow_forward
Titration Calculation Practice 4
1. Nitrous acid has a Ka of 4.0 x 104. Calculate the pH at the following places on a titration curve
when 40.00 mL of 0.125 M NANO2 is titrated against 0.200 M HC1.
a. the initial pH
b. the pH at the point when 12.50 mL acid has been added
c. the pH at the point when 15.00 mL acid has been added
arrow_forward
It’s a 4 part question
arrow_forward
25
arrow_forward
55 ml of Na2CO3 solution was titrated with 1.2 M of HCI according to the following reaction
Na2CO3 + 2HCI
2NACI + H2CO3
If 27 ml of HCI are required to completely reacts with Na2CO3 solution
Calculate the molarity of Na2CO3 solution
Select one:
O a. 2.5 M
O b. 0.3 M
O c. 1.8 M
O d. 0.6 M
O e. 0.9 M
arrow_forward
How to calculate the volume used?
arrow_forward
Can you please do number 14 III. Can you tell us how to get the volume. I want to know how to calculate the volume in this titration of ch3nh2. See pic.. This is not a graded question as it is a practice question . I am 60 years old and helping my son prepare for the AP exam in a few months. We do questions at the back of the textbook by Zumdahl and Zumdahl
arrow_forward
Find the number of moles of HCl added.
Concentration of HCl solution, M: 0.60
Initial buret reading: 0.35 ml
Final buret reading: 5.65 ml
Volume of titrant: 5.35 ml
arrow_forward
Only typed solution
arrow_forward
QUESTION 5
In an experiment, it requires 35 ml of NaOH to titrate 0.35 g of dissolved KHP (molecular weight = 204.22 g/mol)
to the phenolphthalein end point. Calculate the concentration of NaOH in mol/L .
Оa.4.896 М
O b.0.4896 M
Ос. 0.490 М
O d. 0.0490 M
O e. 1.714 M
arrow_forward
Please answer true or false
arrow_forward
of 36 - Module 8: Ho X
om/sac/7086543#/7086543/23/1
e:
>
91.7%
Question 24 of 35 - Module 7 Ho X
pH =
x10
TOOLS
Topic: Week 4 Discussion
h
Resources
144
X
A volume of 500.0 mL of 0.110 M NaOH is added to 585 mL of 0.250 M weak acid (K, = 8.02 x 10-5). What is the pH of the
resulting buffer?
HA(aq) + OH(aq) → H₂O(1) + A (aq)
+
Give Up?
DDI
Q
Hint
☐
Check Answer
Attempt 3
12:51 PM
9/29/2022
O
Y
arrow_forward
In the titration curve shown in Figure 2, the number of data points tends to increase in certain region of the titration curve. Can you explain when this occurs and why it is a good idea? Will you adopt this strategy when you are titrating? (The answer to this last question is yes, you will.)
arrow_forward
based on the data tables provided, what is % CH3COOH in vinegar
arrow_forward
SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Related Questions
- The flask contains 10.0 mL of HCl and a few drops of phenolphthalein indicator. The buret contains 0.140 M NAOH. It requires 16.4 mL of the NAOH solution to reach the end point of the titration. What is the initial concentration of HCl? concentration: M HCI about us careers privacy policy terms of use contact us help docx DII F5 PrtScn 8 Home F9 End F10 PgUp F11 F4 F6 F7arrow_forwardQuantity of Acetic Acid in Salad Dressing Titration Results: 1000 μL aliquots of salad dressing against a sodium hydroxide solution Please only fill in 3 concordant results! Titration number: 1 2 3 Error Final burette reading (mL) 7.9 15 22.2 ±0.05 mL Initial burette reading (mL) 0.9 7.9 17 ±0.05 mL Titre (mL) 7 7.1 7.2 ±0.10 mL Average (mean) volume of concordant titres: 7.1 Concentration of Acetic Acid (M) (to 3 sig figs): 6.88 mL IM Concentration of Acetic Acid (as %w/v) (to 3 sig figs): % Note: %w/v = (g/mL) x 100%arrow_forward14.00 4. A student titrates 20.0 ml of an acid pH vs. Volume NaOH Added 13.00 solution with 0.500 M NaOH and gets the graph shown below. 12.00 Determine the 11.00 concentration of the acid. 10.00 pH 9.00 8.00 7.00 6.00 5.00 4.00 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0 Volume of 0.500 M NaOH Addedarrow_forward
- Calculate the Molarityarrow_forward3. A student titrates 20.0 ml of an acid solution with 0.500 M NaOH and gets the graph shown below. Determine the concentration of the acid.arrow_forwardA 10.0 mL sample of H₂SO4 is titrated with 0.685 M NaOH. The initial buret volume is 0.10 mL and the final buret volume is 28.92 mL. What is the concentration (mol/L) of the H₂SO4 sample? Answer to 3 decimal places with no units. Your Answer: Answerarrow_forward
- From the titrations below, calculate the molarity of the NaOH solution in each of the f ollowing? Make sure you balance the equations. a) NaOH + HCl → NaCl + H2O 32.00 ml of NaOH is required to completely react with 25.00 ml of 0.150 M HCl. ___________ b) NaOH + H2SO4 → Na2SO4 + H2O 42.00 ml of NaOH is required to completely react with 18.00 ml of 0.10M H 2SO4 . __________arrow_forwardPart A: Standardization of a Sodium Hydroxide Solution Titration 1 Titration 2 Titration 3 Mass of 125 mL flask 45.849g 46.715g 44.953g Mass of flask and KHP 46.849g 47.745g 46.003g Initial buret reading (mL) 0.5 ml 0.5 ml 0.5 ml Final buret reading (mL) 27.8 ml 26.5 ml 26.7 ml Volume of NaOH used (mL) 45.11 ml 45.06 ml 45.14 ml Calculations Titration 1 Titration 2 Titration 3 Moles of KHP Moles of NaOH Molarity of NaOH Average Molarity of NaOH: _______________arrow_forwardTitration Calculation Practice 4 1. Nitrous acid has a Ka of 4.0 x 104. Calculate the pH at the following places on a titration curve when 40.00 mL of 0.125 M NANO2 is titrated against 0.200 M HC1. a. the initial pH b. the pH at the point when 12.50 mL acid has been added c. the pH at the point when 15.00 mL acid has been addedarrow_forward
- It’s a 4 part questionarrow_forward25arrow_forward55 ml of Na2CO3 solution was titrated with 1.2 M of HCI according to the following reaction Na2CO3 + 2HCI 2NACI + H2CO3 If 27 ml of HCI are required to completely reacts with Na2CO3 solution Calculate the molarity of Na2CO3 solution Select one: O a. 2.5 M O b. 0.3 M O c. 1.8 M O d. 0.6 M O e. 0.9 Marrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning