2510_2023Sm_Pre1
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Cornell University *
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Course
2510
Subject
Chemistry
Date
Apr 3, 2024
Type
Pages
18
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1
LAST NAME, First (PRINT, please)
CU ID (7 digit number)
Chemistry 2510
Cornell University
Summer 2023
Prelim 1
DO NOT OPEN THIS PRELIM UNTIL YOU ARE TOLD TO BEGIN.
Please write your answers directly on the question page.
All calculated values must be supported by work presented on the page in order to receive full
credit. Numerical answers should be presented with proper units.
You may find it helpful to read through the entire exam and work first on questions that are quick
and/or you are confident in. Once those are complete, you can return to the ones you find more
difficult.
Please follow the directions for each question and enclose answers in boxes where they are
provided.
The exam is printed double-sided and has 7 numbered questions on 10 pages. There is a separate,
colored double-sided packet with a periodic table, a ruler and information needed for several
problems.
Sign below to affirm that you are not presenting anybody else’s work as your own.
Signature:
2
Question 1
Finn Hudson struggles with headaches, so he always has Excedrin Extra Strength with
him. See colored sheets for relevant information.
a)
(8 pts) He wants to purify caffeine, so he grinds up 4 tablets and adds 25.0 mL of ethyl
acetate. After filtering out the insoluble material, he proceeds to add 15.0 mL of buffer (aq)
(pH ~7.5). Below, please indicate the probable location of each compound by drawing its
structure in the correct box (
pay attention to protonation state and formal charges
)
.
Assume
each compound only exists in one of the solvents.
b)
(6 pts) Finn believes that the three compounds are not separable by acid base extraction
because each of the three has an acidic proton (H). Is he correct? Explain briefly.
c)
(2 pts) If Finn obtained 0.421 g of caffeine, what was his percent recovery?
1c answer
Ethyl acetate layer
Buffer (aq) (pH ~7.5) layer
3
Question 2
Quinn Fabray wants to make aspirin from salicylic acid and finds a mixture of benzoic
acid and salicylic acid that the chemistry teacher had prepared for a recrystallization experiment
(like the one you did, except that salicylic acid was the target compound). She has a 1.5 g sample of
salicylic acid contaminated with an unknown amount of benzoic acid.
Compound
Solubility at 0°C (g/L)
Solubility at 100°C (g/L)
Benzoic Acid
1.7
68
Salicylic Acid
2.17
66.6
a)
(5 pts) What is the maximum theoretical percent recovery of salicylic acid?
b)
(5 pts) She gets distracted and accidentally adds 47.3 mL of boiling water to dissolve the
original sample. Rather than start over, she boils the sample until the volume is reduced to
1.3 mL, then cools it to 0°C. What mass of salicylic acid does she theoretically recover?
c)
(5 pts) Quinn repeats the procedure (correctly) and determines that she recovers 96% of the
1.5 g starting sample. From this she reasons that the starting sample is 4% salicylic acid. Is
her logic correct? Explain.
2b answer
2a answer
4
Question 3
Rachel Berry is analyzing the salicylic acid that Robin purified.
a)
(4 pts) She measures the melting point of a small amount of the salicylic acid as 160-
161.5°C (lit: 159°C). Briefly explain the relevance of this result.
b)
(4 pts) Rachel runs a TLC of the salicylic acid and sees a vertical smear extending for half
the plate. What does this indicate about the purity of the compound, if anything?
c)
(4 pts) Sam Evans suggests that Rachel load less sample before running the TLC again. Is
this a reasonable suggestion? Why or why not?
d)
(4 pts) For a TLC of two unknown compounds, when the solvent front is 8.5 cm, the two
spots have R
F
values of 0.25 and 0.62. If the compounds are run again with a solvent front
of 6.0 cm, how far will each spot travel?
5
Question 3 (cont).
e)
(6 pts) Quickies…
i) When running a TLC plate should the lid be ON or OFF the sample chamber?
ii) How deep should the running solvent be relative to the sample origin?
iii) A nonpolar compound will have a LARGE or a SMALL R
F
?
iv) Increasing the polarity of the running solvent DECREASES or INCREASES the R
F
of a polar
compound?
v) How do you know when to stop running a TLC?
vi) Which will result in a lower R
F
for a very polar compound 50:50 or 10:90 ethyl acetate:hexanes?
f)
(4 pts) Puck purifies his reaction mixture by column chromatography after the synthesis
in question 4b. His grid TLC is shown below. On the analytical TLC, fill in a reasonable
approximation of expected results from the indicated fractions.
Fraction #:
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
Analytical TLC
Grid TLC of Fractions
1
2
3
4
5
TLC of Mixture
Before Column
Run Column Chromatography
6
7
8
9
10
6
Question 4:
Kurt Hummel is performing the oxidative cleavage reaction but, foolishly, he relies on
Sue Sylvester to provide the reagents. Instead of the expected diol, Sue gives him 2-methyl-1-
phenylhexane-1,2-diol. Mike uses 3.5 g of the diol and excess oxygen along with sufficient catalyst.
(See data on colored sheets.)
a)
(4 pts) What is the theoretical yield (in grams) for the synthesis of the benzaldehyde?
b)
(5 pts) Kurt runs a TLC and sees three spots by UV detection. One has the same RF as the
starting material. He states that this means that the side product was not formed. Do you
agree with Mike? Explain briefly.
4a answer
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Instructions You are required to produce a short lab report using the information given in the accompanying document, ‘Lab report assessment_student data’. This document introduces an experiment, and also provides a set of experimental data for this experiment. You are required to use this data to perform steps 8 and 9 of the procedure. This includes calculations of a particular value, and then comparison to the true value. Consider any experimental errors when comparing calculated values and true values. Your report should be between 300 and 500 words (including all table contents and titles of tables and graphs). Your lab report should consist of three sections only: • Experimental • Results and Discussion • Conclusion You do NOT need to include an introduction section. Your experimental section should be written in appropriate lab report format, (passive voice, 3 rd person, in paragraphs). Your results and discussion section should contain the data presented in table format, and…
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Simplify. Write each answer in scie
17) (5.4x 10")는 (7X/0")
19) (6 x 10°(4 x 10-1)
21) (7.68 x 10:)는 (9x/0°)
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sure your internet connection is working well. Interrupted service can be used as a reason for a retake,
only have one attempt. There are no retakes.
ot click the "Back" button on your web browser it will kick you out of the exam.
e: Make sure to answer all questions. If you close the exam early with answering all questions in your exam.
wers that you answered will count as your completed exam and all questions not answered will be marked
Question 1
Which of the following best explains why soap and water remove grease?
O Soap molecules are large polymers that absorb grease
O Soap molecules are ionic and attracted to grease
Soap molecules are nonpolar and dissolve in grease
O Soap molecules have ionic "heads" that dissolve in water and nonpolar "tails" that dissolve in water
O Soap molecules have ionic "heads" that dissolve in grease and nonpolar "tails" that dissolve in water.
Quiz saved at 6:52p
ch
O O
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board
Instructions
Please select the best answer for each of the questions.
This test has a time limit of 2 hours.This test will save and submit automatically when the time expires.
Warnings appear when half the time, 5 minutes, 1 minute, and 30 seconds remain.
Timed Test
Multiple Attempts Not allowed. This test can only be taken once.
Force Completion Once started, this test must be completed in one sitting. Do not leave the test before clicking Save and Submit
This test does not allow backtracking. Changes to the answer after submission are prohibited.
Your answers are saved automatically.
Remaining Time: 1 hour, 34 minutes, 00 seconds.
* Question Completion Status:
A Moving to the next question prevents changes to this answer.
Question 2
What is the pH of the solution which results from mixing 25 mL of 0.20 M CH3CO>H and 25 mL of 0.20 M NAOH? (K, for CH3CO>H = 1.8 x 10-b)
OA 8.87
OB. 10.43
OC7.00
OD.9 02
OE 5.13
A Moving to the next question prevents changes to this answer.
*-
F11…
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This question must be finished in your tutorial and this Word document containing your answers
submitted within 120 minutes of the end of your tutorial. You will receive feedback from your tutor
in a few weeks. The answers will be available where you obtained this. There are no marks for this
exercise but it counts towards participation.
Draw your answers on a separate piece of paper, take an image and insert the image(s) into this
Word document at the end.
(a)
Re-draw the following molecule with the CH2CH2CH3 group on the ladder
1.
H
H2
ОН
H3C
H2
CH2
H;C
(b)
Is the molecule in part (a) the same molecule or the enantiomer of the following.
Circle your answer
Explain your answer
CH3
SAME MOLECULE
H2C
H2
-CH3
ENANTIOMER
H2
ОН
3.
What is the configuration (R or S) of the chiral carbon in this molecule.
Label the ranking of each of the groups on the chiral carbon from 1 (highest) to 4 (lowest)
Draw the representation of this molecule with the lowest ranked group (4) on the ladder and…
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Hello, I hope you are doing well on this fine day. For the following quetion please read carefully the question and instruction. PLEASE ANSWER QUESTION IN 20 MINTUES NOT MORE PLEASE AND THANK YOU. If you do answer the question correctly and post it in the next 20 minutes, NO NEED TO SHOW ALL THE WORK, I JUST WOULD LIKE THE CORRECT ANSWER AS SOON AS POSSIBLE. I will write a wonderful and generous feedback/review/rating about you.
What is the total amount (in mol) of ions in solution when 34.7 g of the ionic solid Ba(OH)2·8H2O completely dissolves in water? The molar mass of Ba(OH)2·8H2O is 315.46 g/mol.
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Please answer questions 3 and 4 and show work please. Thank you
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if you could please help! i submitted this previously and was told that it looks incomplete. the questions are complete and there is no additional information to upload with the questions. again there are 6 questions and i have done a majority of them. i really just need help with question 2 and 3, however, if you could look at my answers for the questions i did and tell me if they are correct i will gladly rate you! thank you so much. I apologize if it is small, i made the font smaller to fit everything on one picture
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Please short answer
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The experiment involves diluting a 16% sugar solution, prepared by dissolving 16 g of sugar in 100 mL water. Three different solutions are prepared by mixing the 16% sugar solution with various volumes of water.Make appropriate choices from the dropdowns. Work from left to right. Each answer can be calculated from numbers to the left of it in the row. The objective is to calculate the number in the right-hand most column in each row (% sugar in the solution).
16% sugar solution taken / mL
water added/ mL
diluted solution / mL
Dilutionfactor
% sugarin diluted solution
25
25
[ Select right answer] ["50", "25", "100", "150"]
[ Select right answer] ["1", "0.5", "2"]
[ Select right answer] ["8", "50", "12.5", "25"]
25
8.3
[ Select right answer]…
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2
In your one semester being enrolled in the subject Analytical Chemistry II, write your major take aways that you will never forget and explain why? For the purposes of improvement in terms of course delivery and curriculum, what changes do you wish to suggest? Finally, as a reflection, in a scale of 1-10 (1 being the lowest and 10 being the highest) how do you rate your performance in this subject.
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Please Help me complete question 2
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please i really need your help with this
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Hey! Could you check these answers to make sure they are all correct? If they aren't, could you please help me to figure out what I did wrong?
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ed Test
This test has a time limit of 1 hour.This test will save and submit automatically when th
Warnings appear when half the time, 5 minutes, 1 minute, and 30 seconds remain.
tiple Attempts Not allowed. This test can only be taken once.
ce Completion This test can be saved and resumed at any point until time has expired. The timer will
emaining Time: 57 minutes, 15 seconds.
uestion Completion Status:
A Moving to another question will save this response.
Question 4
The standard Gibb's Free Energy (AGO) = 18.38 kJ at 25C for the reaction
HNO2 2 H+ + NO2-.
What is the value of AG if {HNO2} = 0.75 M, {H+} = 0.13M and {NO2-} = 0.07M?
%3D
%3D
%3D
Is the reaction spontaneous under these conditions?
Moving to another question will save this response.
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Please help answer question 1, 2 and 3
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Arrange the values according to magnitude.
Greatest
Least
Answer Bank
7.1×10−6
3.3×10−2
52000
9.0×10−6
2.2×105
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I need help understanding how to do this, can you please show me how you get the CFU/mL
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I need help calculating and setting up questions 4 or 5.
thank you for your help!
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This question has multiple parts. Work all the parts to get the most points.
Use the References to access important values if needed for this question.
18
16
14
12
10
8
6
4.
Choose the correct relationship for the plot shown above.
O a direct proportion
O an inverse proportion
O linear with a positive slope and nonzero y-intercept
O linear with a negative slope and nonzero y-intercept
Submit
Cengage Learning | Cengage Technical Support
MacBook Air
DII
E5
F6
EZ
FA
F9
F10
F
2$
&
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4
5
6
7
8
* 00
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The spectroscopic data in the table is generated with five solutions of known concentration.
Concentration (M)
0.0133
m=
0.0266
0.0532
0.106
0.213
Absorbance
0.1271
What is the intercept of the linear regression line?
0.08531
0.5388
1.069
Use a spreadsheet program, such as Microsoft Excel, to graph the data points and determine the equation of the best-fit line.
1.954
What is the slope of the linear regression line formed by these points?
M-1
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Below is a simple set of weights obtained while immersing potato slices in various sugar solutions over 30 minutes.
I need help calculating all of this for a 30 min period
a. For each solution, calculate the rate of weight change over this 30-minute period. Show your work in the space below. Once you calculate these rates - fill in the blanks below and then add these answers to your Canvas exam. Write your answer in standard notation and use
3 digits past the decimal point - e.g. 0.005, 0.030. (Note that the last zero in an answer is considered to be a digit). Show your work in the space below.
0.0 M sucrose = _______ _____________ g/min
0.4 M sucrose = _______ ____________ g/min
0.6 M sucrose = ________ ____________ g/min
0.8 M sucrose = ____________________ g/min
1.0 M sucrose = ________ __________ g/min
Using the osmosis data in the question above, determine the percent weight change for each sucrose solution and fill in the blanks given below and then add these answers to…
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Bl pure substances, physically combined. Good examples of a solid mixture would be a salad or a bowl of trail
mix. Solutions are mixtures too. A spoon full of sugar dissolved in water is an example of both a mixture and a solution. Because mixtures
are physical combinations, they are easily separated. Here is a list of mixtures. Match the best method to separate the parts of each
mixture.
Boil the water. Collect the solid.
ITEM BANK: Move to Top
drag and drop answer here
Dissolve salt in water. Pour through filter paper and collect the sand.
Gravel and rocks
drag and drop answer here
Sand and gravel
Remove iron filings with magnet.
drag and drop answer here
Sand and iron filings
Sand and salt
Use a screen to sift and separate the big pieces from smaller pieces.
drag and drop answer here
Sand and wood shavings
drag and drop answer here
Sugar water
Pick out the bigger particles.
drag and drop answer here
Add water and float one type of particle.
53°F A O O
a
search
立
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FINAL Experiment 1- January 2021_-789644623 - Saved
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A friend of yours went panning for gold last weekend and found a nugget
that appears to be gold. With your newfound scientific prowess, you set out
to determine if it is really gold. Your tests show that the nugget has a mass
of 7.6 g. Immersing the nugget in water raised the volume from 7.22 mL to
8.06 mL. The density of gold is 19.32 g/cm3. What will you tell your friend?
acer
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concept that seemed difficult to you at first, but then after working on the concept, you were able to master it. Include a description of what made the concept difficult at first, and then discuss what you did in order to better understand the concept.
If you are not familiar with The Onion, it's a satirical newspaper. That "NSF: Science Hard" article pictured above came out while one of my colleagues was in college. She said that it made her laugh so hard because she was in the middle of a very hard time analyzing data. But, She made it through. And you can make it through this course!
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I wish i could visit a tutor during these times. May I please get a break down for number 12. I'm stuck on this question
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Explain your rationale for using the summative assessment (below) from the lesson plan on mixing substances in a 5th-grade classroom based on the below standard and learning objective, including how it aligns with the learning objective.
Summative Assessment
Summative:
Components of the Lab Report
Purpose: The student should clearly state the purpose of the experiment, which is to determine whether the mixing of two or more substances results in new substances.
Procedure: The student should describe the steps they took to conduct the experiment. This includes the substances they chose to mix and the safety equipment they used.
Observations: The student should record any observable changes that occurred when the substances were mixed. This could include a color change, the formation of a precipitate, or a change in temperature.
Conclusion: The student should state whether a new substance was formed based on their observations. They should also reflect on their accuracy in…
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Topic: Test of cation and anion.(qualitative) for each question right 4/5 bullet points
1. How this topic is related to Environmental science / bioinformatics? Choose 1
2. How this topic is related to our real life / industry? Choose one
3. Recent research and development of this topic.
At least 4 bullet point each question, It will be very helpful for me .Thank you in advance .
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Not Secure - a5.chem.binghamton.edu o
E LON-CAPA t30p04a
O [엘소드/KR Elswrod] 범…
MC Kimetsu no Yaiba - Di.
As you work on the questions, have your lab manual and text book handy.
If you have questions go to one of the office hours and remember, do not leave it for the last
minute!
In the titration of 25.00 mL of a water sample, it took 19.090 mL of 3.165x 10-3 M EDTA solution to reach the
endpoint.
Calculate the number of moles of EDTA required to titrate the water sample. (enter your answer with 3 significant
figures)
6.04x10-5
You are correct.
Your receipt no. is 151-9969 ?
Previous Tries
The total hardness is due to one or a combination of Ca2+, Mg2+, and Fe2+ in your sample. It is convenient to express
this hardness as though it was entirely due to Ca2+. Making this assumption, determine the number of moles of Ca2+
present in the bottled water sample titrated. (enter your answer with 3 significant figures)
6.04x10-5
You are…
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Please answer fast i give you upvote.
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STANDARD SAMPLE PREPARATIONS FOR ABSORBANCE & CONCENTRATION DATA
Concentration of stock nickel sulfate hexahydrate solution = .400 Molarity
Sample
Volume
Absorbance
Concentration (In Molarity)
a
5 mL
.179
10 mL
.329
15 mL
.588
20 mL
.760
25 mL
.939
Reference Blank = 0
Please show how to find Molarity, please show
steps. Thank you and stay safe.
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Please do question 5 for me and please don’t return in it just write one sentence for each box
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- Instructions You are required to produce a short lab report using the information given in the accompanying document, ‘Lab report assessment_student data’. This document introduces an experiment, and also provides a set of experimental data for this experiment. You are required to use this data to perform steps 8 and 9 of the procedure. This includes calculations of a particular value, and then comparison to the true value. Consider any experimental errors when comparing calculated values and true values. Your report should be between 300 and 500 words (including all table contents and titles of tables and graphs). Your lab report should consist of three sections only: • Experimental • Results and Discussion • Conclusion You do NOT need to include an introduction section. Your experimental section should be written in appropriate lab report format, (passive voice, 3 rd person, in paragraphs). Your results and discussion section should contain the data presented in table format, and…arrow_forwardSimplify. Write each answer in scie 17) (5.4x 10")는 (7X/0") 19) (6 x 10°(4 x 10-1) 21) (7.68 x 10:)는 (9x/0°)arrow_forwardsure your internet connection is working well. Interrupted service can be used as a reason for a retake, only have one attempt. There are no retakes. ot click the "Back" button on your web browser it will kick you out of the exam. e: Make sure to answer all questions. If you close the exam early with answering all questions in your exam. wers that you answered will count as your completed exam and all questions not answered will be marked Question 1 Which of the following best explains why soap and water remove grease? O Soap molecules are large polymers that absorb grease O Soap molecules are ionic and attracted to grease Soap molecules are nonpolar and dissolve in grease O Soap molecules have ionic "heads" that dissolve in water and nonpolar "tails" that dissolve in water O Soap molecules have ionic "heads" that dissolve in grease and nonpolar "tails" that dissolve in water. Quiz saved at 6:52p ch O Oarrow_forward
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- Please short answerarrow_forwardThe experiment involves diluting a 16% sugar solution, prepared by dissolving 16 g of sugar in 100 mL water. Three different solutions are prepared by mixing the 16% sugar solution with various volumes of water.Make appropriate choices from the dropdowns. Work from left to right. Each answer can be calculated from numbers to the left of it in the row. The objective is to calculate the number in the right-hand most column in each row (% sugar in the solution). 16% sugar solution taken / mL water added/ mL diluted solution / mL Dilutionfactor % sugarin diluted solution 25 25 [ Select right answer] ["50", "25", "100", "150"] [ Select right answer] ["1", "0.5", "2"] [ Select right answer] ["8", "50", "12.5", "25"] 25 8.3 [ Select right answer]…arrow_forward2 In your one semester being enrolled in the subject Analytical Chemistry II, write your major take aways that you will never forget and explain why? For the purposes of improvement in terms of course delivery and curriculum, what changes do you wish to suggest? Finally, as a reflection, in a scale of 1-10 (1 being the lowest and 10 being the highest) how do you rate your performance in this subject.arrow_forward
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