Lab 3 Reaction Rates Report
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Experiment: Reac/on Rates Abstract
The goal of this experiment was to observe the various reactions and determine their reaction rate as well as how long it would take for the reaction to blur and make the dot beneath disappear. Show the temperature rates as well as the reaction concentrations. The calculations were done to determine the link between the concentration and the rate of action of the reactant. Introduction
In this lab they wanted to show the rate, time, and reaction between the two substances and water. When the concentrations mix they will form the reaction and determines on how fast the reaction completes. Changes of the different temperatures and the reactants concentration will initially affect the reaction rate of the entire experiment. Objective
The objective is to investigate how concentration and temperature affect the rate of reaction between sodium thiosulfate and hydrochloric acid. Experimental
The experimental technique for this lab was to test the calculations of the various reactions and do the calculations to discover the average rate, pre rate, and the graph to demonstrate the decline, slope, and Ln(k). Conclusion
The lab results confirmed the experimental technique. Possible error could have been due to the computa/ons, experiment, rates, and ac/ons, A different technique could have involved using fewer or more of the dis/nct sequences of which compounds were u/lized to create each reac/on. Another op/on would have been to do three trails instead of two in oder to achieve a higher average. Page of 5 1
Experiment: Reac/on Rates Data and Calcula+ons Part A1: Dependence of Reac+on Rate on Concentra+on Table A1-1 – Trial Data 20drops=1mL 10 drops*1mL/20drops=0.5mL
Table A1-2 – Rela+ve Rate and Concentra+on Calcula+ons 1/+me= rela+ve rate M1V1=M2V2
Part A2: Determina+on of the Reac+on Orders Calcula/on of “m” and “n”using mixtures 1, 2, 3 and 4. Use the values calculated in Table A1-2 for rela/ve reac/on rate and reactant concentra/on. Do this on a sheet of paper and insert a photo of your calcula/on. Record the calculated value of m and n here, rounded to the nearest integer: Reac+on Time
Volume 0.1 M Na
2
S
2
O
3
Volume Water
Volume 1.0 M HCl
Total Solu+o
n Volume
Temp.
(s)
Drops
mL
Drops
mL
Drops
mL
mL
(°C)
Mixtur
e
Trial 1
Trial 2
Average
1
53
51
66
10
0.5
0
0
2
0.1
0.6
25
2
62
64
63
8
0.4
2
0.1
2
0.1
0.6
25
3
96
98
97
6
0.3
4
0.1
2
0.1
0.6
25
4
53
53
53
8
0.4
0
0.2
4
0.2
0.6
25
5
142
142
142
4
0.2
6
0.3
2
0.1
0.6
25
Mixture
Average Reac/on Time
Rela/ve reac/on rate
Reactant Concentra/on [S
2
O
3
2–
]
Reactant Concentra/on [H
+
]
(S)
(s
-1
)
(M)
(M)
1
66
0.015
0.083
0.167
2
63
0.016
0.067
0.167
3
97
0.010
0.050
0.167
4
53
0.019
0.067
0.333
Calculate mixture 5 during Part A4: Predic+on of Rela+ve Reac+on Rate
5
142
0.007
0.0333
0.1667
Page of 5 2
Experiment: Reac/on Rates Part A3: Determina+on of the Rela+ve Rate Constant, k’ Table A3 - Determination of the Relative Rate Constant,
k’
1.
Why should k’ have nearly the same value for each of the above reac/ons? k’ should have nearly the same value for each reac+on because the reac+on in in equilibrium. Part A4: Predic+on of Rela+ve Reac+on Rate Table A4 -
Prediction of Relative Reaction Rate for Mixture 5
m
=
ln
(
relative
rate
1
relative
rate
3
)
ln
[
S
2
O
2
−
3
S
2
O
2
−
3
]
n
=
ln
(
relative
rate
4
relative
rate
2
)
ln
[
H
+
H
+
]
m= 0.8003
n= 0.0035
Mixture
1
2
3
4
Average
k’ =
0.279
0.319
0.25
0.32
0.287
Predicted
Observed
% Error
Page of 5 3
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Experiment: Reac/on Rates Part B. Effect of Temperature on Reac+on Rate: The Ac+va+on Energy Table B1 - Determination of Activation Energy:
Insert Excel Graph Here: Rela+ve Rate
0.00955
0.007
26.7%
t
(+me)
104.71204
142
35.6%
Water Bath
Measured Temp Reac+on Time sec
Rela+ve Rate Constant k’
ln(k’)
Temp. Unit
°C
sec
sec
-1
K
K
-1
Hot ~40 °C
40
16
0.0625
0.753
-0.283
313
0.000319
Room ~20 °C
20
52
0.0192
0.231
-1.465
293
0.003413
Cold ~10 °C
9
134
0.0074
0.089
-2.419
281
0.003559
Ice Cold ~0 °C
2
185
0.0054
0.065
-2.733
277
0.003610
Rela+ve rate 1
time
, 1
T
Slope = E
a
=
Page of 5 4
Experiment: Reac/on Rates Lab Photos Show Sample Calcula+ons
Page of 5 5
Experiment: Reac/on Rates Page of 5 6
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