Lab 3 Reaction Rates Report

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Neumann University *

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107

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Chemistry

Date

Jan 9, 2024

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pdf

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6

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Experiment: Reac/on Rates Abstract The goal of this experiment was to observe the various reactions and determine their reaction rate as well as how long it would take for the reaction to blur and make the dot beneath disappear. Show the temperature rates as well as the reaction concentrations. The calculations were done to determine the link between the concentration and the rate of action of the reactant. Introduction In this lab they wanted to show the rate, time, and reaction between the two substances and water. When the concentrations mix they will form the reaction and determines on how fast the reaction completes. Changes of the different temperatures and the reactants concentration will initially affect the reaction rate of the entire experiment. Objective The objective is to investigate how concentration and temperature affect the rate of reaction between sodium thiosulfate and hydrochloric acid. Experimental The experimental technique for this lab was to test the calculations of the various reactions and do the calculations to discover the average rate, pre rate, and the graph to demonstrate the decline, slope, and Ln(k). Conclusion The lab results confirmed the experimental technique. Possible error could have been due to the computa/ons, experiment, rates, and ac/ons, A different technique could have involved using fewer or more of the dis/nct sequences of which compounds were u/lized to create each reac/on. Another op/on would have been to do three trails instead of two in oder to achieve a higher average. Page of 5 1
Experiment: Reac/on Rates Data and Calcula+ons Part A1: Dependence of Reac+on Rate on Concentra+on Table A1-1 – Trial Data 20drops=1mL 10 drops*1mL/20drops=0.5mL Table A1-2 – Rela+ve Rate and Concentra+on Calcula+ons 1/+me= rela+ve rate M1V1=M2V2 Part A2: Determina+on of the Reac+on Orders Calcula/on of “m” and “n”using mixtures 1, 2, 3 and 4. Use the values calculated in Table A1-2 for rela/ve reac/on rate and reactant concentra/on. Do this on a sheet of paper and insert a photo of your calcula/on. Record the calculated value of m and n here, rounded to the nearest integer: Reac+on Time Volume 0.1 M Na 2 S 2 O 3 Volume Water Volume 1.0 M HCl Total Solu+o n Volume Temp. (s) Drops mL Drops mL Drops mL mL (°C) Mixtur e Trial 1 Trial 2 Average 1 53 51 66 10 0.5 0 0 2 0.1 0.6 25 2 62 64 63 8 0.4 2 0.1 2 0.1 0.6 25 3 96 98 97 6 0.3 4 0.1 2 0.1 0.6 25 4 53 53 53 8 0.4 0 0.2 4 0.2 0.6 25 5 142 142 142 4 0.2 6 0.3 2 0.1 0.6 25 Mixture Average Reac/on Time Rela/ve reac/on rate Reactant Concentra/on [S 2 O 3 2– ] Reactant Concentra/on [H + ] (S) (s -1 ) (M) (M) 1 66 0.015 0.083 0.167 2 63 0.016 0.067 0.167 3 97 0.010 0.050 0.167 4 53 0.019 0.067 0.333 Calculate mixture 5 during Part A4: Predic+on of Rela+ve Reac+on Rate 5 142 0.007 0.0333 0.1667 Page of 5 2
Experiment: Reac/on Rates Part A3: Determina+on of the Rela+ve Rate Constant, k’ Table A3 - Determination of the Relative Rate Constant, k’ 1. Why should k’ have nearly the same value for each of the above reac/ons? k’ should have nearly the same value for each reac+on because the reac+on in in equilibrium. Part A4: Predic+on of Rela+ve Reac+on Rate Table A4 - Prediction of Relative Reaction Rate for Mixture 5 m = ln ( relative   rate 1 relative   rate 3 ) ln [ S 2 O 2 3 S 2 O 2 3 ] n = ln ( relative   rate 4 relative   rate 2 ) ln [ H + H + ] m= 0.8003 n= 0.0035 Mixture 1 2 3 4 Average k’ = 0.279 0.319 0.25 0.32 0.287 Predicted Observed % Error Page of 5 3
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