7 salt packs data sheet

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Saint Joseph's University *

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120

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Chemistry

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Jan 9, 2024

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docx

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4

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Evaluating salts for use in Hot-Packs or Cold-Packs based on Enthalpy of Solution Lab Jing Maniaci 31 st October 2023 Results Data Table I: Temperature Change on Solution Formation Salt 1: NH 4 NO 3 Salt 2: CaCl 2 Salt 1 Trial 1 Trial 2 Trial 3 Mass of Calorimeter, g 26.69 27.01 27.89 Mass of Salt, g 2.05 2.65 2.37 Mass of calorimeter + solution, g 126.93 127.69 126.88 Mass of Solution, g 100.24 100.68 98.99 T water , o C 21.7 21.5 21.4 T solution , o C 20.3 20.7 19.9 Change in temperature, ΔT, o C -1.4 -0.8 -1.5 Salt 2 Trial 1 Trial 2 Trial 3 Mass of Calorimeter, g 27.50 27.50 27.40 Mass of Salt, g 2.36 2.27 2.40 Mass of calorimeter + solution, g 127.51 127.30 128.0 Mass of Solution, g 100.01 99.8 100.6 T water , o C 21.5 22.2 21.8 T solution , o C 22.7 23.7 24.4 Change in temperature, ΔT, o C 1.2 1.5 2.6 Data Table II: Determining the Most Effective Hot-Pack and Cold-Pack
Salt Salt Name q sol , J q rxn , J Δ H o , kJ/mol q per gram of salt, J/g 1 NH 4 NO 3 -514.43 514.43 17.43 217.98 2 CaCl 2 754.17 -754.17 -35.74 -322.29 Based on the calculated enthalpy of solution for each of the salts in Data Table II identify the salt/s that would be used either in a hot pack or a cold pack below: Hot pack: CaCl 2 Cold pack : NH4NO3 Calculations NH 4 NO 3 : Heat absorbed or released by the solution: q sol = m soln x Cs x ΔT m soln : (100.24 +100.68 + 98.99)/3 = 99.96g Cs: 4.184 J/g.K ΔT: -1.23 o C Q sol : 99.96 g x 4.184 x -1.23 o C = -514.43 J Heat absorbed or released by the reaction: Q rxn = -q sol Q rxn = 514.43 J Enthalpy of solution formation: ΔH o rxn = q rxn /n: n: 2.36/80.04 = 0.0295 ΔH o rxn : 0.51443/0.00295 = 17.43 kJ/mol q per gram of salt: qrxn / mass of salt: = 514.43/2.36 = 217.98 J/g CaCl 2 :
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