Quiz 3

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University of Massachusetts, Lowell *

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Chemistry

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Jan 9, 2024

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Name: Quiz 3 E=hν λ =h/mv 1/λ = R(1/m 2 -1/n 2 ) h: 6.6x10 -34 Js R= 1.097x10 -2 nm -1 1. Which of the following has the largest radius. a. O 2- b. Mg 2+ c. Ne d. F - e. Al 3+ 2. Which of the following has the highest EA1. a. Na b. C c. N d. F e. Li 3. What happens to an atom’s radius when it loses an electron? a. It gets larger c. It stays the same b. It gets smaller d. It depends 4. What possible element has the following ionization energies (all in kJ/mol)? IE 1 = 786 IE 2 = 1580 IE 3 = 3230 IE 4 = 4360 IE 5 = 16100 a. Si b. P c. Al d. Mg e. Cl 5. Which reaction below represents the electron affinity of K? a. K(g) + e⁻ → K⁻(g) + EA1 b. K(g) + EA1 → K⁺(g) + e⁻ c. K(g) + e⁻ → K⁺(g) + EA1 d. K⁺(g) + e⁻ → K(g) + EA1 e. K⁺(g) + EA1→ K (g) + e⁻ 6. (2 points) Which of the following is not correct? a. n = 3 l = 3 m l = 0 c. n = 2 l = 1 m l = 0 b. n = 5 l = 1 m l = -1 d. n = 4 l = 2 m l = -2 e. None of above 7. (2 points) How many nodes in 5s orbital? a. 0 b. 1 c. 2 d. 3 e. 4 8. How many orbitals are contained in the third principal level ( n = 3) of a given atom? a. 8 b. 18 c. 10 d. 9 e. 5 9. Theoretically, how many 15p orbitals exist? a. 1 b. 3 c. 5 d. 7 e. 9
Name: __________________ 10. If ℓ = 0, which of the following may be true? a . n=6 b. m l = -1 c. m l = + 1 d. m s = 0 e. m s = +1 11. Identify the correct values for a 2p sublevel a. n = 2, l = 2, m l =0 c. n = 2, l = 1, m l = 2 b. n = 2, l = 1, m l =-1 d. n= 3, l = 1, m l = -1 12. What are the possible values of quantum numbers for an electron in a 4 f orbital? a. n = 4 and l = 3 c. n = 3 and m l = -2, -1, 0, +1, or +2 b. n = 3 and m l = -2, -1, 0, +1, +2 d. n = 4 and l = 4 13. Give the expected ground-state configuration of Cd (Z=48). a. [Kr] 5s 2 4d 10 b. [Kr] 5s 2 4d 10 5p 2 c. 1s 2 2s 2 2p 6 3s 2 3p 6 3d 10 d. 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 14. A Bohr model of an atom of hydrogen is shown in the figure. Which transition(s) depicted by arrows result in energy emission, found as a line in the atomic emission spectrum? n = 1 n = 2 n = 3 (1) (2) (3) (4) a. Only 1 b. Only 1 and 4 c. Only 2 d. Only 2 and 3 15. What are the possible values of quantum numbers for an electron in a 4 f orbital? a. n = 4 and l = 3 c. n = 3 and m l = -2, -1, 0, +1, or +2 b. n = 3 and m l = -2, -1, 0, +1, +2 d. n = 4 and l = 4 16. What is the maximum number of electrons that can have the following set of quantum numbers? n = 4, ℓ = 2, m = 1, m s = -½ a. 1 b. 3 c. 7 d. 6 e. 14
17. (4 points)What is the noble gas configuration of Zn 2+ ? Is this cation paramagnetic or diamagnetic? [Ar] 3d 10 Diamagnetic Name: Quiz 3 E=hν λ =h/mv 1/λ = R(1/m 2 -1/n 2 ) h: 6.6x10 -34 Js R= 1.097x10 -2 nm -1 1. (2 points)What are the possible values of quantum numbers for an electron in a 4 d orbital? a. n = 4 and l = 3 c. n = 3 and m l = -2, -1, 0, +1, or +2 b. n = 4 and m l = -2, -1, 0, +1, +2 d. n = 1, 2, 3, 4 and m l = -2, -1, 0, +1, +2 2. (2 points)Which of the following has the largest radius. a. Ca b. Cl - c. P 3- d. S 2- e. They are the same 3. (2 points)Which of the following has the highest IE1. a. Cs b. Cl c. Na d. Al e. Not enough info 4. (2 points)What happens to an atom’s radius when it gains an electron? a. It gets larger c. It stays the same b. It gets smaller d. It depends on situation 5. What possible element has the following ionization energies (all in kJ/mol)? IE 1 = 578 IE 2 = 1820 IE 3 = 2750 IE 4 = 11600 a. Al b. P c. Si d. Mg e. Cl 6. Which reaction below represents the ionization energy of F? a. F(g) + e⁻ → F⁻(g) +IE1 b. F(g) +IE1 → F⁺(g) + e⁻ c. F(g) + e⁻ → F⁺(g) +IE1 d. F⁺(g) + e⁻ → F(g) +IE2 7. Give the set of four quantum numbers that represent the last electron added (using the Aufbau principle) to the Ni atom(atomic number 28). a. n = 4, l = 3, m l = 3, m s = - 1 2 d. n = 3, l = 2, m l = 0, m s = - 1 2 b. n = 3, l = 1, m l = 1, m s = + 1 2 e. n = 3, l = 3, m l = 2, m s = - 1 2 c. n = 4, l = 2, m l = 0, m s = + 1 2 8. (2 points) Give the expected ground-state configuration of Zn (Z=30).
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