Chem 121 Module 3 Exam

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Portage Learning *

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121

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Chemistry

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Jan 9, 2024

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Problem #3 Show the calculaƟon of the volume of H2O gas produced by the combusƟon of 33.5 grams of ethanol by excess O2 gas at 35°C and 1.05 atm. The combusƟon of ethanol (C2H5OH) takes place by the following reacƟon equaƟon. C2H5OH (l) + 3 O2 (g) 2 CO2 (g) + 3 H2O (g) Answer: MW=46 g/mol 33.5 g 0.7283 mol 3 X 0.7283 mol H2O V = nRT / P = (2.1849)(0.0821)(308.15)/1.05 = 52.64 liters Problem #4 Show the calculaƟon of the mole fracƟon of each gas in a 1.00 liter container holding a mixture of 7.60 g of N2 and 8.40 g of O2 at 35°C. Answer: n N2 = 7.60/28.02= .2712 mol n O2 = 8.40/32.00=.2625 mol N2 mol fracƟon = .2712/(.2712+.2625)= .5082 O2 mol fracƟon = .2625/(.2712 + .2625)= .4918 Problem #5 Show the calculaƟon of the molecular weight of an unknown gas if the rate of effusion of oxygen gas (O2) is 1.562 Ɵmes faster than that of an unknown gas. Answer: (r O2 /r unknown ) 2 = MW unknown /MW O2 (1.562/1) 2 = MW unknown /32.00 (1.562/1) 2 X 32.00 = 78.08 Problem #6
Write the subshell electron configuraƟon (i.e. 1s 2 2s 2 , etc.) for the K19 atom and idenƟfy which are valence (outer shell) electrons and determine how many valence electrons there are. Answer: K 19 = 1s 2 2s 2 2p 6 3s 2 3p 6 4s 1 4s 1 is outermost with 1 electron 1 valence electron Problem #7 Using up and down arrows, write the orbital diagram for the Cr 24 atom and idenƟfy which are unpaired electrons and determine how many unpaired electrons there are. Answer: ↑↓ ↑↓ ↑↓↑↓↑↓ ↑↓ ↑↓↑↓↑↓ ↑↓ ↑↑↑↑ 4 unpaired electrons Problem #8 Write the subshell electron configuraƟon (i.e. 1s 2 2s 2 , etc.) for the V23 atom and then idenƟfy the last electron to fill and write the 4 quantum numbers (n, l, m l , m s ) for this electron. Answer: V 23 = 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 3 n=3, l=2, m l =0, m s =+1/2 Problem #9 List and explain your answers for the following two problems: 1) List and explain which of the following is the larger atom: Ga or Se 2) List and explain which of the following atoms holds its valence electrons less Ɵghtly Al or S Answer: 1) Ga is larger than Se since atomic size as you move the right in a period which means that Ga is larger
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