A 1.000 liter sample of sea water was evaporated to a small volume and treated with an excess of sodium tetraphenylboron. The precipitated tetraphenylboron was filtered and then redissolved in acetone. The analysis was completed by a Mohr titration that required 34.32 ml of 0.03875 M AgNO3. Calculate the parts per million of potassium in the sea water sample. K* + NaB(C,H5)4 → KB(C,H5)4ls) + Na* ; Ag* + KB(C;Hs)4 → AgB(C6H5)4(s) + K*

Fundamentals Of Analytical Chemistry
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Chapter17: Complexation And Precipitation Reactions And Titrations
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Problem 17.35QAP
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A 1.000 liter sample of sea water was evaporated to a small volume and treated with
an excess of sodium tetraphenylboron. The precipitated tetraphenylboron was
filtered and then redissolved in acetone. The analysis was completed by a Mohr
titration that required 34.32 ml of 0.03875 M AGNO3. Calculate the parts per million
of potassium in the sea water sample.
K* + NaB(C,Hs)4 → KB(C,Hs)4(s) + Na* ;
Ag* + KB(C,H5)4 > AgB(CgHs)4(6) + K*
Transcribed Image Text:A 1.000 liter sample of sea water was evaporated to a small volume and treated with an excess of sodium tetraphenylboron. The precipitated tetraphenylboron was filtered and then redissolved in acetone. The analysis was completed by a Mohr titration that required 34.32 ml of 0.03875 M AGNO3. Calculate the parts per million of potassium in the sea water sample. K* + NaB(C,Hs)4 → KB(C,Hs)4(s) + Na* ; Ag* + KB(C,H5)4 > AgB(CgHs)4(6) + K*
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